US20080054361A1 - Method and apparatus for reducing flicker noise in a semiconductor device - Google Patents
Method and apparatus for reducing flicker noise in a semiconductor device Download PDFInfo
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- US20080054361A1 US20080054361A1 US11/619,255 US61925507A US2008054361A1 US 20080054361 A1 US20080054361 A1 US 20080054361A1 US 61925507 A US61925507 A US 61925507A US 2008054361 A1 US2008054361 A1 US 2008054361A1
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- H—ELECTRICITY
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- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/785—Field effect transistors with field effect produced by an insulated gate having a channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
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- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
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- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/77—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
- H01L21/78—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
- H01L21/82—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
- H01L21/84—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being other than a semiconductor body, e.g. being an insulating body
- H01L21/845—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being other than a semiconductor body, e.g. being an insulating body including field-effect transistors with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
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- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier
- H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body
- H01L27/1203—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body the substrate comprising an insulating body on a semiconductor body, e.g. SOI
- H01L27/1211—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body the substrate comprising an insulating body on a semiconductor body, e.g. SOI combined with field-effect transistors with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
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- H—ELECTRICITY
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- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66787—Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel
- H01L29/66795—Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
- H01L29/66803—Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET with a step of doping the vertical sidewall, e.g. using tilted or multi-angled implants
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
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- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/785—Field effect transistors with field effect produced by an insulated gate having a channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
- H01L29/7853—Field effect transistors with field effect produced by an insulated gate having a channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET the body having a non-rectangular crossection
- H01L29/7854—Field effect transistors with field effect produced by an insulated gate having a channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET the body having a non-rectangular crossection with rounded corners
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
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- H01L29/785—Field effect transistors with field effect produced by an insulated gate having a channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
- H01L29/7851—Field effect transistors with field effect produced by an insulated gate having a channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET with the body tied to the substrate
Definitions
- Embodiments described herein relate generally to semiconductor devices and more particularly, to field-effect transistors (FETs) and methods of fabricating the same.
- FETs field-effect transistors
- Flicker noise is a dominant noise source in metal oxide semiconductor field-effect transistor (MOSFET) devices at low frequencies.
- MOSFET metal oxide semiconductor field-effect transistor
- FIG. 1A-1E illustrate a sequence of cross-sectional drawings of a partially completed semiconductor wafer showing some embodiments of a method of fabrication of a semiconductor device having a dopant implanted into silicon fins.
- FIG. 2 is a flow chart showing some embodiments of a method of fabricating a FinFET.
- FIG. 3 illustrates a cross-sectional drawing of a partially completed semiconductor wafer showing some embodiment of a method of fabrication of a semiconductor device using a high-k material such as hafnium oxide and having a dopant implanted into fins.
- wafer and “substrate” may be used interchangeably to refer generally to any structure on which integrated circuits are formed and also to such structures during various stages of integrated circuit fabrication.
- substrate is understood to include a semiconductor wafer.
- substrate is also used to refer to semiconductor structures during processing and may include other layers that have been fabricated thereupon. Both “wafer” and “substrate” include doped and undoped semiconductors, epitaxial semiconductor layers supported by a base semiconductor or insulator, as well as other semiconductor structures well known to one skilled in the art.
- conductor is understood to generally include n-type and p-type semiconductors and the term “insulator” or “dielectric” is defined to include any material that is less electrically conductive than the materials referred to as “conductors.” The following detailed description is, therefore, not to be taken in a limiting sense.
- FIGS. 1A-1E illustrate a sequence of cross-sectional drawings of a partially completed semiconductor wafer 100 of some embodiments of a method of fabrication showing a dopant implanted into vertical silicon fins 102 A, 102 B, 102 C, and 102 D.
- Vertically positioned silicon fins 102 A-D are disposed and positioned vertically on a substrate 104 .
- the shape, height “h”, width “w” of each of the silicon fins 102 A-D and the spacing “s” between two consequent fins are dependant upon the characteristics of the device being fabricated.
- height “h” of the silicon fins 102 A-D falls within a range and is given by equation Lg min /2 ⁇ h ⁇ 1 ⁇ m, where, Lg min is the minimum gate length according to the technology used in a particular case.
- Lg min is the minimum gate length according to the technology used in a particular case.
- the height “h” determines the power consumption of single fin digital circuits such as logical gates or static random access memory (SRAMs).
- typical minimum gate lengths used are in the range of 45 nm to 65 nm, and hence, height “h” in some embodiments can be as small as 20 nm.
- the upper limit of height “h” is determined by the mechanical stability of the fins. Typically, the higher the fin the smaller the device area.
- the spacing “s” between the silicon fins 102 A-D falls within a range and is given by equation h/2 ⁇ s ⁇ 3 ⁇ m. Spacing “s” can be made larger, however, may be constrained by factors such as available device area, gate resistance, and parasitic gate capacitance.
- the thickness (or width) “w” of the silicon fins 102 A-D can be chosen according to the desired device characteristics. When a width “w” ⁇ 10 nm is used, a fully depleted device is provided with good sub-threshold characteristics and without floating-body effect. In some embodiments, where a larger thickness is used for silicon fins 102 A-D, it leads to a partially depleted device with reduced source and drain resistance and reduced flicker noise which is important for the performance of radio-frequency (RF) circuits.
- RF radio-frequency
- a reduction in the flicker noise is achieved when a larger thickness “w” is used. This is as a result of having the presence of different flicker noises corresponding to different surface features. Different flicker noise on different surface orientation is a result of different matching between silicon lattice of the fin and the gate insulator material at the surface. Surface direction is defined by the miller indices (e.g. (100)). In some embodiments, surfaces having surface directions (100), (010) and (001) show lowest flicker noise. In some embodiments, as a result of the use of plasma nitrided gate oxides, other surface directions also have been found to have low flicker noise.
- a particular surface direction has the lowest flicker noise for a certain carrier type (holes or electrons).
- the surface at the top of the fin can be different from the sidewalls.
- a MuGFET with a (100) top surface by drawing the fin with a 45° angle to the (010) surface can get a (011) surface for the sidewall conducting channels.
- Such different surface orientations are chosen to enhance mobility.
- a trade-off between mobility and flicker noise together with source and drain resistance is performed by choosing different contributions of top and sidewall surfaces. This can be achieved by increasing the thickness “w” of the fin.
- the signal can be increased by reducing the source-drain resistance and flicker noise is reduced by increasing the thickness of the fin. Consequently, the signal-to-noise ratio is increased due to the increase in signal and reduction in the flicker noise.
- flicker noise is surface roughness.
- the flicker noise is dependent on the different surface features such as surface roughness and surface orientation.
