US3418232A - Anolyte liquid level control for chlor-alkali diaphragm cells - Google Patents

Anolyte liquid level control for chlor-alkali diaphragm cells Download PDF

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US3418232A
US3418232A US51031765A US3418232A US 3418232 A US3418232 A US 3418232A US 51031765 A US51031765 A US 51031765A US 3418232 A US3418232 A US 3418232A
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anolyte
cell
liquid level
level control
chlor
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Alvin T Emery
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Occidental Chemical Corp
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Hooker Chemical Corp
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Priority to NL136394D priority Critical patent/NL136394C/xx
Application filed by Hooker Chemical Corp filed Critical Hooker Chemical Corp
Priority claimed from US510225A external-priority patent/US3403083A/en
Priority to US51031765 priority patent/US3418232A/en
Priority to GB5301566A priority patent/GB1174264A/en
Priority to SE1625466A priority patent/SE331675B/xx
Priority to NL6616808A priority patent/NL6616808A/xx
Priority to DE1966H0061128 priority patent/DE1567963B2/en
Priority to BE690427D priority patent/BE690427A/xx
Priority to FR85425A priority patent/FR1502407A/en
Publication of US3418232A publication Critical patent/US3418232A/en
Application granted granted Critical
Assigned to OCCIDENTAL CHEMICAL CORPORATION reassignment OCCIDENTAL CHEMICAL CORPORATION CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). EFFECTIVE APRIL 1, 1982. Assignors: HOOKER CHEMICALS & PLASTICS CORP.
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Expired - Lifetime legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/34Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
    • C25B1/46Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
    • C25B15/08Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05DSYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
    • G05D9/00Level control, e.g. controlling quantity of material stored in vessel
    • G05D9/02Level control, e.g. controlling quantity of material stored in vessel without auxiliary power
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/4456With liquid valves or liquid trap seals
    • Y10T137/4463Liquid seal in liquid flow line; flow liquid forms seal
    • Y10T137/4576U-seals
    • Y10T137/4606Even diameter legs
    • Y10T137/4613Access opening
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/8593Systems
    • Y10T137/86236Tank with movable or adjustable outlet or overflow pipe

