WO2003094239A1 - Semiconductor device having strained silicon and silicon germanium alloy layers - Google Patents
Semiconductor device having strained silicon and silicon germanium alloy layers Download PDFInfo
- Publication number
- WO2003094239A1 WO2003094239A1 PCT/GB2003/001825 GB0301825W WO03094239A1 WO 2003094239 A1 WO2003094239 A1 WO 2003094239A1 GB 0301825 W GB0301825 W GB 0301825W WO 03094239 A1 WO03094239 A1 WO 03094239A1
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- WIPO (PCT)
- Prior art keywords
- layer
- silicon
- conduction layer
- conduction
- substrate
- Prior art date
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- 229910000577 Silicon-germanium Inorganic materials 0.000 title claims abstract description 33
- LEVVHYCKPQWKOP-UHFFFAOYSA-N [Si].[Ge] Chemical compound [Si].[Ge] LEVVHYCKPQWKOP-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 30
- 239000010703 silicon Substances 0.000 title claims abstract description 30
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 23
- 239000000956 alloy Substances 0.000 title claims abstract description 23
- 239000004065 semiconductor Substances 0.000 title claims abstract description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000758 substrate Substances 0.000 claims abstract description 23
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 10
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 4
- 230000005669 field effect Effects 0.000 claims description 12
- 229910021483 silicon-carbon alloy Inorganic materials 0.000 claims description 2
- 238000000926 separation method Methods 0.000 abstract description 6
- 230000000295 complement effect Effects 0.000 abstract description 2
- 229910006990 Si1-xGex Inorganic materials 0.000 abstract 1
- 229910007020 Si1−xGex Inorganic materials 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000001459 lithography Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 3
- 229920005591 polysilicon Polymers 0.000 description 3
- 238000005530 etching Methods 0.000 description 2
- 238000005468 ion implantation Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000002800 charge carrier Substances 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/16—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic System
- H01L29/161—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic System including two or more of the elements provided for in group H01L29/16, e.g. alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/77—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
- H01L21/78—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
- H01L21/82—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
- H01L21/822—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
- H01L21/8232—Field-effect technology
- H01L21/8234—MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type
- H01L21/8238—Complementary field-effect transistors, e.g. CMOS
- H01L21/823807—Complementary field-effect transistors, e.g. CMOS with a particular manufacturing method of the channel structures, e.g. channel implants, halo or pocket implants, or channel materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/77—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
- H01L21/78—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
- H01L21/82—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
- H01L21/822—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
- H01L21/8232—Field-effect technology
- H01L21/8234—MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type
- H01L21/8238—Complementary field-effect transistors, e.g. CMOS
- H01L21/823878—Complementary field-effect transistors, e.g. CMOS isolation region manufacturing related aspects, e.g. to avoid interaction of isolation region with adjacent structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier
- H01L27/04—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being a semiconductor body
- H01L27/08—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being a semiconductor body including only semiconductor components of a single kind
- H01L27/085—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being a semiconductor body including only semiconductor components of a single kind including field-effect components only
- H01L27/088—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being a semiconductor body including only semiconductor components of a single kind including field-effect components only the components being field-effect transistors with insulated gate
- H01L27/092—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being a semiconductor body including only semiconductor components of a single kind including field-effect components only the components being field-effect transistors with insulated gate complementary MIS field-effect transistors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/06—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
- H01L29/10—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions with semiconductor regions connected to an electrode not carrying current to be rectified, amplified or switched and such electrode being part of a semiconductor device which comprises three or more electrodes
- H01L29/1025—Channel region of field-effect devices
- H01L29/1029—Channel region of field-effect devices of field-effect transistors
- H01L29/1033—Channel region of field-effect devices of field-effect transistors with insulated gate, e.g. characterised by the length, the width, the geometric contour or the doping structure
- H01L29/1054—Channel region of field-effect devices of field-effect transistors with insulated gate, e.g. characterised by the length, the width, the geometric contour or the doping structure with a variation of the composition, e.g. channel with strained layer for increasing the mobility
Definitions
- the present invention relates to semiconductor devices, and relates particularly, but not exclusively to CMOS devices having strained silicon and silicon germanium alloy layers to provide channels for transistors.
- NMOS transistors are known in which a silicon layer is grown on a layer of silicon-germanium alloy such that the silicon layer is under tensile strain.
- the separation of atoms in pure silicon is less than in pure germanium, and when the silicon layer is grown on the silicon-germanium alloy layer, the separation of the silicon atoms therefore increases to follow the atomic arrangement of the underlying silicon-germanium layer.
- the resulting silicon layer is under tension, and the tensile strain of the silicon layer improves the conductivity of electrons in the strained silicon. This phenomenon can be used to improve the speed of operation of NMOS transistors when the conduction channel is formed in the strained silicon layer.