- side-walls 105 of silicon fins 102 A-D are usually of rougher surface than the surface of top 107 of silicon fins 102 A-D. This is as a result of fin etching that is described later in this specification.
- the smooth surface having a lattice arrangement (100) of top 107 , has lower flicker noise than a rough surface, characterized by a lattice orientation of (010) or (011), of side-walls 105 . Consequently, by choosing a larger thickness “w”, the amount of low flicker noise contributed by smooth surface (100) of 107 can be relatively increased in comparison to the high flicker noise contribution from sidewalls 105 .
- the thickness “w” is within the range of about 5 nm and about 30 nm. In some embodiments, the lower limit of about 5 nm for thickness “w” is essential to enable fluorine to be implanted in silicon fins 102 A-D. In general, a thickness “w” smaller than 5 nm is not preferable due to the increased drain and source resistance. In some embodiments, devices with a reduced drain and source resistance, a reduced flicker noise thickness “w” can range from about 30 nm to about 3 ⁇ m. Hence, by increasing the thickness “w” of the fin one can combine the advantage of lower flicker noise together with lower drain and source resistance which is advantageous for devices used in RF circuits.
- the reduced contribution to the total current in the sidewalls in this case can be compensated by using a surface orientation with higher mobility for the sidewalls.
- use of thickness “w” larger than 3 ⁇ m can lead to increased gate resistance and a parallel finger structure may be used to realize larger gate widths for finFET devices.
- silicon fins 102 A-D are approximately rectangular in shape. In some embodiments, strictly rectangular shaped silicon fins 102 A-D are avoided. Some other embodiments use rectangular-shaped silicon fins with the edges rounded that provides better electrical device performance.
- substrate 104 is a buried oxide layer. In other embodiments, substrate 104 is a bulk silicon layer.
- FIG. 1A is a cross-sectional view through a partially completed semiconductor wafer 100 having silicon fins 102 A-D being oxidized to form a screening oxide layer 106 on each of the silicon fins 102 A-D.
- screening oxide layer 106 includes silicon dioxide. Screening oxide layer 106 is grown over the silicon surface prior to a dopant implant process performed according to that shown in FIG. 1B . Screening oxide layer 106 provides protection against unintended knock-on metallic contaminants (such as iron (Fe) and Nickel (Ni)) received from the ion implanter.
- the thickness of the screening oxide layer can range from about 1 nm to about 15 nm. In some embodiments, the thickness of screening oxide would be around 3 nm.
- FIG. 1B is a cross-sectional view through the partially completed semiconductor wafer 100 shown in FIG. 1A showing an ion beam 108 enabling implantation of a dopant into silicon fins 102 A-D according to some embodiment of the invention.
- ion beam 108 is incident on silicon fins 102 A-D at an implantation angle “a” to the vertical axis of silicon fins 102 A-D.
- implantation could be either a dual mode or a quad mode operation.
- a dual-mode is an implant mode having two separate implantations performed on silicon fins 102 A-D using ion beam 108 . In this mode, semiconductor wafer 100 is first implanted with the dopant and then semiconductor wafer 100 is rotated by 180° about its vertical axis, following which another implantation is performed on the remaining channel area that was not implanted during the first implant.
- a quad-mode operation is an implant mode having four separate implantations performed on silicon fins 102 A-D using ion beam 108 .
- semiconductor wafer 100 is first implanted with dopant and then semiconductor wafer 100 is rotated by 90° about its vertical axis followed by an implantation with the dopant.
- the implantation mode continues with two more rotations by increments of 90°, each followed by a further implantation.
- the above-described method of rotating semiconductor wafer 100 in a dual-mode or a quad-mode is used to ensure all channel-forming surfaces of silicon fins 102 A-D are evenly implanted with the dopant.
- Fluorine is used as a dopant.
- other dopant materials such as Boron difluoride (BF2), Boron trifluoride (BF3), Chlorine, Hydrogen, Deuterium, Nitrogen, Argon, Xenon, Neon and Krypton are used.
- Argon is implanted to the backside of the wafer using and implant dose of around 2E18 atoms/cm 2 and implant energy below 1 keV.
- the implant energy of the dopant directed on silicon fins 102 A-D is distributed such that the peak concentration of impact distribution is on the center of the fins.
- the implant dose would range from around 1E15 atoms/cm 2 to about 5E16 atoms/cm 2 and the implant energy would range from around 10 keV to about 60 keV.
- the implant dose applied on silicon fins 102 A-D is selected to be lower than about 6E15 atoms/cm 2 and the implant energy is selected to be less than 20 keV.
- conventional methods use a higher implant energy and implant dose for fabrications having metal gates. Accordingly, in some embodiments, a higher implant energy and implant dose similar to that used in conventional methods can also be used for fabrications having metal gates.
- FIG. 1C illustrates a cross-sectional view through the partially fabricated semiconductor wafer 100 in FIG. 1B showing silicon fins 102 A-D after the removal of screening oxide 106 .
- screening oxide 106 is removed in some embodiments by a process of wet etching using Hydrogen fluoride (HF) acid or dry etching using HF vapor.
- HF Hydrogen fluoride
- a cleaning process is performed on silicon fins 102 A-D using ammonia hydrogen peroxide water. Cleaning of silicon fins 102 A-D using ammonia hydrogen peroxide water results in a decrease in flicker noise.
- an annealing process is performed to heal crystal damage in the fin from the implant.
- the thermal annealing process activates the dopant material within the silicon fins. If fluorine is used as dopant, there is no change in electrical conductivity. However, in the case where dopant materials used are implants such as B, P, and As some change in electrical conductivity will be realized as a result of the thermal annealing process.
- the anneal time and temperature depend on the desired characteristics of the semiconductor device being fabricated.
- crystal damage annealing can be one of a rapid thermal anneal (RTA) or a laser anneal.
- the anneal process has temperatures ranging from around 950° C. to about 1200° C. for a duration of about 1 to 60 seconds.
- a hydrogen (H 2 ) anneal is performed.
- This anneal provides smoothing of the corners and the rough sidewalls which are a result of etching the fin. This gives better electrical performance in terms of mobility and leakage current.
- the annealing temperature ranges from about 700° C. to 900° C. for about 1 to 10 minutes.
- the process steps described above is also performed after the H 2 anneal if the implant dose of a dopant such as fluorine is low.
- H 2 and fluorine compete with each other to quench gate insulator and interface traps. The lower binding energy of H 2 compared to fluorine leads to stronger increase of flicker noise under hot carrier stress.
- a wet HF dip followed by a cleaning using ammonia hydrogen peroxide water is used.
- a further HF vapor clean can be applied to remove low-quality native oxide.
- Low-quality native oxide grows relatively quick and is a problem in achieving very thin high-quality gate oxides.