Definitions

  • anolyte withdrawal means comprising a conduit extending from the interior of the anolyte compartment of the cell to a liquid retaining vessel within which is disposed an overflow pipe which may be adjusted to raise or lower the overflow inlet and thereby raise or lower the level of the anolyte in the electrolytic cell.
  • the liquid level control device may be equipped with means to equalize the pressure within the anolyte compartment and a sight glass for observation of liquid flow.
  • This invention relates to an anolyte liquid level control device for chlor-alkali cells, and more particularly, to an apparatus for the withdrawal of anolyte solution from a chlor-alkali diaphragm cell while maintaining a predetermined liquid level within the anolyte compartment.
  • an anolyte liquor withdrawal means for a chlor-alkali diaphragm cell comprising a passageway for liquids, such as a tube, said passageway having an inlet means and an outlet means for liquids, said inlet means being in communication with the anolyte compartment of said cell and said outlet means being positioned external to the anolyte compartment of said cell, said outlet means having liquid level control means in communication therewith, thereby providing for the controlled removal of anolyte liquor from said anolyte compartment.
  • the described passageway is a tube, pipe or drain positioned below the surface of the anolyte liquid in the anolyte compartment, through which anolyte liquor flows to a level control means, said level control means having 3,418,232 Patented Dec. 24, 1968 pressure equalizing means in communication with the anolyte compartment, such as a gas vent, wherein the level of the anolyte liquor within the cell is controlled by the position of an overflow device within said level control means.
  • the present anolyte liquid level control has particular advantages in withdrawing anolyte liquor from below the liquid surface in the anolyte compartment in that it provides more thorough mixing of the feed brine within the anolyte compartment due to the greater distance between the brine feed means and the withdrawal point and in eliminating the withdrawal of the particles which float on the surface of the anolyte liquor, such as pieces of asbestos, thus reducing the likelihood of clogging the withdrawal means.
  • the apparatus of the present invention is preferably mounted on the upper cell wall of a chlor-alkali cell in a position such that passageway 12 extends through packing 17 into the anolyte compartment 14 of said chlor-alkali cell.
  • Passage 12 has liquid inlet means 16 and outlet means 18 in communication with level control means 20.
  • Level control means 20 is a liquid retainer having pressure equalizing means 24 to vent gases to anolyte compartment 14 through opening 15' above anolyte liquid level 22. Since chlor-alkali cells normally are run under slightly reduced pressure, pressure equalizing means are preferably provided to result in a smooth withdrawal of liquid from the cell. Rather than equalizing the gaseous pressure directly with the anolyte compartment, pressure equalizing means can be attached to the chlorine withdrawal means of the cell.
  • Liquid overflow 26 regulates the anolyte liquid level 22 within anolyte compartment 14 by withdrawing liquid through passageway 12 into level control means 20 from which it is subsequently removed through overflow 26 into stand pipe 38.
  • Overflow 26 can be adjusted by raising or lowering the liquid intake 28, by means of handle 27 which protrudes through bushing 29 in cap 31, thereby controlling the anolyte level 22 within the cell.
  • brine is fed through brine feed means 39 into anolyte compartment 14, from whence it passes into the catholyte compartment 34 by passing through diaphragm 32.
  • Cell liquor (brine containing sodium hydroxide) is withdrawn from the catholyte compartment by means of withdrawal pipe 36.
  • the brine feed rate is greater than the rate at which the brine passes from the anolyte compartment 14 through the diaphragm 32 into the catholyte compartment 34. This excess brine may be withdrawn from the anolyte compartment 14 by means of passageway 12.
  • One means of adjusting the anolyte liquid level 22 is by raising or lowering overflow 26 within liquid level control means 20 by sliding overflow 26 through gasket means 21.
  • adjustments can be made in the position of liquid intake 28 on overflow 26 by manual movements of overflow 26, by placing or removing tubular extensions on the top of overflow 26, by changing the level at which liquid flows into overflow 26 as by opening or closing a series of openings along the length of said overflow device as well as other methods which will be readily apparent to those skilled in the art from the disclosure herein.
  • the anolyte liquid level 22 can be raised to within about half-inch or so of the top of the anolyte compartment of the chlor-alkali cell and lowered to the level of passageway 12.
  • anolyte liquid level 22 changes the hydrostatic pressure 3 within the cell and affects the flow of liquid through diaphragm 32.
  • the flow of anolyte liquor through the diaphragm 32 can be regulated by changing anolyte liquid level 22.
  • a higher liquid level 22 increases the hydrostatic pressure and, as such, increases the flow rate through the diaphragm.
  • Passageway 12 and overflow 26 are of a diameter suflicient to withdraw anolyte liquor at a rate approaching that at which brine is fed to the anolyte compartment. Since the brine is often fed to the anolyte compartment under pressure, and whereas the flow through the liquid withdrawal means is primarily by means of gravity, the diameter of passageway 12 and overflow 26 are preferably about equal to or larger than brine feed means 30. Normally, passageway 12 and overflow 26 have an inside cross-sectional area equal to about 1 to times the inside cross-sectional area of brine feed means 30.
  • the anolyte liquor withdrawn from the cell by means of level control 20 is passed to manifold 42 for subsequent mixing with additional anolyte liquor from other cells prior to resaturation with salt and returning to the anolyte compartment of a cell for further reaction.
  • level control means 20 and overflow 26 may be constructed of any material substantially inert to the conditions existing within the cell. Such conditions include operating temperatures within the range of about 90 to 110 degrees centigrade while in contact with a concentrated salt (NaCl) solution saturated with chlorine. In addition, such material of construction is preferably capable of withstanding chlorine attack at a pH in the range of about 1 to 7. The material selected is preferably, but not necessarily, electrically nonconductive to avoid loss of electrical current. It has been found, that various synthetic polymers, such as polyvinylidene chloride, afterchlorinated polyvinyl chloride, chlorinated polyesters, chlorinated rubbers, and the like materials can be used. Glass and ceramic and various metals, such as tantalum, titanium, and the like, can also be used as the anolyte level control apparatus.
  • various synthetic polymers such as polyvinylidene chloride, afterchlorinated polyvinyl chloride, chlorinated polyesters, chlorinated rubbers, and the like materials can be used. Glass and ceramic and
  • Stand pipe 38 into which overflow 26 passes anolyte liquor, has sight glass 40 through which observations of the liquor being withdrawn from the anolyte compartment 14 and the flow rate thereof can be made.
  • the present invention provides a means for controlling the caustic soda concentration of the cell liquor produced in the catholyte compartment of the cell by regulating the caustic concentration, so that a more desirable salt to caustic ratio can be obtained.
  • the hydrostatic pressure is changed, thus changing the residence time of the brine within the catholyte compartment due to a slower flow through the diaphragm.
  • the present apparatus coacts with the cell to produce a more desirable cell liquor.
  • a chlor-alkali diaphragm cell comprising an anolyte compartment separated from a catholyte compartment by a porous diaphragm, said anolyte compartment comprising an anode, brine feed means and chlorine gas withdrawal means, the improvement which is anolyte liquor withdrawal means comprising a passageway having an inlet in communication with the anolyte compartment of said cell and an outlet external to the anolyte compartment, said outlet having liquid level control means in communication therewith which provides for controlled removal of anolyte from said anolyte compartment.
  • liquid level control means has gaseous pressure equalizing means between upper portions of said control and said anolyte compartment.
  • liquid level control means comprises a liquid retainer having positioned therein liquid overflow means.
  • sight means is provided in communication with said liquid level control means for the observation of liquid flow.
  • liquid level control means is a liquid retainer having an adjustable liquid overflow therein and gaseous pressure equalizing means in communication with the anolyte compartment above the liquid level thereof.