- PMOS devices are also known in which a silicon-germanium alloy layer with a higher density of germanium is grown on a silicon- germanium alloy layer having a lower germanium density.
- the atoms of the silicon-germanium layer of higher germanium density are arranged closer together, as a result of which that silicon-germanium layer is placed under compressive strain.
- This increases the conductivity of the layer to holes, which improves the speed of operation of PMOS transistors of which the hole conduction channels are formed in the silicon- germanium layer.
- CMOS type devices which are the commonest type of microelectronic device, it is necessary to have both NMOS and PMOS transistors on the same device.
- the problem arises that the performance of one type of transistor must generally be compromised to maximise the performance of the other type.
- EP0683522 discloses a CMOS device incorporating NMOS transistors having an n-channel under tensile strain, and PMOS transistors having a p-channel under compressive strain.
- the device of EP0683522 suffers from a number of drawbacks.
- the object of the device of EP0683522 is specifically to create buried n-channel and p-channel layers and to remove carriers from the gate dielectric interface and to have the p-channel closer to the gate electrode than the n- channel. This unduly degrades the performance (e.g. transconductance) of n-channel transistors, which are crucial to high performance in CMOS circuits . Better performance is obtained with the n-channel at the gate dielectric interface.
- the invention specifies a virtual substrate of silicon germanium having a germanium fraction between 0.2 - 0.5, which makes high temperature device processing problematic due to the high degree of strain incorporated within conducting layers .
- Preferred embodiments of the present invention seek to overcome the above disadvantages of the prior art.
- a semiconductor device comprising: -
- first conduction layer formed on a first side of said substrate layer and comprising silicon-germanium alloy having a lattice constant in an unstrained state larger than that of said substrate layer such that said first conduction layer is under compressive strain, wherein said first conduction layer is adapted to have respective source and drain regions of at least one first field effect transistor formed therein;
- a second conduction layer formed on a side of said first conduction layer remote from said substrate layer and comprising silicon, such that said second conduction layer is under tensile strain, wherein said second conduction layer is adapted to have respective source and drain regions of at least one second field effect transistor formed therein.
- this provides the advantage of enabling the advantageous features of a surface n-channel device to be combined with the advantages of a buried p-channel device without having to compromise the performance of either type of device.
- the device may further comprise an electrically insulating layer formed on a side of said second conduction layer remote from said first conduction layer, and respective gate electrodes of at least one said first and second field effect transistor formed on said electrically insulating layer.
- the substrate layer may be provided on a silicon substrate.
- the second conduction layer is preferably directly formed on said first conduction layer.
- said first conduction layer further comprises respective source and drain regions of at least one p-channel field effect transistor.
- said second conduction layer further comprises respective source and drain regions of at least one n-channel field effect transistor.
- said substrate layer is silicon- germanium alloy having the formula Si ⁇ _ x Ge x , where x is between 0 and 0.25.
- the first conduction layer may comprise silicon-germanium alloy having an average germanium density higher than that of said substrate layer.
- said first conduction layer is formed directly on said substrate layer and comprises silicon- germanium alloy and has a thickness of at least 5 nm.
- the substrate layer may comprise silicon-carbon alloy.
- the device may further comprise respective gate regions of a plurality of said first and second field effect transistors arranged on a side of said second conduction layer remote from said first conduction layer, and an electrically insulating layer arranged between each said gate region and the second conduction layer.
- Figures 1 to 6 are schematic cross-sectional views showing steps in the formation of a semiconductor device embodying the present invention.
- CMOS complementary metal-oxide- silicon
- a CMOS (complementary metal-oxide- silicon) heterojunction semiconductor device is formed by growing a virtual substrate 1 of silicon-germanium alloy on a silicon wafer 2, the silicon wafer 2 being in a relaxed state and the silicon-germanium alloy of the virtual substrate 1 having the formula Si ⁇ - x Ge x , where x varies between 0 and 0.25, and is typically 0.15.
- a first conduction layer 3 of silicon-germanium alloy having the formula Si ⁇ _ y Ge y where y is less than x+0.3 is then grown on the relaxed silicon-germanium substrate 1. Because of the higher average germanium density in layer 3 compared with virtual substrate 1, the separation of atoms in layer 3 is less than in virtual substrate 1, as a result of which layer 3 is under compressive strain. As will be familiar to persons skilled in the art, this significantly increases the conductivity of the layer 3 to holes compared with a relaxed layer (i.e. not under compressive strain) of the same material.
- a second conduction layer 4 of silicon is then grown on silicon-germanium alloy layer 3. Because the separation of silicon atoms is less than in silicon-germanium, the silicon layer 4 is placed under tensile stress, which significantly increases the conductivity of layer 4 to electrons.
- the wafer is cleaned, and alignment marks are defined on the wafer for lithography steps.
- the active area is then defined, and dielectric regions 5 are formed by low temperature processing to avoid diffusion of germanium from layer 3 into layer 4, which would degrade devices formed in silicon layer 4.