- this cleaning is performed in the same chamber were the gate insulator oxidation is performed.
- FIG. 1D illustrates a cross-sectional view through the partially fabricated semiconductor wafer 100 in FIG. 1C showing the growth of a gate insulator layer 110 after the thermal annealing process performed above. Following this a final post oxidation anneal is performed to distribute the dopant to the gate insulator silicon interface and into the gate insulator to quench interface and gate insulator traps.
- post-oxidation anneal by itself already leads to reduced flicker noise for gate insulators grown at lower temperatures as it is the case for thin oxides of newer technologies due to the release of mechanical stress between the fin and the gate insulator.
- post oxidation anneal is performed in the temperature range from about 950C to about 1200C for a time period between about 1 second to about 20 seconds.
- the gate insulator includes at least one of an oxide, a nitride, nitrided silicon oxide and hafnium oxide or any dielectric with high dielectric constant (k).
- the gate insulator thickness ranges from about 15 nm down to about 0.5 nm. Smaller thicknesses could lead to higher gate leakage currents and larger thicknesses could require gate voltages above 5 V. Neither of these scenarios are desirable and hence not used in battery-driven systems.
- the generation of gate insulator layer 110 can provide the anneal temperature for diffusion of the fluorine.
- the diffusion of fluorine flows from the silicon fins 102 A-D to the gate insulator-fin interface 111 and into the gate insulator layer 110 .
- this gate insulator layer 110 generation process is followed by a further post oxidation anneal.
- this anneal is the source or drain junction anneal. That anneal provides the full diffusion of the fluorine as described above, due to the high diffusivity of fluorine in single crystal silicon and also due to the strong attraction of fluorine by the dangling bonds of the gate-insulator-silicon-fin interface.
- FIG. 1E illustrates a cross-sectional view through the partially fabricated semiconductor wafer 100 in FIG. 1D showing the inclusion of a gate stack 112 for a finFET or Multi-Gate transistor.
- gate stack 112 may include at least one of a poly silicon gate, a fully silicided (FUSI) gate and a metal gate.
- FIG. 2 is a flow diagram 200 showing some embodiments of a method of fabricating a finFET.
- the method proceeds by performing oxidation of silicon fins 102 A-D that are vertically disposed on substrate 104 is performed thereby generating a screening oxide layer 106 .
- the method proceeds by implanting fluorine into silicon fins 102 A-D. As described earlier, the implantation can be either of a dual mode (at 180°) or a quad mode (at 90°).
- the capability of adjusting implantation angle “a” to achieve an optimum implant provides an added advantage over conventional methods such as plasma fluoridation of the gate insulator in finFETs or Multi-gate FETs where the option of adjusting the implantation angle “a” is not available.
- the method proceeds by removing screening oxide layer 106 from silicon fins 102 A-D.
- Removal of screening oxide layer 106 from silicon fins 102 A-D may include the process of wet-etching using HF acid as well as cleaning using ammonia hydrogen peroxide water.
- the method proceeds by annealing silicon fins 102 A-D.
- Annealing of silicon fins 120 A-D enables the healing of crystal lattice damage.
- the healing of crystal lattice damage through annealing is followed by a H 2 anneal process.
- the H 2 anneal process is followed by a wet HF dip.
- the wet HF dip is followed by a cleaning using ammonia hydrogen peroxide water.
- the method continues by performing a HF vapor cleaning in the same chamber were gate oxidation is performed.
- the method proceeds by generating a gate insulator layer 110 over the silicon fins 102 A-D.
- a post oxidation anneal is provided in 212 .
- the method proceeds by performing post-oxidation annealing of the semiconductor wafer 100 to distribute fluorine into gate insulator. In some embodiments, 212 is optional.
- CMOS complementary metal oxide semiconductor
- LNA low-noise amplifiers
- VCO voltage-controlled oscillators
- metal gates provide low diffusivity towards dopants such as fluorine and consequently implantation of fluorine into gate insulators is prohibited using conventional methods.
- the method described in flow diagram FIG. 2 allows semiconductor wafers having metal gates to be implanted with dopants.
- the material of metal gate includes at least one of Titanium Nitride (TiN) and Tantalum Nitride (TaN).
- TiN Titanium Nitride
- TaN Tantalum Nitride
- embodiments of the method disclosed above alleviates the problem arising from implantation of fluorine in the drain and source regions due to the reduced implant dose and energy required for the described process compared to conventional methods.
- Implantation of fluorine in the drain and source regions with a high dose after gate insulator growth and prior to the source/drain anneal step has the disadvantage of increasing junction capacitance (in bulk CMOS) and increasing dramatically junction leakage current.
- embodiments of the disclosed method avoid creation of increased diffusion capacitance that reduces the RF figure of merit maximum oscillation frequency (fmax).
- embodiments of the disclosed method prevent high junction leakage that increases standby power consumption which is an important drawback for battery-driven systems.
- embodiments of the method described in FIG. 2 can be applied to semiconductor wafers utilizing hafnium oxide.
- the hafnium oxide contains various compositions of hafnium, silicon, oxygen and nitrogen.
- FIG. 3 illustrates a cross-sectional drawing of the partially completed semiconductor wafer 100 showing some embodiments of a method of fabrication of a semiconductor device having a material with a high dielectric constant (a “high-k dielectric” material) and having a dopant implanted into the fins.
- the order of layers formed start from fin 102 .
- Fin 102 is followed by a support layer 302 .
- Support layer 302 contains almost none or very low concentration of hafnium.
- support layer 302 is formed using silicon oxide.
- support layer 302 is formed using nitrided silicon oxide.
- Support layer 302 is followed by a high-k dielectric material layer 304 as shown in FIG. 3 .
- layer 304 comprises a material having a high-k material.
- high-k materials include selected oxides and silicates of zirconium (Zr) and hafnium (Hf).
- Other suitable high-k materials for layer 304 may also include, for example, Al 2 O 3 , Gd 2 O 3 , Yb 2 O 3 , Dy 2 O 3 , Nb 2 O 5 , Y 2 O 3 , La 2 O 3 , TiO 2 , Ta 2 O 5 , SrTiO 3 , Ba x Sr 1-x TiO 3 , Zr x Si 1-x O y , Hf x Si 1-x O y and Al x Zr 1-x O 2 , as well as other compounds.
- layer 304 comprises a material such as a hafnium-enriched silicon oxide or nitrided silicon oxide.
- the hafnium concentration at the interface between the gate insulating layer and fin interface is low.
- the gate insulator stack is generated using one of two process sequences namely (1) pre-oxidation process and (2) post-oxidation process of hafnium-free silicon oxide interface layer or hafnium-free nitrided silicon oxide interface layer.
- the pre-oxidation process mentioned above involves the formation of silicon oxide interface layer by using thermal oxidation.