Description

A. T. EMERY Dec. 24, 1968 ANOLYTE LIQUID LEVEL CONTROL FOR CHLOR-ALKALI DIAPHRAGM CELLS Filed Nov. 29, 1965 United States Patent 3,418,232 ANOLYTE LIQUID LEVEL CONTROL FOR CHLGR-ALKALI DIAPHRAGM CELLS Alvin T. Emery, North Tonawanda, N.Y., assignor to Hooker Chemical Corporation, Niagara Falls, N.Y.,
a corporation of New York Filed Nov. 29, 1965, Ser. No. 510,317 7 Claims. (Cl. 204263) ABSTRACT OF THE DISCLOSURE Recirculation of anolyte in a diaphragm type chlor-alkali electrolytic cell is performed in conjunction with control of the anolyte level in the anolyte compartment by anolyte withdrawal means comprising a conduit extending from the interior of the anolyte compartment of the cell to a liquid retaining vessel within which is disposed an overflow pipe which may be adjusted to raise or lower the overflow inlet and thereby raise or lower the level of the anolyte in the electrolytic cell. The liquid level control device may be equipped with means to equalize the pressure within the anolyte compartment and a sight glass for observation of liquid flow.
This invention relates to an anolyte liquid level control device for chlor-alkali cells, and more particularly, to an apparatus for the withdrawal of anolyte solution from a chlor-alkali diaphragm cell while maintaining a predetermined liquid level within the anolyte compartment.
It has recently been found to be desirable to operate a chlor-alkali diaphragm cell utilizing an anolyte recirculation method wherein brine feed solution is fed to the anolyte compartment of a chlor-alkali cell at a rate greater than that at which the feed solution flows through the diaphragm into the catholyte compartment. In the operation of the anolyte recirculation method, it is also desirable to maintain a certain liquid level within the anolyte compartment which level provides a hydrostatic head which brings pressure to bear upon the diaphragm thereby forcing liquid through the diaphragm. It is further desirable to be able to change the hydrostatic head within the anolyte compartment to provide for changes in operating procedures, thereby regulating the flow rate of anolyte liquor through the diaphragm into the catholyte compartment.
It is an object of the present invention to provide an apparatus for the withdrawal of excess brine feed solution from an anolyte compartment of a chlor-alkali cell diaphragm cell. Another object of the present invention is to provide an apparatus for the control of the liquid level within the anolyte compartment of such cells. These and other objects will become apparent to those skilled in the art from the description of the invention which follows.
in accordance with the invention, there is provided an anolyte liquor withdrawal means for a chlor-alkali diaphragm cell comprising a passageway for liquids, such as a tube, said passageway having an inlet means and an outlet means for liquids, said inlet means being in communication with the anolyte compartment of said cell and said outlet means being positioned external to the anolyte compartment of said cell, said outlet means having liquid level control means in communication therewith, thereby providing for the controlled removal of anolyte liquor from said anolyte compartment. In a preferred embodiment of the present invention, the described passageway is a tube, pipe or drain positioned below the surface of the anolyte liquid in the anolyte compartment, through which anolyte liquor flows to a level control means, said level control means having 3,418,232 Patented Dec. 24, 1968 pressure equalizing means in communication with the anolyte compartment, such as a gas vent, wherein the level of the anolyte liquor within the cell is controlled by the position of an overflow device within said level control means. 7
The present anolyte liquid level control has particular advantages in withdrawing anolyte liquor from below the liquid surface in the anolyte compartment in that it provides more thorough mixing of the feed brine within the anolyte compartment due to the greater distance between the brine feed means and the withdrawal point and in eliminating the withdrawal of the particles which float on the surface of the anolyte liquor, such as pieces of asbestos, thus reducing the likelihood of clogging the withdrawal means.
The invention will be readily understood by reference to the drawing which is a partial vertical sectional view of a chlor-alkali diaphragm cell showing the apparatus of the present invention located on the upper sidewall of the cell.
