US20040129219A1 - Atomic layer deposition apparatus and method - Google Patents

Atomic layer deposition apparatus and method Download PDF

Info

Publication number
US20040129219A1
US20040129219A1 US10/741,300 US74130003A US2004129219A1 US 20040129219 A1 US20040129219 A1 US 20040129219A1 US 74130003 A US74130003 A US 74130003A US 2004129219 A1 US2004129219 A1 US 2004129219A1
Authority
US
United States
Prior art keywords
chamber
vacuum pump
roughing vacuum
feeding
roughing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/741,300
Inventor
Trung Doan
Gurtej Sandhu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to US10/741,300 priority Critical patent/US20040129219A1/en
Publication of US20040129219A1 publication Critical patent/US20040129219A1/en
Priority to US11/055,487 priority patent/US7030037B2/en
Priority to US11/364,738 priority patent/US7431773B2/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • C23C16/45523Pulsed gas flow or change of composition over time
    • C23C16/45525Atomic layer deposition [ALD]
    • C23C16/45544Atomic layer deposition [ALD] characterized by the apparatus
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/4412Details relating to the exhausts, e.g. pumps, filters, scrubbers, particle traps
    • CCHEMISTRY; METALLURGY
    • C30CRYSTAL GROWTH
    • C30BSINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B25/00Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
    • C30B25/02Epitaxial-layer growth
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67017Apparatus for fluid treatment

Definitions

  • This invention relates to atomic layer deposition.
  • Atomic layer deposition involves the deposition of successive monolayers over a substrate within a deposition chamber typically maintained at subatmospheric pressure.
  • An exemplary such method includes feeding a single vaporized precursor to a deposition chamber effective to form a first monolayer over a substrate received therein. Thereafter, the flow of the first deposition precursor is ceased and an inert purge gas is flowed through the chamber effective to remove any remaining first precursor which is not adhering to the substrate from the chamber. Subsequently, a second vapor precursor different from the first is flowed to the chamber effective to form a second monolayer on/with the first monolayer. The second monolayer might react with the first monolayer. Additional precursors can form successive monolayers, or the above process can be repeated until a desired thickness and composition layer has been formed over the substrate.
  • the invention includes improvements in apparatus and methods of atomic layer depositions, whether existing or yet-to-be developed, whereby at least one monolayer is formed over a substrate.
  • an atomic layer deposition method includes positioning a semiconductor substrate within an atomic layer deposition chamber.
  • a first deposition precursor is fed to the chamber under first vacuum conditions effective to form a first monolayer on the substrate.
  • the first vacuum conditions are maintained at least in part by a first non-roughing vacuum pump connected to the chamber and through which at least some of the first deposition precursor flows.
  • a purge gas is fed to the chamber under second vacuum conditions maintained at least in part by a second non-roughing vacuum pump connected to the chamber which is different from the first non-roughing vacuum pump and through which at least some of the purge gas flows.
  • an atomic layer deposition apparatus includes an atomic layer deposition chamber having a substrate passageway communicating to externally of the chamber.
  • a first non-roughing vacuum pump is in fluid communication with the chamber apart from the substrate passageway.
  • a second non-roughing vacuum pump is in fluid communication with the chamber apart from the substrate passageway.
  • FIG. 1 is a diagrammatic depiction of an atomic layer deposition apparatus in accordance with an aspect of the invention.
  • FIG. 2 is a diagrammatic depiction of an atomic layer deposition apparatus in accordance with an aspect of the invention.
  • FIG. 3 is a diagrammatic depiction of an atomic layer deposition apparatus in accordance with an aspect of the invention.
  • FIG. 4 is a sectional view taken through line 4 - 4 in FIG. 3.
  • FIG. 5 is an alternate embodiment sectional view as would be taken through line 4 - 4 in FIG. 3.
  • FIG. 6 is a diagrammatic depiction of an atomic layer deposition apparatus in accordance with an aspect of the invention in a first operational state.
  • FIG. 7 is a view of the FIG. 6 apparatus in a second operational state.
  • FIG. 8 is a diagrammatic depiction of an atomic layer deposition apparatus in accordance with an aspect of the invention.
  • FIG. 9 is a diagrammatic depiction of an atomic layer deposition apparatus in accordance with an aspect of the invention.
  • FIG. 1 depicts a first embodiment atomic layer deposition apparatus 10 .
  • Such comprises an atomic layer deposition chamber 12 having a substrate passageway 14 communicating to externally of the chamber.
  • a load chamber 16 is in fluid communication with atomic layer deposition chamber 12 through substrate passageway 14 .
  • a load chamber vacuum pump is diagrammatically depicted with numeral 18 , and is in fluid communication with load chamber 16 apart from through substrate passageway 14 .