- the silicon oxide interface layer may be nitrided.
- Use of nitrided silicon oxide can lead to higher flicker noise compared to pure silicon oxide depending on the nitridation process. Consequently, in some embodiments, plasma nitridation is performed.
- post oxidation of thermal nitrided silicon oxide is performed. Following which, a hafnium-containing silicon gate oxide layer is formed.
- MOCVD metal-organic vapor deposition
- the post-oxidation process mentioned above involves the sequence of generating a hafnium containing portion of the gate insulator followed by a hafnium-free silicon oxide (or nitrided silicon oxide) interface layer that is generated by thermal oxidation.
- the nearly hafnium free oxide interface layer is between about 0.1 nm and about 1.0 nm thick. In some embodiments, the nearly hafnium free oxide interface layer has a thickness between about 0.1 nm and about half the thickness of the gate insulator.
- the method of incorporating fluorine into the silicon oxide interfacial layer is not limited to embodiments having a hafnium-containing gate stack but can also be applied to embodiments having any kind of gate insulator with a high dielectric constant (k) having a silicon or nitrided silicon oxide interface layer present.
- inventive subject matter may be referred to herein, individually and/or collectively, by the term “invention” merely for convenience and without intending to voluntarily limit the scope of this application to any single invention or inventive concept if more than one is in fact disclosed.
- inventive concept merely for convenience and without intending to voluntarily limit the scope of this application to any single invention or inventive concept if more than one is in fact disclosed.
- inventive subject matter is intended to cover any and all adaptations or variations of various embodiments. Combinations of the above embodiments, and other embodiments not specifically described herein, will be apparent to those of skill in the art upon reviewing the above description.
- the terms “including” and “comprising” are used in an open-ended fashion, and thus should be interpreted to mean “including, but not limited to . . . ”.
Abstract
Some embodiments discussed relate to an integrated circuit and methods for making it, comprises a semiconductor substrate and a plurality of fins disposed on the semiconductor substrate and a gate insulator disposed on the plurality of fins and a gate stack disposed on the gate insulator and the plurality of fins are implanted by a dopant.
Description
- This patent application claims the benefit of priority, under 35 U.S.C. Section 119(e), to U.S. Provisional Patent Application No. 60/813,630, filed on Aug. 30, 2006, which is incorporated herein by reference.
- Embodiments described herein relate generally to semiconductor devices and more particularly, to field-effect transistors (FETs) and methods of fabricating the same.
- Flicker noise is a dominant noise source in metal oxide semiconductor field-effect transistor (MOSFET) devices at low frequencies. In battery-driven circuits where signal-to-noise ratio cannot be improved at the cost of power consumption, a reduction of flicker noise is desired.
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FIG. 1A-1E illustrate a sequence of cross-sectional drawings of a partially completed semiconductor wafer showing some embodiments of a method of fabrication of a semiconductor device having a dopant implanted into silicon fins. -
FIG. 2 is a flow chart showing some embodiments of a method of fabricating a FinFET. -
FIG. 3 illustrates a cross-sectional drawing of a partially completed semiconductor wafer showing some embodiment of a method of fabrication of a semiconductor device using a high-k material such as hafnium oxide and having a dopant implanted into fins. - The following detailed description refers to the accompanying drawings that show, by way of illustration, specific details and embodiments in which the invention may be practiced. These embodiments are described in sufficient detail to enable those skilled in the art to practice the invention. Other embodiments may be utilized and structural, logical, and electrical changes may be made without departing from the scope of the invention. The various embodiments are not necessarily mutually exclusive, as some embodiments can be combined with one or more other embodiments to form new embodiments.
- In the following description, the terms “wafer” and “substrate” may be used interchangeably to refer generally to any structure on which integrated circuits are formed and also to such structures during various stages of integrated circuit fabrication. The term “substrate” is understood to include a semiconductor wafer. The term “substrate” is also used to refer to semiconductor structures during processing and may include other layers that have been fabricated thereupon. Both “wafer” and “substrate” include doped and undoped semiconductors, epitaxial semiconductor layers supported by a base semiconductor or insulator, as well as other semiconductor structures well known to one skilled in the art.
- The term “conductor” is understood to generally include n-type and p-type semiconductors and the term “insulator” or “dielectric” is defined to include any material that is less electrically conductive than the materials referred to as “conductors.” The following detailed description is, therefore, not to be taken in a limiting sense.
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FIGS. 1A-1E illustrate a sequence of cross-sectional drawings of a partially completedsemiconductor wafer 100 of some embodiments of a method of fabrication showing a dopant implanted intovertical silicon fins silicon fins 102A-D are disposed and positioned vertically on asubstrate 104. The shape, height “h”, width “w” of each of the silicon fins 102A-D and the spacing “s” between two consequent fins are dependant upon the characteristics of the device being fabricated. - In some embodiments, height “h” of the
silicon fins 102A-D falls within a range and is given by equation Lgmin/2≦h≦1 μm, where, Lgmin is the minimum gate length according to the technology used in a particular case. The rationale for this is that the height “h” determines the power consumption of single fin digital circuits such as logical gates or static random access memory (SRAMs). Given that, in some embodiments, typical minimum gate lengths used are in the range of 45 nm to 65 nm, and hence, height “h” in some embodiments can be as small as 20 nm. The upper limit of height “h” is determined by the mechanical stability of the fins. Typically, the higher the fin the smaller the device area. - In some embodiments, the spacing “s” between the silicon fins 102A-D falls within a range and is given by equation h/2≦s≦3 μm. Spacing “s” can be made larger, however, may be constrained by factors such as available device area, gate resistance, and parasitic gate capacitance.
- In some embodiments, the thickness (or width) “w” of the
silicon fins 102A-D can be chosen according to the desired device characteristics. When a width “w” ≦10 nm is used, a fully depleted device is provided with good sub-threshold characteristics and without floating-body effect. In some embodiments, where a larger thickness is used forsilicon fins 102A-D, it leads to a partially depleted device with reduced source and drain resistance and reduced flicker noise which is important for the performance of radio-frequency (RF) circuits. - In some embodiments, a reduction in the flicker noise is achieved when a larger thickness “w” is used. This is as a result of having the presence of different flicker noises corresponding to different surface features. Different flicker noise on different surface orientation is a result of different matching between silicon lattice of the fin and the gate insulator material at the surface. Surface direction is defined by the miller indices (e.g. (100)). In some embodiments, surfaces having surface directions (100), (010) and (001) show lowest flicker noise. In some embodiments, as a result of the use of plasma nitrided gate oxides, other surface directions also have been found to have low flicker noise. In general, for a certain process a particular surface direction has the lowest flicker noise for a certain carrier type (holes or electrons). For example, in MuGFETs, the surface at the top of the fin can be different from the sidewalls. A MuGFET with a (100) top surface by drawing the fin with a 45° angle to the (010) surface can get a (011) surface for the sidewall conducting channels. Such different surface orientations are chosen to enhance mobility. A trade-off between mobility and flicker noise together with source and drain resistance is performed by choosing different contributions of top and sidewall surfaces. This can be achieved by increasing the thickness “w” of the fin. Thus, the signal can be increased by reducing the source-drain resistance and flicker noise is reduced by increasing the thickness of the fin. Consequently, the signal-to-noise ratio is increased due to the increase in signal and reduction in the flicker noise.