The apparatus of the present invention is preferably mounted on the upper cell wall of a chlor-alkali cell in a position such that passageway 12 extends through packing 17 into the anolyte compartment 14 of said chlor-alkali cell. Passage 12 has liquid inlet means 16 and outlet means 18 in communication with level control means 20. Level control means 20 is a liquid retainer having pressure equalizing means 24 to vent gases to anolyte compartment 14 through opening 15' above anolyte liquid level 22. Since chlor-alkali cells normally are run under slightly reduced pressure, pressure equalizing means are preferably provided to result in a smooth withdrawal of liquid from the cell. Rather than equalizing the gaseous pressure directly with the anolyte compartment, pressure equalizing means can be attached to the chlorine withdrawal means of the cell.
Liquid overflow 26 regulates the anolyte liquid level 22 within anolyte compartment 14 by withdrawing liquid through passageway 12 into level control means 20 from which it is subsequently removed through overflow 26 into stand pipe 38. Overflow 26 can be adjusted by raising or lowering the liquid intake 28, by means of handle 27 which protrudes through bushing 29 in cap 31, thereby controlling the anolyte level 22 within the cell.
In the operation of the cell, brine is fed through brine feed means 39 into anolyte compartment 14, from whence it passes into the catholyte compartment 34 by passing through diaphragm 32. Cell liquor (brine containing sodium hydroxide) is withdrawn from the catholyte compartment by means of withdrawal pipe 36. In using the anolyte recirculation method, the brine feed rate is greater than the rate at which the brine passes from the anolyte compartment 14 through the diaphragm 32 into the catholyte compartment 34. This excess brine may be withdrawn from the anolyte compartment 14 by means of passageway 12.
One means of adjusting the anolyte liquid level 22 is by raising or lowering overflow 26 within liquid level control means 20 by sliding overflow 26 through gasket means 21. Alternatively, adjustments can be made in the position of liquid intake 28 on overflow 26 by manual movements of overflow 26, by placing or removing tubular extensions on the top of overflow 26, by changing the level at which liquid flows into overflow 26 as by opening or closing a series of openings along the length of said overflow device as well as other methods which will be readily apparent to those skilled in the art from the disclosure herein. Thus, the anolyte liquid level 22 can be raised to within about half-inch or so of the top of the anolyte compartment of the chlor-alkali cell and lowered to the level of passageway 12. Such a change in anolyte liquid level 22 changes the hydrostatic pressure 3 within the cell and affects the flow of liquid through diaphragm 32. By these means, the flow of anolyte liquor through the diaphragm 32 can be regulated by changing anolyte liquid level 22. A higher liquid level 22 increases the hydrostatic pressure and, as such, increases the flow rate through the diaphragm.
Passageway 12 and overflow 26 are of a diameter suflicient to withdraw anolyte liquor at a rate approaching that at which brine is fed to the anolyte compartment. Since the brine is often fed to the anolyte compartment under pressure, and whereas the flow through the liquid withdrawal means is primarily by means of gravity, the diameter of passageway 12 and overflow 26 are preferably about equal to or larger than brine feed means 30. Normally, passageway 12 and overflow 26 have an inside cross-sectional area equal to about 1 to times the inside cross-sectional area of brine feed means 30. The anolyte liquor withdrawn from the cell by means of level control 20 is passed to manifold 42 for subsequent mixing with additional anolyte liquor from other cells prior to resaturation with salt and returning to the anolyte compartment of a cell for further reaction.
Passageway 12, level control means 20 and overflow 26 may be constructed of any material substantially inert to the conditions existing within the cell. Such conditions include operating temperatures within the range of about 90 to 110 degrees centigrade while in contact with a concentrated salt (NaCl) solution saturated with chlorine. In addition, such material of construction is preferably capable of withstanding chlorine attack at a pH in the range of about 1 to 7. The material selected is preferably, but not necessarily, electrically nonconductive to avoid loss of electrical current. It has been found, that various synthetic polymers, such as polyvinylidene chloride, afterchlorinated polyvinyl chloride, chlorinated polyesters, chlorinated rubbers, and the like materials can be used. Glass and ceramic and various metals, such as tantalum, titanium, and the like, can also be used as the anolyte level control apparatus.