  • Load chamber vacuum pump 18 includes an illustrated discharge indicated by a downward arrow, and a by-pass inlet illustrated by a horizontal arrow pointing to the left proximate thereto.
  • additional vacuum pumps might be associated with load chamber 16 and/or pump 18 could be configured to include a roughing vacuum pump apparatus and a non-roughing vacuum pump apparatus.
  • a “roughing vacuum pump” is a vacuum pump (or sub-pumping components/apparatus of a non-roughing vacuum pump) which is configured to provide an initial reduced pressure from at or near atmospheric pressure, and which is used with a non-roughing vacuum pump that further reduces pressure.
  • a “non-roughing vacuum pump” is a vacuum pump configured to provide a subatmospheric deposition operating pressure within the chamber.
  • atomic layer deposition chamber 12 is provided with three gas inlets 20 , 22 and 24 .
  • any two of such inlets might be configured for feeding different deposition precursors to chamber 12 , with the remaining inlet being configured for feeding a purge gas to deposition chamber 12 .
  • a first non-roughing vacuum pump 26 is in fluid communication with deposition chamber 12 apart from substrate passageway 14 .
  • a second non-roughing vacuum pump 28 is in fluid communication with deposition chamber 12 apart from substrate passageway 14 .
  • Any suitable pumps capable of producing a desired subatmospheric deposition pressure are contemplated whether existing or yet-to-be developed.
  • such include turbomolecular pumps, diffusion pumps, sublimation pumps, cryo pumps, diffusion ejector pumps, absorption pumps, sliding-vane rotary pumps, rotary piston pumps, rotary plunger pumps, root pumps, etc.
  • a roughing vacuum pump 30 is provided in fluid communication with chamber 12 apart from substrate passageway 14 .
  • a roughing vacuum pump may or may not be utilized, and might alternately comprise a sub-pumping device of non-roughing vacuum pump assemblies. Further, such might be in fluid communication with chamber 12 through a separate line from non-roughing vacuum pumps 26 and 28 (as shown), or through conduits or other gas passageways (not shown) associated with non-roughing vacuum pumps 26 and 28 . Further of course, non-roughing vacuum pumps 26 and 28 could comprise respective multiple pumping devices/components/apparatus (roughing and/or non-roughing) connected in series and/or in parallel.
  • the first and second non-roughing vacuum pumps can be configured to have different rated throughputs over a given operating pressure range. Alternately, the first and second non-roughing vacuum pumps can be configured to have common rated throughputs over a given operating pressure range.
  • Second non-roughing vacuum pump 28 is depicted as being diagrammatically larger than first non-roughing vacuum pump 26 , thereby having corresponding larger and smaller throughputs, respectively. In such depicted preferred embodiment, second non-roughing vacuum pump 28 is configured with chamber 12 for feeding a purge gas to the chamber, while first non-roughing vacuum pump 26 is configured with chamber 12 for feeding a deposition precursor to the chamber.
  • first and second non-roughing vacuum pumps 26 and 28 might be configured for operating at variable speeds over a given operating pressure range, or configured for operating at respective constant speeds over a given operating pressure range. Further, one may be configured for operating at a constant speed over a given operating pressure range with the other being configured for operating at variable speeds over a given operating pressure range.
  • FIG. 1 depicts an embodiment whereby chamber 12 is provided with multiple outlets 32 and 34 , with one of said outlets (outlet 32 ) being in fluid communication with first non-roughing vacuum pump 26 and another of said outlets (outlet 34 ) being in fluid communication with second non-roughing vacuum pump 28 .
  • pressure control valving or other apparatus could be associated with one or more of the illustrated pumps, outlets and/or conduits for controlling the pressure, or isolating one or more pumps from the chamber while one or more other pump(s) operate(s) relative to the chamber.
  • by-pass inlets are illustrated by respective horizontal arrows pointing to the right proximate each pump, for example should a pump be isolated from communicating with chamber 12 during operation. Such might be used to minimize transient pressure changes with respect to the feedlines when switching between pumps.
  • FIG. 2 illustrates an alternate embodiment 10 a .
  • Atomic layer deposition apparatus 10 a is provided with one outlet 38 at chamber 12 which is in fluid communication with both first and second non-roughing vacuum pumps 26 a and 28 a , respectively.
  • a suitable conduit 40 extends from outlet 38 .
  • First and second non-roughing vacuum pumps 26 a and 28 a are in fluid communication with conduit 40 .
  • At least one isolation valve is associated with the illustrated first and second pumps.
  • there is one and only one such isolation valve diagrammatically depicted as an embodiment 42 .
  • isolation valve assembly 42 is in the form of a pivotable flap valve 44 received within conduit 40 and configured for selectively isolating the first and second pumps 26 a and 28 a , respectively, from fluid communication with conduit 40 .