- Another effect that influences flicker noise is surface roughness. In general, the flicker noise is dependent on the different surface features such as surface roughness and surface orientation. In some embodiments, side-
walls 105 of silicon fins 102A-D are usually of rougher surface than the surface oftop 107 of silicon fins 102A-D. This is as a result of fin etching that is described later in this specification. - The smooth surface, having a lattice arrangement (100) of
top 107, has lower flicker noise than a rough surface, characterized by a lattice orientation of (010) or (011), of side-walls 105. Consequently, by choosing a larger thickness “w”, the amount of low flicker noise contributed by smooth surface (100) of 107 can be relatively increased in comparison to the high flicker noise contribution fromsidewalls 105. - In some embodiments having fully depleted devices, the thickness “w” is within the range of about 5 nm and about 30 nm. In some embodiments, the lower limit of about 5 nm for thickness “w” is essential to enable fluorine to be implanted in
silicon fins 102A-D. In general, a thickness “w” smaller than 5 nm is not preferable due to the increased drain and source resistance. In some embodiments, devices with a reduced drain and source resistance, a reduced flicker noise thickness “w” can range from about 30 nm to about 3 μm. Hence, by increasing the thickness “w” of the fin one can combine the advantage of lower flicker noise together with lower drain and source resistance which is advantageous for devices used in RF circuits. In some embodiments, the reduced contribution to the total current in the sidewalls in this case can be compensated by using a surface orientation with higher mobility for the sidewalls. In some embodiments, use of thickness “w” larger than 3 μm can lead to increased gate resistance and a parallel finger structure may be used to realize larger gate widths for finFET devices. - In the embodiments shown in
FIGS. 1A-1E and FIG-2,silicon fins 102A-D are approximately rectangular in shape. In some embodiments, strictly rectangular shapedsilicon fins 102A-D are avoided. Some other embodiments use rectangular-shaped silicon fins with the edges rounded that provides better electrical device performance. - In some embodiments,
substrate 104 is a buried oxide layer. In other embodiments,substrate 104 is a bulk silicon layer. -
FIG. 1A is a cross-sectional view through a partially completedsemiconductor wafer 100 havingsilicon fins 102A-D being oxidized to form ascreening oxide layer 106 on each of thesilicon fins 102A-D. In some embodiments,screening oxide layer 106 includes silicon dioxide.Screening oxide layer 106 is grown over the silicon surface prior to a dopant implant process performed according to that shown inFIG. 1B .Screening oxide layer 106 provides protection against unintended knock-on metallic contaminants (such as iron (Fe) and Nickel (Ni)) received from the ion implanter. In some embodiments, the thickness of the screening oxide layer can range from about 1 nm to about 15 nm. In some embodiments, the thickness of screening oxide would be around 3 nm. -
FIG. 1B is a cross-sectional view through the partially completedsemiconductor wafer 100 shown inFIG. 1A showing anion beam 108 enabling implantation of a dopant intosilicon fins 102A-D according to some embodiment of the invention. In some embodiments,ion beam 108 is incident onsilicon fins 102A-D at an implantation angle “a” to the vertical axis ofsilicon fins 102A-D. Implantation angle “a” is selected according to fin spacing “s” and height “h” and is determined by the equation tan(a)=s/h. - In some embodiments, implantation could be either a dual mode or a quad mode operation. A dual-mode is an implant mode having two separate implantations performed on
silicon fins 102A-D usingion beam 108. In this mode,semiconductor wafer 100 is first implanted with the dopant and thensemiconductor wafer 100 is rotated by 180° about its vertical axis, following which another implantation is performed on the remaining channel area that was not implanted during the first implant. A quad-mode operation is an implant mode having four separate implantations performed onsilicon fins 102A-D usingion beam 108. In embodiments according to this mode,semiconductor wafer 100 is first implanted with dopant and thensemiconductor wafer 100 is rotated by 90° about its vertical axis followed by an implantation with the dopant. The implantation mode continues with two more rotations by increments of 90°, each followed by a further implantation. The above-described method ofrotating semiconductor wafer 100 in a dual-mode or a quad-mode is used to ensure all channel-forming surfaces ofsilicon fins 102A-D are evenly implanted with the dopant. - In some embodiments, Fluorine is used as a dopant. In some embodiments, other dopant materials such as Boron difluoride (BF2), Boron trifluoride (BF3), Chlorine, Hydrogen, Deuterium, Nitrogen, Argon, Xenon, Neon and Krypton are used. In conventional methods Argon is implanted to the backside of the wafer using and implant dose of around 2E18 atoms/cm2 and implant energy below 1 keV.
- In some embodiments, the implant energy of the dopant directed on
silicon fins 102A-D is distributed such that the peak concentration of impact distribution is on the center of the fins. In some embodiments, the implant dose would range from around 1E15 atoms/cm2 to about 5E16 atoms/cm2 and the implant energy would range from around 10 keV to about 60 keV. In some embodiments, while using the dopants to achieve flicker noise reduction, there is a starting threshold dose and a saturating dose of the dopant (e.g., Fluorine) beyond which no more improvement in flicker noise reduction is achievable. - In some embodiments, the implant dose applied on
silicon fins 102A-D is selected to be lower than about 6E15 atoms/cm2 and the implant energy is selected to be less than 20 keV. On the contrary, conventional methods use a higher implant energy and implant dose for fabrications having metal gates. Accordingly, in some embodiments, a higher implant energy and implant dose similar to that used in conventional methods can also be used for fabrications having metal gates. -
FIG. 1C illustrates a cross-sectional view through the partially fabricatedsemiconductor wafer 100 inFIG. 1B showingsilicon fins 102A-D after the removal ofscreening oxide 106. In some embodiments,screening oxide 106 is removed in some embodiments by a process of wet etching using Hydrogen fluoride (HF) acid or dry etching using HF vapor. In some embodiments, a cleaning process is performed onsilicon fins 102A-D using ammonia hydrogen peroxide water. Cleaning ofsilicon fins 102A-D using ammonia hydrogen peroxide water results in a decrease in flicker noise. Following the cleaning ofsilicon fins 102A-D, in some embodiments, an annealing process is performed to heal crystal damage in the fin from the implant. Additionally, in some embodiments, the thermal annealing process activates the dopant material within the silicon fins. If fluorine is used as dopant, there is no change in electrical conductivity. However, in the case where dopant materials used are implants such as B, P, and As some change in electrical conductivity will be realized as a result of the thermal annealing process. The anneal time and temperature depend on the desired characteristics of the semiconductor device being fabricated. In some embodiments, crystal damage annealing can be one of a rapid thermal anneal (RTA) or a laser anneal. In some embodiments, the anneal process has temperatures ranging from around 950° C. to about 1200° C. for a duration of about 1 to 60 seconds. - Following the crystal damage anneal performed above, a hydrogen (H2) anneal is performed. This anneal provides smoothing of the corners and the rough sidewalls which are a result of etching the fin. This gives better electrical performance in terms of mobility and leakage current. For MOSFETs in general and especially for finFETs it has been shown that annealing in a H2 ambient reduces flicker noise. In some embodiments the annealing temperature ranges from about 700° C. to 900° C. for about 1 to 10 minutes. In some embodiments, the process steps described above is also performed after the H2 anneal if the implant dose of a dopant such as fluorine is low. In general, H2 and fluorine compete with each other to quench gate insulator and interface traps. The lower binding energy of H2 compared to fluorine leads to stronger increase of flicker noise under hot carrier stress.