Stand pipe 38 into which overflow 26 passes anolyte liquor, has sight glass 40 through which observations of the liquor being withdrawn from the anolyte compartment 14 and the flow rate thereof can be made.
The present invention provides a means for controlling the caustic soda concentration of the cell liquor produced in the catholyte compartment of the cell by regulating the caustic concentration, so that a more desirable salt to caustic ratio can be obtained. By changing the anolyte liquid level within the cell by means of the present invention, the hydrostatic pressure is changed, thus changing the residence time of the brine within the catholyte compartment due to a slower flow through the diaphragm. Thus, in addition to withdrawing anolyte liquor from the cell, the present apparatus coacts with the cell to produce a more desirable cell liquor.
As will be readily recognized by those skilled in the art, various modifications of the present apparatus can be made without departing from the spirit thereof. The particular shape and design of the liquid level control can be changed to meet the particular cell requirements and to provide for various other methods of changing the liquid level Within the cell.
While there have been described various embodiments of the pres ent invention, the apparatus described is not intended to be understood as limiting the scope of the invention, as it is realized that changes therein are possible. It is further intended that each element recited in any of the following claims is to be understood as referring to all equivalent elements for accomplishing substantially the same results in substantially the same or equivalent manner. It is intended 'to cover the invention broadly in whatever form its principles may be utilized.
What is claimed is:
1. In a chlor-alkali diaphragm cell comprising an anolyte compartment separated from a catholyte compartment by a porous diaphragm, said anolyte compartment comprising an anode, brine feed means and chlorine gas withdrawal means, the improvement which is anolyte liquor withdrawal means comprising a passageway having an inlet in communication with the anolyte compartment of said cell and an outlet external to the anolyte compartment, said outlet having liquid level control means in communication therewith which provides for controlled removal of anolyte from said anolyte compartment.
2. The apparatus of claim 1 wherein said liquid level control means has gaseous pressure equalizing means between upper portions of said control and said anolyte compartment.
3. The apparatus of claim 2 wherein said liquid level control means comprises a liquid retainer having positioned therein liquid overflow means.
4. The apparatus of claim 3 wherein the liquid level within said anolyte compartment is regulated by changing the level at which said overflow means withdraws liquids in said level control means.
5. The apparatus of claim 1 wherein sight means is provided in communication with said liquid level control means for the observation of liquid flow.
6. The apparatus of claim 4 wherein the liquid intake means of said overflow means in said liquid level control is vertically movable to change the liquid level in said anolyte compartment.
7. The apparatus of claim 1 wherein said liquid level control means is a liquid retainer having an adjustable liquid overflow therein and gaseous pressure equalizing means in communication with the anolyte compartment above the liquid level thereof.
References Cited UNITED STATES PATENTS 1,558,085 10/1925 Giordani et al. 204266 1,694,471 12/1928 Jacobi 137-577 XR 1,884,855 10/1932 Pryce l37247.5l 1,949,364 2/1934 Ball 137577 XR 2,867,213 1/1959 Thomas 137-559 XR 3,089,508 5/1963 Schulze et al. 137577 XR 1,361,905 12/1920 Ripley 137590 XR FOREIGN PATENTS 549,105 7/ 1956 Belgium.
78,313 6/1955 Netherlands.
HENRY T. KLINKSIEK, Primary Examiner.
U.S. Cl. X.R.
US51031765 1965-11-29 1965-11-29 Anolyte liquid level control for chlor-alkali diaphragm cells Expired - Lifetime US3418232A (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
NL136394D NL136394C (en) 1965-11-29
US51031765 US3418232A (en) 1965-11-29 1965-11-29 Anolyte liquid level control for chlor-alkali diaphragm cells
GB5301566A GB1174264A (en) 1965-11-29 1966-11-25 Operation of chlor-alkali cells and anolyte liquid level control.
SE1625466A SE331675B (en) 1965-11-29 1966-11-28
NL6616808A NL6616808A (en) 1965-11-29 1966-11-29
DE1966H0061128 DE1567963B2 (en) 1965-11-29 1966-11-29 METHOD OF OPERATING A CHLORAL CALIDIAPHRAGMA CELL WITH CONTINUOUS FLUSHING OF THE ANODE COMPARTMENT WITH FRESH BRINE
BE690427D BE690427A (en) 1965-11-29 1966-11-29
FR85425A FR1502407A (en) 1965-11-29 1966-11-29 Method and device for the operation of tanks intended for the production of chlorine and caustic alkali