  • FIGS. 3 - 5 depict an alternate embodiment atomic layer deposition apparatus 10 b .
  • Atomic layer deposition apparatus 10 b includes a rotatable valve 42 b received within conduit 40 b , and which is configured for selectively isolating first and second pumps 26 b and 28 b , respectively, from fluid communication with conduit 40 b .
  • Rotatable valve 42 b is depicted in the exemplary embodiment as being mounted for rotation about a central axis 43 .
  • a valve opening 46 is received radially from axis 43 and can be selectively positioned to provide flow relative to second non-roughing vacuum pump 28 b (as shown), or with respect to first non-roughing vacuum pump 26 b by 180° rotation about axis 43 (not shown).
  • FIG. 5 depicts an exemplary alternate embodiment rotatable valve 48 having two adjacent valve openings 50 and 52 positioned proximate to but radially 90° from one another. This particular exemplary embodiment would enable switching between first non-roughing vacuum pump 26 b and second non-roughing vacuum pump 28 b by 90° rotation as opposed to the 180° of rotation with respect to the 42 b diagrammatic embodiment.
  • FIGS. 6 and 7 illustrate another alternate embodiment atomic layer deposition apparatus 10 c , and in different respective operational configurations. Like numerals from the above-described embodiments are utilized where appropriate, with differences being indicated with the suffix “c”, or with different numerals.
  • Valve assembly 42 c is depicted diagrammatically as a slidable valve received within conduit 40 c and configured for selectively isolating first and second pumps 26 c and 28 c , respectively, from fluid communication with conduit 40 c .
  • FIG. 6 depicts one operational configuration where valve 42 c is slid to provide fluid communication of pump 26 c with conduit 40 c , while second pump 28 c is restricted from fluid communication with conduit 40 c .
  • FIG. 7 depicts the opposite.
  • FIG. 8 illustrates another alternate embodiment atomic layer deposition apparatus 10 d .
  • Atomic layer deposition apparatus 10 d comprises a third non-roughing vacuum pump 60 in fluid communication with chamber 12 d apart from substrate passageway 14 .
  • third non-roughing vacuum pump 60 is configured with chamber 12 d for feeding a second deposition precursor to chamber 12 d .
  • separate precursor feed pumps i.e., pumps 26 d and 60
  • pump 26 d and 60 are separately optimized for their respective different deposition precursors (for example, in one or both of materials of construction or designed throughput) while another of the non-roughing vacuum pumps (i.e., pump 28 d ) is configured for feeding a purge gas to the chamber (for example, with respect to desired higher throughput than with the deposition precursors).
  • FIG. 8 depicted embodiment shows chamber 12 d as being provided with multiple outlets 32 d , 34 d and 62 , which are in respective fluid communication with first non-roughing vacuum pump 26 d , second non-roughing vacuum pump 28 d and third non-roughing vacuum pump 60 , respectively.
  • FIG. 9 depicts an alternate embodiment atomic layer deposition apparatus 10 e wherein a chamber 12 e is provided with one outlet 40 e at the chamber. Outlet 40 e is in fluid communication with each of first, second and third non-roughing vacuum pumps 32 e , 34 e and 60 e , respectively. Of course, more than three non-roughing vacuum pumps could be utilized.
  • the invention contemplates an atomic layer deposition method using the above-described apparatus, and methods independent thereof.
  • the concluding apparatus claims are not limited by the method claims, nor are the concluding method claims limited by any attribute of the apparatus claims, unless literal language appears in such claims and without any limiting or interpretative reference to the specification or drawings.
  • the respective method claim families and apparatus claim families stand as literally worded without reference to the other.
  • An exemplary first embodiment atomic layer deposition method in accordance with the invention positions a semiconductor substrate within an atomic layer deposition chamber, for example any of the above-described chambers.
  • semiconductor substrate or “semiconductive substrate” is defined to mean any construction comprising semiconductive material, including, but not limited to, bulk semiconductive materials such as a semiconductive wafer (either alone or in assemblies comprising other materials thereon), and semiconductive material layers (either alone or in assemblies comprising other materials).
  • substrate refers to any supporting structure, including, but not limited to, the semiconductive substrates described above. Such positioning can occur by passing a substrate 70 to be processed from load chamber 16 through substrate passageway 14 onto a suitable substrate holder (not shown) within atomic layer deposition chamber 12 . A first deposition precursor is fed through the chamber under first vacuum conditions effective to form a first monolayer on the substrate. The first vacuum conditions are maintained, at least in part, by a first non-roughing vacuum pump connected to the chamber and through which at least some of the first deposition precursor flows.
  • a purge gas is fed to the chamber under second vacuum conditions maintained, at least in part, by a second non-roughing vacuum pump connected to the chamber, which is different from the first non-roughing vacuum pump, and through which at least some of the purge gas flows.