- Following the H2 anneal performed above a wet HF dip followed by a cleaning using ammonia hydrogen peroxide water is used. After the cleaning step a further HF vapor clean can be applied to remove low-quality native oxide. Low-quality native oxide grows relatively quick and is a problem in achieving very thin high-quality gate oxides. In some embodiments, this cleaning is performed in the same chamber were the gate insulator oxidation is performed.
-
FIG. 1D illustrates a cross-sectional view through the partially fabricatedsemiconductor wafer 100 inFIG. 1C showing the growth of agate insulator layer 110 after the thermal annealing process performed above. Following this a final post oxidation anneal is performed to distribute the dopant to the gate insulator silicon interface and into the gate insulator to quench interface and gate insulator traps. In some embodiments, post-oxidation anneal by itself already leads to reduced flicker noise for gate insulators grown at lower temperatures as it is the case for thin oxides of newer technologies due to the release of mechanical stress between the fin and the gate insulator. Typically, post oxidation anneal is performed in the temperature range from about 950C to about 1200C for a time period between about 1 second to about 20 seconds. In some embodiments, the gate insulator includes at least one of an oxide, a nitride, nitrided silicon oxide and hafnium oxide or any dielectric with high dielectric constant (k). In some embodiments, the gate insulator thickness ranges from about 15 nm down to about 0.5 nm. Smaller thicknesses could lead to higher gate leakage currents and larger thicknesses could require gate voltages above 5 V. Neither of these scenarios are desirable and hence not used in battery-driven systems. - In some embodiments, the generation of
gate insulator layer 110 can provide the anneal temperature for diffusion of the fluorine. The diffusion of fluorine flows from thesilicon fins 102A-D to the gate insulator-fin interface 111 and into thegate insulator layer 110. In some embodiments, thisgate insulator layer 110 generation process is followed by a further post oxidation anneal. In some embodiments, this anneal is the source or drain junction anneal. That anneal provides the full diffusion of the fluorine as described above, due to the high diffusivity of fluorine in single crystal silicon and also due to the strong attraction of fluorine by the dangling bonds of the gate-insulator-silicon-fin interface. -
FIG. 1E illustrates a cross-sectional view through the partially fabricatedsemiconductor wafer 100 inFIG. 1D showing the inclusion of agate stack 112 for a finFET or Multi-Gate transistor. In some embodiments,gate stack 112 may include at least one of a poly silicon gate, a fully silicided (FUSI) gate and a metal gate. -
FIG. 2 is a flow diagram 200 showing some embodiments of a method of fabricating a finFET. In 202, the method proceeds by performing oxidation ofsilicon fins 102A-D that are vertically disposed onsubstrate 104 is performed thereby generating ascreening oxide layer 106. In 204, the method proceeds by implanting fluorine intosilicon fins 102A-D. As described earlier, the implantation can be either of a dual mode (at 180°) or a quad mode (at 90°). Additionally, the capability of adjusting implantation angle “a” to achieve an optimum implant provides an added advantage over conventional methods such as plasma fluoridation of the gate insulator in finFETs or Multi-gate FETs where the option of adjusting the implantation angle “a” is not available. - In 206, the method proceeds by removing
screening oxide layer 106 fromsilicon fins 102A-D. Removal ofscreening oxide layer 106 fromsilicon fins 102A-D may include the process of wet-etching using HF acid as well as cleaning using ammonia hydrogen peroxide water. - In 208, the method proceeds by annealing
silicon fins 102A-D. Annealing of silicon fins 120A-D enables the healing of crystal lattice damage. In some embodiments, the healing of crystal lattice damage through annealing is followed by a H2 anneal process. In some embodiments, the H2 anneal process is followed by a wet HF dip. In some embodiments, the wet HF dip is followed by a cleaning using ammonia hydrogen peroxide water. In some embodiments, the method continues by performing a HF vapor cleaning in the same chamber were gate oxidation is performed. - In 210, the method proceeds by generating a
gate insulator layer 110 over thesilicon fins 102A-D. As described earlier, in some embodiments, following the formation of agate insulator layer 110, a post oxidation anneal is provided in 212. In 212, the method proceeds by performing post-oxidation annealing of thesemiconductor wafer 100 to distribute fluorine into gate insulator. In some embodiments, 212 is optional. - The above described method of implanting fluorine has several advantages over conventional methods of implanting dopants into gate stacks. In some embodiments, as described earlier other dopants such as Boron difluoride (BF2), Boron trifluoride (BF3), Chlorine, Hydrogen, Deuterium, Nitrogen, Argon, Xenon, Neon, or Krypton may be used. The method described in flow diagram
FIG. 2 reduces the flicker noise of the device being fabricated. Flicker noise is a design constraint that limits complimentary metal oxide semiconductor (CMOS) RF and analog circuit performance with respect to signal-to-noise ratio in low-noise amplifiers (LNA), noise contribution of direct down conversion mixers and phase noise of voltage-controlled oscillators (VCO). - In some embodiments, metal gates provide low diffusivity towards dopants such as fluorine and consequently implantation of fluorine into gate insulators is prohibited using conventional methods. The method described in flow diagram
FIG. 2 allows semiconductor wafers having metal gates to be implanted with dopants. In some embodiments, the material of metal gate includes at least one of Titanium Nitride (TiN) and Tantalum Nitride (TaN). The advantage of embodiments of the method described herein is that it can be used in semiconductor devices irrespective of the gate stack material since the implantation is performed before the gate stack is formed during the fabrication process. - Additionally, embodiments of the method disclosed above alleviates the problem arising from implantation of fluorine in the drain and source regions due to the reduced implant dose and energy required for the described process compared to conventional methods. Implantation of fluorine in the drain and source regions with a high dose after gate insulator growth and prior to the source/drain anneal step has the disadvantage of increasing junction capacitance (in bulk CMOS) and increasing dramatically junction leakage current. Moreover, embodiments of the disclosed method avoid creation of increased diffusion capacitance that reduces the RF figure of merit maximum oscillation frequency (fmax). Furthermore, embodiments of the disclosed method prevent high junction leakage that increases standby power consumption which is an important drawback for battery-driven systems.