- p-type 6 and n-type 7 wells are formed by a suitable technique such as ion implantation, the wells extending downwards into the virtual substrate 1.
- the wells are intended to surround source and drain regions of transistors to be formed in the wafer.
- Gate stacks, each of which comprises a gate oxide layer 8 and a polysilicon gate electrode 9 are formed by growing a continuous layer of gate oxide 8, depositing a continuous layer of polysilicon 9, and using lithographic techniques and etching to define the date region and then remove unwanted oxide and polysilicon. This arrangement is shown in Figure 3.
- source 10 and drain 11 regions of an n-channel transistor are formed by ion implantation and annealing, the source and drain regions extending downwards into the virtual substrate 1.
- source 12 and drain 13 regions of a p-channel transistor are formed.
- a continuous dielectric layer 14 of BPSG boron phosphorous silica glass is deposited over the top surface of the wafer as shown in Figure 5.
- contact windows are opened in dielectric layer 14 by lithography and etching, and metal for forming contacts to the gates, sources and drains of the transistors is deposited. The metal is then patterned using lithography and etched to leave source 15, gate 16 and drain 17 contacts respectively.
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2003227894A AU2003227894A1 (en) | 2002-04-29 | 2003-04-28 | Semiconductor device having strained silicon and silicon germanium alloy layers |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0209739.2 | 2002-04-29 | ||
GB0209739A GB0209739D0 (en) | 2002-04-29 | 2002-04-29 | Semiconductor device having strained silicon and silicon-germanium alloy layers |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003094239A1 true WO2003094239A1 (en) | 2003-11-13 |
Family
ID=9935693
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2003/001825 WO2003094239A1 (en) | 2002-04-29 | 2003-04-28 | Semiconductor device having strained silicon and silicon germanium alloy layers |
Country Status (3)
Country | Link |
---|---|
AU (1) | AU2003227894A1 (en) |
GB (1) | GB0209739D0 (en) |
WO (1) | WO2003094239A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006006972A1 (en) * | 2004-06-24 | 2006-01-19 | International Business Machines Corporation | Improved strained-silicon cmos device and method |
US7495266B2 (en) * | 2004-06-16 | 2009-02-24 | Massachusetts Institute Of Technology | Strained silicon-on-silicon by wafer bonding and layer transfer |
US7808081B2 (en) | 2004-08-31 | 2010-10-05 | International Business Machines Corporation | Strained-silicon CMOS device and method |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0683522A2 (en) * | 1994-05-20 | 1995-11-22 | International Business Machines Corporation | CMOS with strained Si/SiGe layers |
US6310367B1 (en) * | 1999-02-22 | 2001-10-30 | Kabushiki Kaisha Toshiba | MOS transistor having a tensile-strained SI layer and a compressive-strained SI-GE layer |
-
2002
- 2002-04-29 GB GB0209739A patent/GB0209739D0/en not_active Ceased
-
2003
- 2003-04-28 WO PCT/GB2003/001825 patent/WO2003094239A1/en not_active Application Discontinuation
- 2003-04-28 AU AU2003227894A patent/AU2003227894A1/en not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0683522A2 (en) * | 1994-05-20 | 1995-11-22 | International Business Machines Corporation | CMOS with strained Si/SiGe layers |
US6310367B1 (en) * | 1999-02-22 | 2001-10-30 | Kabushiki Kaisha Toshiba | MOS transistor having a tensile-strained SI layer and a compressive-strained SI-GE layer |
Non-Patent Citations (1)
Title |
---|
ARMSTRONG M A ET AL: "Design of Si/SiGe heterojunction complementary metal-oxide-semiconductor transistors", ELECTRON DEVICES MEETING, 1995., INTERNATIONAL WASHINGTON, DC, USA 10-13 DEC. 1995, NEW YORK, NY, USA,IEEE, US, 10 December 1995 (1995-12-10), pages 761 - 764, XP010161102, ISBN: 0-7803-2700-4 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7495266B2 (en) * | 2004-06-16 | 2009-02-24 | Massachusetts Institute Of Technology | Strained silicon-on-silicon by wafer bonding and layer transfer |
WO2006006972A1 (en) * | 2004-06-24 | 2006-01-19 | International Business Machines Corporation | Improved strained-silicon cmos device and method |
EP1790012A1 (en) * | 2004-06-24 | 2007-05-30 | International Business Machines Corporation | Improved strained-silicon cmos device and method |
US7227205B2 (en) | 2004-06-24 | 2007-06-05 | International Business Machines Corporation | Strained-silicon CMOS device and method |
US7808081B2 (en) | 2004-08-31 | 2010-10-05 | International Business Machines Corporation | Strained-silicon CMOS device and method |
Also Published As
Publication number | Publication date |
---|---|
AU2003227894A1 (en) | 2003-11-17 |
GB0209739D0 (en) | 2002-06-05 |
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