  • a roughing vacuum pump is utilized to lower chamber pressure prior to feeding the first deposition precursor.
  • a second deposition precursor is fed to the chamber effective to form a second monolayer on the first monolayer.
  • any existing or yet-to-be developed deposition precursors are of course contemplated.
  • the second deposition precursor feeding might be conducted under third vacuum conditions effective to form a second monolayer on the first monolayer using the first non-roughing vacuum pump.
  • the second deposition precursor feeding to the chamber might be conducted under third vacuum conditions maintained, at least in part, by a third non-roughing vacuum pump connected to the chamber, which is different from the first and second non-roughing vacuum pumps.
  • the first vacuum conditions include a substantially constant vacuum pressure within the chamber.
  • the first vacuum conditions include varied vacuum pressure within the chamber.
  • the vacuum pressure within the chamber is substantially the same under the first and second vacuum conditions, and in a most preferred embodiment, the vacuum pressure is substantially constant within the chamber under the first and second vacuum conditions.
  • the vacuum pressure within the chamber is different under the first and second vacuum conditions, and in a sub-embodiment, preferably is both substantially constant during each of the first and second vacuum conditions but different from one another under the first and second vacuum conditions.
  • an atomic layer deposition method in accordance with the invention includes isolating the first non-roughing vacuum pump from the chamber during at least some of the purge gas feeding.
  • the method includes isolating the second non-roughing vacuum pump from the chamber during at least some of the first deposition precursor feeding, and in one sub-embodiment, preferably during all of the first deposition precursor feeding.
  • the method comprises operating the second non-roughing vacuum pump at a higher pumping speed during the purge gas feeding than the first non-roughing vacuum pump is operated at during the first deposition precursor feeding.

Abstract

An atomic layer deposition method includes positioning a semiconductor substrate within an atomic layer deposition chamber. A first deposition precursor is fed to the chamber under first vacuum conditions effective to form a first monolayer on the substrate. The first vacuum conditions are maintained at least in part by a first non-roughing vacuum pump connected to the chamber and through which at least some of the first deposition precursor flows. After forming the first monolayer, a purge gas is fed to the chamber under second vacuum conditions maintained at least in part by a second non-roughing vacuum pump connected to the chamber which is different from the first non-roughing vacuum pump and through which at least some of the purge gas flows. An atomic layer deposition apparatus is disclosed.

Description

    TECHNICAL FIELD
  • This invention relates to atomic layer deposition. [0001]
  • BACKGROUND OF THE INVENTION
  • Atomic layer deposition involves the deposition of successive monolayers over a substrate within a deposition chamber typically maintained at subatmospheric pressure. An exemplary such method includes feeding a single vaporized precursor to a deposition chamber effective to form a first monolayer over a substrate received therein. Thereafter, the flow of the first deposition precursor is ceased and an inert purge gas is flowed through the chamber effective to remove any remaining first precursor which is not adhering to the substrate from the chamber. Subsequently, a second vapor precursor different from the first is flowed to the chamber effective to form a second monolayer on/with the first monolayer. The second monolayer might react with the first monolayer. Additional precursors can form successive monolayers, or the above process can be repeated until a desired thickness and composition layer has been formed over the substrate. [0002]
  • The invention includes improvements in apparatus and methods of atomic layer depositions, whether existing or yet-to-be developed, whereby at least one monolayer is formed over a substrate. [0003]
  • SUMMARY
  • The invention includes atomic layer deposition methods and apparatus. In one implementation, an atomic layer deposition method includes positioning a semiconductor substrate within an atomic layer deposition chamber. A first deposition precursor is fed to the chamber under first vacuum conditions effective to form a first monolayer on the substrate. The first vacuum conditions are maintained at least in part by a first non-roughing vacuum pump connected to the chamber and through which at least some of the first deposition precursor flows. After forming the first monolayer, a purge gas is fed to the chamber under second vacuum conditions maintained at least in part by a second non-roughing vacuum pump connected to the chamber which is different from the first non-roughing vacuum pump and through which at least some of the purge gas flows. [0004]
  • In one implementation, an atomic layer deposition apparatus includes an atomic layer deposition chamber having a substrate passageway communicating to externally of the chamber. A first non-roughing vacuum pump is in fluid communication with the chamber apart from the substrate passageway. A second non-roughing vacuum pump is in fluid communication with the chamber apart from the substrate passageway. [0005]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • Preferred embodiments of the invention are described below with reference to the following accompanying drawings. [0006]
  • FIG. 1 is a diagrammatic depiction of an atomic layer deposition apparatus in accordance with an aspect of the invention. [0007]
  • FIG. 2 is a diagrammatic depiction of an atomic layer deposition apparatus in accordance with an aspect of the invention. [0008]
  • FIG. 3 is a diagrammatic depiction of an atomic layer deposition apparatus in accordance with an aspect of the invention. [0009]
  • FIG. 4 is a sectional view taken through line [0010] 4-4 in FIG. 3.