- Conventional methods of implanting fluorine in polysilicon gates of PMOS transistors exhibit strong co-diffusion of boron from the boron-doped poly silicon gate through the gate oxide into the n-well of a bulk CMOS device. Due to this boron diffusion an unwanted reduction of threshold voltage occurs. However, implanting of fluorine into buried oxide of a silicon-on-insulator (SOI) wafer could avoid some of the disadvantages of implanting it into the gate stack. Such an approach is inefficient because fluorine gets incorporated at the silicon oxide interface (“fluorine pile-up” in secondary-ion mass spectrometry (SIMS) profiling) of two interfaces exist above and below the buried oxide. Consequently, a high dose and high energy implant of the dopant is needed while using embodiments of the present methods. Furthermore, plasma fluoridation is difficult to apply to finFETs and Multi-gate FETs due to the vertical structure of the fins. Embodiments of the method described herein avoid some difficulties encountered with conventional methods, as described above.
- Furthermore, embodiments of the method described in
FIG. 2 can be applied to semiconductor wafers utilizing hafnium oxide. In some embodiments, the hafnium oxide contains various compositions of hafnium, silicon, oxygen and nitrogen. -
FIG. 3 illustrates a cross-sectional drawing of the partially completedsemiconductor wafer 100 showing some embodiments of a method of fabrication of a semiconductor device having a material with a high dielectric constant (a “high-k dielectric” material) and having a dopant implanted into the fins. The order of layers formed start fromfin 102.Fin 102 is followed by asupport layer 302.Support layer 302 contains almost none or very low concentration of hafnium. In some embodiments,support layer 302 is formed using silicon oxide. In some embodiments,support layer 302 is formed using nitrided silicon oxide.Support layer 302 is followed by a high-kdielectric material layer 304 as shown inFIG. 3 . In some embodiments,layer 304 comprises a material having a high-k material. Examples of such high-k materials include selected oxides and silicates of zirconium (Zr) and hafnium (Hf). Other suitable high-k materials forlayer 304 may also include, for example, Al2O3, Gd2O3, Yb2O3, Dy2O3, Nb2O5, Y2O3, La2O3, TiO2, Ta2O5, SrTiO3, BaxSr1-xTiO3, ZrxSi1-xOy, HfxSi1-xOy and AlxZr1-xO2, as well as other compounds. In some embodiments,layer 304 comprises a material such as a hafnium-enriched silicon oxide or nitrided silicon oxide. In such embodiments, the hafnium concentration at the interface between the gate insulating layer and fin interface is low. In some embodiments, the gate insulator stack is generated using one of two process sequences namely (1) pre-oxidation process and (2) post-oxidation process of hafnium-free silicon oxide interface layer or hafnium-free nitrided silicon oxide interface layer. - The pre-oxidation process mentioned above involves the formation of silicon oxide interface layer by using thermal oxidation. In some embodiments, the silicon oxide interface layer may be nitrided. Use of nitrided silicon oxide can lead to higher flicker noise compared to pure silicon oxide depending on the nitridation process. Consequently, in some embodiments, plasma nitridation is performed. In some embodiments, post oxidation of thermal nitrided silicon oxide is performed. Following which, a hafnium-containing silicon gate oxide layer is formed. This is performed in low temperature using a metal-organic vapor deposition (MOCVD) technique and the diffusion of fluorine into the hafnium-containing portion of the gate insulator is avoided and as a result the wastage of fluorine in the fin is avoided.
- The post-oxidation process mentioned above involves the sequence of generating a hafnium containing portion of the gate insulator followed by a hafnium-free silicon oxide (or nitrided silicon oxide) interface layer that is generated by thermal oxidation. In some embodiments, the nearly hafnium free oxide interface layer is between about 0.1 nm and about 1.0 nm thick. In some embodiments, the nearly hafnium free oxide interface layer has a thickness between about 0.1 nm and about half the thickness of the gate insulator.
- The method of incorporating fluorine into the silicon oxide interfacial layer is not limited to embodiments having a hafnium-containing gate stack but can also be applied to embodiments having any kind of gate insulator with a high dielectric constant (k) having a silicon or nitrided silicon oxide interface layer present.
- It should be noted that the methods described herein do not have to be executed in the order described, or in any particular order, unless it is otherwise specified that a particular order is required. Moreover, unless otherwise specified, various activities described with respect to the methods identified herein can be executed in repetitive, simultaneous, serial, or parallel fashion.
- The accompanying drawings that form a part hereof show by way of illustration, and not of limitation, specific embodiments in which the subject matter may be practiced. The embodiments illustrated are described in sufficient detail to enable those skilled in the art to practice the teachings disclosed herein. Other embodiments may be utilized and derived therefrom, such that structural and logical substitutions and changes may be made without departing from the scope of this disclosure. This Detailed Description, therefore, is not to be taken in a limiting sense, and the scope of various embodiments is defined only by the appended claims, along with the full range of equivalents to which such claims are entitled.
- Such embodiments of the inventive subject matter may be referred to herein, individually and/or collectively, by the term “invention” merely for convenience and without intending to voluntarily limit the scope of this application to any single invention or inventive concept if more than one is in fact disclosed. Thus, although specific embodiments have been illustrated and described herein, it should be appreciated that any arrangement calculated to achieve the same purpose may be substituted for the specific embodiments shown. This disclosure is intended to cover any and all adaptations or variations of various embodiments. Combinations of the above embodiments, and other embodiments not specifically described herein, will be apparent to those of skill in the art upon reviewing the above description. In the previous discussion and in the claims, the terms “including” and “comprising” are used in an open-ended fashion, and thus should be interpreted to mean “including, but not limited to . . . ”.