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US51017965A 1965-11-29 1965-11-29
US510225A US3403083A (en) 1965-11-29 1965-11-29 Operation of chlor-alkali cells
US51031765 US3418232A (en) 1965-11-29 1965-11-29 Anolyte liquid level control for chlor-alkali diaphragm cells

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US3418232A true US3418232A (en) 1968-12-24

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US (1) US3418232A (en)
BE (1) BE690427A (en)
DE (1) DE1567963B2 (en)
FR (1) FR1502407A (en)
GB (1) GB1174264A (en)
NL (2) NL6616808A (en)
SE (1) SE331675B (en)

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US4032424A (en) * 1975-12-22 1977-06-28 Diamond Shamrock Corporation Electrical current breaker for fluid stream
US4149955A (en) * 1976-10-26 1979-04-17 Basf Wyandotte Corporation Feeding of brine to chlor-alkali cells
US4469554A (en) * 1983-04-05 1984-09-04 At&T Bell Laboratories Etch procedure for optical fibers
US4781894A (en) * 1987-03-09 1988-11-01 Wheaton Jeffrey C Control mechanism for delivery of gas product at constant pressure

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SU987997A1 (en) * 1981-05-07 1999-08-10 С.В. Голубков METHOD FOR OBTAINING A CONCENTRATED SOLUTION OF ALKALINE METAL AND CHLORINE HYDROXIDE

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US1694471A (en) * 1927-01-05 1928-12-11 Norbert J Jacobi Oil saver
US1949364A (en) * 1930-01-18 1934-02-27 Chain Belt Co Apparatus for supplying water to concrete mixers
US1884855A (en) * 1931-09-21 1932-10-25 Pryce Matthew Byrne Transparent trap
US2867213A (en) * 1957-06-12 1959-01-06 Jr Paul A Thomas Flutter valve for drainage of the pleural cavity
US3089508A (en) * 1958-10-10 1963-05-14 Culligan Inc Chemical solution tank and means for controlling chemical dosage

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3871484A (en) * 1973-08-02 1975-03-18 Henry A Thomas Oil mist lubrication and oil immersion system
US4032424A (en) * 1975-12-22 1977-06-28 Diamond Shamrock Corporation Electrical current breaker for fluid stream
US4149955A (en) * 1976-10-26 1979-04-17 Basf Wyandotte Corporation Feeding of brine to chlor-alkali cells
US4469554A (en) * 1983-04-05 1984-09-04 At&T Bell Laboratories Etch procedure for optical fibers
US4781894A (en) * 1987-03-09 1988-11-01 Wheaton Jeffrey C Control mechanism for delivery of gas product at constant pressure

Also Published As

Publication number Publication date
SE331675B (en) 1971-01-11
NL136394C (en) 1900-01-01
NL6616808A (en) 1967-05-30
BE690427A (en) 1967-05-29
DE1567963B2 (en) 1977-05-12
DE1567963A1 (en) 1970-09-03
GB1174264A (en) 1969-12-17
FR1502407A (en) 1967-11-18

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