  • FIG. 5 is an alternate embodiment sectional view as would be taken through line [0011] 4-4 in FIG. 3.
  • FIG. 6 is a diagrammatic depiction of an atomic layer deposition apparatus in accordance with an aspect of the invention in a first operational state. [0012]
  • FIG. 7 is a view of the FIG. 6 apparatus in a second operational state. [0013]
  • FIG. 8 is a diagrammatic depiction of an atomic layer deposition apparatus in accordance with an aspect of the invention. [0014]
  • FIG. 9 is a diagrammatic depiction of an atomic layer deposition apparatus in accordance with an aspect of the invention. [0015]
  • DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • This disclosure of the invention is submitted in furtherance of the constitutional purposes of the U.S. Patent Laws “to promote the progress of science and useful arts” (Article 1, Section 8). [0016]
  • FIG. 1 depicts a first embodiment atomic [0017] layer deposition apparatus 10. Such comprises an atomic layer deposition chamber 12 having a substrate passageway 14 communicating to externally of the chamber. A load chamber 16 is in fluid communication with atomic layer deposition chamber 12 through substrate passageway 14. A load chamber vacuum pump is diagrammatically depicted with numeral 18, and is in fluid communication with load chamber 16 apart from through substrate passageway 14. Load chamber vacuum pump 18 includes an illustrated discharge indicated by a downward arrow, and a by-pass inlet illustrated by a horizontal arrow pointing to the left proximate thereto. In the preferred embodiment, additional vacuum pumps might be associated with load chamber 16 and/or pump 18 could be configured to include a roughing vacuum pump apparatus and a non-roughing vacuum pump apparatus. In the context of this document, a “roughing vacuum pump” is a vacuum pump (or sub-pumping components/apparatus of a non-roughing vacuum pump) which is configured to provide an initial reduced pressure from at or near atmospheric pressure, and which is used with a non-roughing vacuum pump that further reduces pressure. Also in the context of this document, a “non-roughing vacuum pump” is a vacuum pump configured to provide a subatmospheric deposition operating pressure within the chamber.
  • In the illustrated exemplary embodiment, atomic [0018] layer deposition chamber 12 is provided with three gas inlets 20, 22 and 24. By way of example only, any two of such inlets might be configured for feeding different deposition precursors to chamber 12, with the remaining inlet being configured for feeding a purge gas to deposition chamber 12.
  • A first [0019] non-roughing vacuum pump 26 is in fluid communication with deposition chamber 12 apart from substrate passageway 14. A second non-roughing vacuum pump 28 is in fluid communication with deposition chamber 12 apart from substrate passageway 14. Any suitable pumps capable of producing a desired subatmospheric deposition pressure are contemplated whether existing or yet-to-be developed. By way of example only, such include turbomolecular pumps, diffusion pumps, sublimation pumps, cryo pumps, diffusion ejector pumps, absorption pumps, sliding-vane rotary pumps, rotary piston pumps, rotary plunger pumps, root pumps, etc. A roughing vacuum pump 30 is provided in fluid communication with chamber 12 apart from substrate passageway 14. As described above with respect to load chamber vacuum pump 18, a roughing vacuum pump may or may not be utilized, and might alternately comprise a sub-pumping device of non-roughing vacuum pump assemblies. Further, such might be in fluid communication with chamber 12 through a separate line from non-roughing vacuum pumps 26 and 28 (as shown), or through conduits or other gas passageways (not shown) associated with non-roughing vacuum pumps 26 and 28. Further of course, non-roughing vacuum pumps 26 and 28 could comprise respective multiple pumping devices/components/apparatus (roughing and/or non-roughing) connected in series and/or in parallel.
  • The first and second non-roughing vacuum pumps can be configured to have different rated throughputs over a given operating pressure range. Alternately, the first and second non-roughing vacuum pumps can be configured to have common rated throughputs over a given operating pressure range. Second [0020] non-roughing vacuum pump 28 is depicted as being diagrammatically larger than first non-roughing vacuum pump 26, thereby having corresponding larger and smaller throughputs, respectively. In such depicted preferred embodiment, second non-roughing vacuum pump 28 is configured with chamber 12 for feeding a purge gas to the chamber, while first non-roughing vacuum pump 26 is configured with chamber 12 for feeding a deposition precursor to the chamber. For example, and by way of example only, it might be desirable to draw or feed the purge gas through the system at much higher throughput over a given pressure range than a throughput which would be desired over a given pressure range (under the same or different pressure range) for a deposition precursor. Also, first and second non-roughing vacuum pumps 26 and 28 might be configured for operating at variable speeds over a given operating pressure range, or configured for operating at respective constant speeds over a given operating pressure range. Further, one may be configured for operating at a constant speed over a given operating pressure range with the other being configured for operating at variable speeds over a given operating pressure range.