- The Abstract of the Disclosure is provided to comply with 37 C.F.R. §1.72(b), requiring an abstract that will allow the reader to quickly ascertain the nature of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. In addition, in the foregoing Detailed Description, it can be seen that various features are grouped together in a single embodiment for the purpose of streamlining the disclosure. This method of disclosure is not to be interpreted as reflecting an intention that the claimed embodiments require more features than are expressly recited in each claim. Rather, as the following claims reflect, inventive subject matter lies in less than all features of a single disclosed embodiment. Thus the following claims are hereby incorporated into the Detailed Description, with each claim standing on its own as a separate embodiment.
Claims (32)
1. An integrated circuit, comprising:
a semiconductor substrate;
a plurality of fins disposed on the semiconductor substrate, wherein the plurality of fins are implanted by a dopant;
a gate insulator disposed on the plurality of fins; and
a gate stack disposed on the gate insulator.
2. The integrated circuit of claim 1 , wherein the dopant comprises at least one of the group of materials consisting of Fluorine, Boron difluoride, Boron trifluoride, Chlorine, Hydrogen, Deuterium, Nitrogen, Argon, Xenon, Neon, and Krypton.
3. The integrated circuit of claim 2 , wherein the plurality of fins further comprises a high-k material and a supporting layer adapted to receive the dopant.
4. The integrated circuit of claim 3 , wherein the supporting layer comprises at least one of the group of materials consisting of silicon oxide and nitrided silicon dioxide.
5. The integrated circuit of claim 2 , wherein the gate stack includes at least one of a poly silicon gate, a fully silicided gate and a metal gate.
6. The integrated circuit of claim 2 , wherein the gate insulator comprises at least one of the group of materials consisting of an oxide, a nitride, a nitrided silicon oxide and a high-k dielectric material.
7. The integrated circuit of claim 1 , wherein the plurality of fins has a width between about 30 nm to about 3 μm.
8. The integrated circuit of claim 2 , further comprising:
at least one of NMOS and PMOS transistors.
9. The integrated circuit of claim 2 , further comprising:
a multi-gate FET device.
10. A method of fabricating an integrated circuit, comprising:
providing a semiconductor wafer including a plurality of fins;
oxidizing the semiconductor wafer to form a screening oxide layer on the plurality of fins;
implanting a dopant into the plurality of fins;
removing the screening oxide layer from the plurality of fins;
annealing the semiconductor wafer; and
providing a gate insulator and a gate stack disposed over the plurality of fins after the implanting of the dopant on the plurality of fins.
11. The method of claim 10 , wherein the dopant comprises at least one of the group of materials consisting of Fluorine, Boron difluoride, Boron trifluoride, Chlorine, Hydrogen, Deuterium, Nitrogen, Argon, Xenon, Neon and Krypton.
12. The method of claim 11 , wherein implanting the dopant on the plurality of fins is performed at an implantation angle that is determined by solving the equation:
tan(a)=s/h
tan(a)=s/h
where, “s” is the spacing between two consequent fins, and “h” is the height of the silicon fins.
13. The method of claim 11 , wherein implanting the dopant on the plurality of fins is performed in a dual mode.
14. The method of claim 11 , wherein implanting the dopant on the plurality of fins is performed in a quad mode.
15. The method of claim 11 , wherein annealing the semiconductor wafer includes maintaining the semiconductor wafer at a temperature between about 950° C. and about 1200° C. for a time period between about 1 second and about 60 seconds.
16. The method of claim 11 , wherein the gate insulator includes at least one of an oxide, a nitride, nitrided silicon oxide and a high-k dielectric material.
17. The method of claim 11 , wherein implanting the dopant into the plurality of fins further comprises implanting using an implant dose less than about 6E15 atoms/cm2 and an implant energy less than about 20 keV.
18. The method of claim 17 , further comprises cleaning of the plurality of fins using a cleaning agent.
19. The method of claim 18 , wherein the cleaning agent includes ammonia hydrogen peroxide water.
20. The method of claim 15 , wherein annealing the semiconductor wafer further comprises a post-oxidation annealing to allow distribution of the dopant into the gate insulator.
21. The method of claim 15 , wherein the post-oxidation annealing includes maintaining the wafer at a temperature between about 950° C. and about 1200° C. for a time period between about 1 second and about 20 seconds.
22. The method of claim 11 , wherein removing the screening oxide layer from the plurality of fins includes a cleaning using Hydrogen fluoride (HF) vapor.
23. The method of claim 11 , wherein removing the screening oxide layer from the plurality of fins includes a wet etching process.
24. The method of claim 23 , wherein the wet etching process is performed using an etching agent including HF acid.
25. The method of claim 11 , wherein the gate stack includes at least one of a poly silicon gate, a fully silicided gate and a metal gate.
26. The method of claim 10 , wherein the dopant comprises at least one of the group of materials consisting of Boron difluoride and Boron trifluoride and implanted into the plurality of fins in an NMOS device using an implant dose between about 5E13 atoms/cm2 and about 6E15 atoms/cm2.
27. The method of claim 10 , wherein the dopant comprises at least one of the group of materials consisting of Boron difluoride and Boron trifluoride and implanted into the plurality of fins, the plurality of fins includes n-type doping material.
28. The method of claim 10 , wherein the dopant comprises at least one of the group of materials consisting of Boron difluoride and Boron trifluoride and implanting the plurality of fins includes implanting a plurality of n-doped fins in a PMOS device.
29. The method of claim 26 , wherein implanting the dopant on the plurality of fins is performed at an implantation angle that is determined by solving the equation:
tan(a)=s/h
tan(a)=s/h
where, “s” is the spacing between two consequent fins, and “h” is the height of the silicon fins.
30. A method for fabricating a semiconductor wafer, the method comprising:
providing a substrate having a buried silicon oxide layer and a single crystal silicon layer disposed above the substrate;
implanting a dopant into the buried silicon oxide layer;
providing a gate insulator disposed on the silicon layer after implanting the dopant into the buried silicon oxide layer;
annealing the semiconductor wafer; and
providing a gate stack.
31. The method of claim 30 , wherein the dopant includes at least one of the group of materials consisting of Fluorine, Boron difluoride, Boron trifluoride, Chlorine, Hydrogen, Deuterium, Nitrogen, Argon, Xenon, Neon, and Krypton.
32. The method of claim 30 , wherein the gate insulator comprises depositing a high-k dielectric material onto the single crystal silicon layer.
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US13/763,989 US20130214360A1 (en) | 2006-08-30 | 2013-02-11 | Method and apparatus for reducing flicker noise in a semiconductor device |
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Also Published As
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DE102007041082A1 (en) | 2008-03-27 |
US20110201186A1 (en) | 2011-08-18 |
DE102007041082B4 (en) | 2012-04-26 |
DE102007063781B3 (en) | 2017-11-02 |
US8372736B2 (en) | 2013-02-12 |
US20130214360A1 (en) | 2013-08-22 |
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