  • FIG. 1 depicts an embodiment whereby [0021] chamber 12 is provided with multiple outlets 32 and 34, with one of said outlets (outlet 32) being in fluid communication with first non-roughing vacuum pump 26 and another of said outlets (outlet 34) being in fluid communication with second non-roughing vacuum pump 28. Of course, pressure control valving or other apparatus could be associated with one or more of the illustrated pumps, outlets and/or conduits for controlling the pressure, or isolating one or more pumps from the chamber while one or more other pump(s) operate(s) relative to the chamber. For example, by-pass inlets are illustrated by respective horizontal arrows pointing to the right proximate each pump, for example should a pump be isolated from communicating with chamber 12 during operation. Such might be used to minimize transient pressure changes with respect to the feedlines when switching between pumps.
  • FIG. 2 illustrates an [0022] alternate embodiment 10 a. Like numerals from the first embodiment are utilized where appropriate, with differences being indicated by the suffix “a” or with different numerals. Atomic layer deposition apparatus 10 a is provided with one outlet 38 at chamber 12 which is in fluid communication with both first and second non-roughing vacuum pumps 26 a and 28 a, respectively. In this exemplary depicted preferred embodiment, a suitable conduit 40 extends from outlet 38. First and second non-roughing vacuum pumps 26 a and 28 a, respectively, are in fluid communication with conduit 40. At least one isolation valve is associated with the illustrated first and second pumps. In the depicted preferred embodiment, there is one and only one such isolation valve diagrammatically depicted as an embodiment 42. Further in the depicted embodiment, isolation valve assembly 42 is in the form of a pivotable flap valve 44 received within conduit 40 and configured for selectively isolating the first and second pumps 26 a and 28 a, respectively, from fluid communication with conduit 40.
  • FIGS. [0023] 3-5 depict an alternate embodiment atomic layer deposition apparatus 10 b. Like numerals from the first and second described embodiments are utilized where appropriate, with differences being indicated by the suffix “b” or with different numerals. Atomic layer deposition apparatus 10 b includes a rotatable valve 42 b received within conduit 40 b, and which is configured for selectively isolating first and second pumps 26 b and 28 b, respectively, from fluid communication with conduit 40 b. Rotatable valve 42 b is depicted in the exemplary embodiment as being mounted for rotation about a central axis 43. A valve opening 46 is received radially from axis 43 and can be selectively positioned to provide flow relative to second non-roughing vacuum pump 28 b (as shown), or with respect to first non-roughing vacuum pump 26 b by 180° rotation about axis 43 (not shown).
  • FIG. 5 depicts an exemplary alternate embodiment [0024] rotatable valve 48 having two adjacent valve openings 50 and 52 positioned proximate to but radially 90° from one another. This particular exemplary embodiment would enable switching between first non-roughing vacuum pump 26 b and second non-roughing vacuum pump 28 b by 90° rotation as opposed to the 180° of rotation with respect to the 42 b diagrammatic embodiment.
  • FIGS. 6 and 7 illustrate another alternate embodiment atomic [0025] layer deposition apparatus 10 c, and in different respective operational configurations. Like numerals from the above-described embodiments are utilized where appropriate, with differences being indicated with the suffix “c”, or with different numerals. Valve assembly 42 c is depicted diagrammatically as a slidable valve received within conduit 40 c and configured for selectively isolating first and second pumps 26 c and 28 c, respectively, from fluid communication with conduit 40 c. FIG. 6 depicts one operational configuration where valve 42 c is slid to provide fluid communication of pump 26 c with conduit 40 c, while second pump 28 c is restricted from fluid communication with conduit 40 c. FIG. 7 depicts the opposite.
  • Of course, any additional or alternate isolating valving assemblies, whether existing or yet-to-be developed, might be utilized. [0026]
  • FIG. 8 illustrates another alternate embodiment atomic [0027] layer deposition apparatus 10 d. Like numerals from the above-described embodiments are utilized where appropriate, with differences being indicated with the suffix “d”, or with different numerals. Atomic layer deposition apparatus 10 d comprises a third non-roughing vacuum pump 60 in fluid communication with chamber 12 d apart from substrate passageway 14. In one preferred embodiment, third non-roughing vacuum pump 60 is configured with chamber 12 d for feeding a second deposition precursor to chamber 12 d. For example, in one preferred embodiment, separate precursor feed pumps (i.e., pumps 26 d and 60) are separately optimized for their respective different deposition precursors (for example, in one or both of materials of construction or designed throughput) while another of the non-roughing vacuum pumps (i.e., pump 28 d) is configured for feeding a purge gas to the chamber (for example, with respect to desired higher throughput than with the deposition precursors).
  • The FIG. 8 depicted embodiment shows [0028] chamber 12 d as being provided with multiple outlets 32 d, 34 d and 62, which are in respective fluid communication with first non-roughing vacuum pump 26 d, second non-roughing vacuum pump 28 d and third non-roughing vacuum pump 60, respectively. FIG. 9 depicts an alternate embodiment atomic layer deposition apparatus 10 e wherein a chamber 12 e is provided with one outlet 40 e at the chamber. Outlet 40 e is in fluid communication with each of first, second and third non-roughing vacuum pumps 32 e, 34 e and 60 e, respectively. Of course, more than three non-roughing vacuum pumps could be utilized.
  • The invention contemplates an atomic layer deposition method using the above-described apparatus, and methods independent thereof. In other words, the concluding apparatus claims are not limited by the method claims, nor are the concluding method claims limited by any attribute of the apparatus claims, unless literal language appears in such claims and without any limiting or interpretative reference to the specification or drawings. The respective method claim families and apparatus claim families stand as literally worded without reference to the other. An exemplary first embodiment atomic layer deposition method in accordance with the invention positions a semiconductor substrate within an atomic layer deposition chamber, for example any of the above-described chambers. In the context of this document, the term “semiconductor substrate” or “semiconductive substrate” is defined to mean any construction comprising semiconductive material, including, but not limited to, bulk semiconductive materials such as a semiconductive wafer (either alone or in assemblies comprising other materials thereon), and semiconductive material layers (either alone or in assemblies comprising other materials). The term “substrate” refers to any supporting structure, including, but not limited to, the semiconductive substrates described above. Such positioning can occur by passing a [0029] substrate 70 to be processed from load chamber 16 through substrate passageway 14 onto a suitable substrate holder (not shown) within atomic layer deposition chamber 12. A first deposition precursor is fed through the chamber under first vacuum conditions effective to form a first monolayer on the substrate. The first vacuum conditions are maintained, at least in part, by a first non-roughing vacuum pump connected to the chamber and through which at least some of the first deposition precursor flows.
  • After forming the first monolayer, a purge gas is fed to the chamber under second vacuum conditions maintained, at least in part, by a second non-roughing vacuum pump connected to the chamber, which is different from the first non-roughing vacuum pump, and through which at least some of the purge gas flows. In one preferred embodiment, a roughing vacuum pump is utilized to lower chamber pressure prior to feeding the first deposition precursor. In one preferred embodiment, after feeding the purge gas, a second deposition precursor, different from the first deposition precursor, is fed to the chamber effective to form a second monolayer on the first monolayer. In the context of atomic layer deposition, any existing or yet-to-be developed deposition precursors are of course contemplated. The second deposition precursor feeding might be conducted under third vacuum conditions effective to form a second monolayer on the first monolayer using the first non-roughing vacuum pump. Alternately by way of example only, the second deposition precursor feeding to the chamber might be conducted under third vacuum conditions maintained, at least in part, by a third non-roughing vacuum pump connected to the chamber, which is different from the first and second non-roughing vacuum pumps. [0030]
  • In one preferred embodiment, the first vacuum conditions include a substantially constant vacuum pressure within the chamber. In another preferred embodiment, the first vacuum conditions include varied vacuum pressure within the chamber. In yet another preferred embodiment, the vacuum pressure within the chamber is substantially the same under the first and second vacuum conditions, and in a most preferred embodiment, the vacuum pressure is substantially constant within the chamber under the first and second vacuum conditions. In another preferred embodiment, the vacuum pressure within the chamber is different under the first and second vacuum conditions, and in a sub-embodiment, preferably is both substantially constant during each of the first and second vacuum conditions but different from one another under the first and second vacuum conditions. [0031]
  • In one preferred embodiment, an atomic layer deposition method in accordance with the invention includes isolating the first non-roughing vacuum pump from the chamber during at least some of the purge gas feeding. In another preferred embodiment, the method includes isolating the second non-roughing vacuum pump from the chamber during at least some of the first deposition precursor feeding, and in one sub-embodiment, preferably during all of the first deposition precursor feeding. [0032]
  • In one preferred embodiment, the method comprises operating the second non-roughing vacuum pump at a higher pumping speed during the purge gas feeding than the first non-roughing vacuum pump is operated at during the first deposition precursor feeding. [0033]
  • In compliance with the statute, the invention has been described in language more or less specific as to structural and methodical features. It is to be understood, however, that the invention is not limited to the specific features shown and described, since the means herein disclosed comprise preferred forms of putting the invention into effect. The invention is, therefore, claimed in any of its forms or modifications within the proper scope of the appended claims appropriately interpreted in accordance with the doctrine of equivalents. [0034]

Claims (53)

1. An atomic layer deposition method, comprising:
positioning a semiconductor substrate within an atomic layer deposition chamber;
feeding a first deposition precursor to the chamber under first vacuum conditions effective to form a first monolayer on the substrate, the first vacuum conditions being maintained at least in part by a first non-roughing vacuum pump connected to the chamber and through which at least some of the first deposition precursor flows; and
after forming the first monolayer, feeding a purge gas to the chamber under second vacuum conditions maintained at least in part by a second non-roughing vacuum pump connected to the chamber which is different from the first non-roughing vacuum pump and through which at least some of the purge gas flows.
2. The method of claim 1 comprising using a roughing vacuum pump to lower chamber pressure prior to the first deposition precursor feeding.
3. The method of claim 1 comprising after feeding the purge gas, feeding a second deposition precursor different from the first deposition precursor to the chamber effective to form a second monolayer on the first monolayer.
4. The method of claim 1 comprising after feeding the purge gas, feeding a second deposition precursor to the chamber different from the first deposition precursor under third vacuum conditions effective to form a second monolayer on the first monolayer and using the first non-roughing vacuum pump in fluid communication with the chamber during the second deposition precursor feeding.
5. The method of claim 1 comprising after feeding the purge gas, feeding a second deposition precursor to the chamber different from the first deposition precursor under third vacuum conditions effective to form a second monolayer on the first monolayer, the third vacuum conditions being maintained at least in part by a third non-roughing vacuum pump connected to the chamber which is different from the first and second non-roughing vacuum pumps.
6. The method of claim 1 wherein the first vacuum conditions include a substantially constant vacuum pressure within the chamber.
7. The method of claim 1 wherein the first vacuum conditions include varied vacuum pressure within the chamber.
8. The method of claim 1 wherein vacuum pressure within the chamber is substantially the same under the first and second vacuum conditions.
9. The method of claim 1 wherein vacuum pressure within the chamber is substantially constant and the same under the first and second vacuum conditions.
10. The method of claim 1 wherein vacuum pressure within the chamber is different under the first and second vacuum conditions.
11. The method of claim 1 wherein vacuum pressure within the chamber is substantially constant and different under the first and second vacuum conditions.
12. The method of claim 1 comprising isolating the first non-roughing vacuum pump from the chamber during at least some of the purge gas feeding.
13. The method of claim 1 comprising isolating the second non-roughing vacuum pump from the chamber during at least some of the first deposition precursor feeding.
14. The method of claim 1 comprising isolating the second non-roughing vacuum pump from the chamber during all of the first deposition precursor feeding.
15. The method of claim 1 comprising operating the second non-roughing vacuum pump at a higher pumping speed during the purge gas feeding than the first non-roughing vacuum pump is operated at during the first deposition precursor feeding.
16. The method of claim 1 wherein the chamber is provided with multiple outlets at the chamber, one of said outlets being in fluid communication with the first non-roughing vacuum pump, another of said outlets being in fluid communication with the second non-roughing vacuum pump.
17. The method of claim 1 wherein the chamber is provided with one outlet at the chamber which is in fluid communication with both the first and second non-roughing vacuum pumps.
18. An atomic layer deposition method, comprising:
positioning a semiconductor substrate within an atomic layer deposition chamber;
feeding a first deposition precursor to the chamber under first vacuum conditions effective to form a first monolayer on the substrate, the first vacuum conditions being maintained at least in part by a first non-roughing vacuum pump connected to the chamber and through which at least some of the first deposition precursor flows, the first non-roughing vacuum pump being operated at a first substantially constant pumping speed while forming the first monolayer; and
after forming the first monolayer, isolating the first non-roughing vacuum pump from the chamber and feeding a purge gas to the chamber under second vacuum conditions maintained at least in part by a second non-roughing vacuum pump connected to the chamber which is different from the first non-roughing vacuum pump and through which at least some of the purge gas flows, the second non-roughing vacuum pump being operated at a second pumping speed which is greater than the first pumping speed.
19. The method of claim 18 wherein the isolating occurs during the purge gas feeding.
20. The method of claim 18 wherein the isolating occurs before the purge gas feeding.
21. The method of claim 18 comprising isolating the second non-roughing vacuum pump from the chamber during at least some of the first deposition precursor feeding.
22. The method of claim 18 comprising isolating the second non-roughing vacuum pump from the chamber during all of the first deposition precursor feeding.
23. The method of claim 18 comprising after feeding the purge gas, feeding a second deposition precursor different from the first deposition precursor to the chamber effective to form a second monolayer on the first monolayer.
24. The method of claim 18 comprising after feeding the purge gas, feeding a second deposition precursor to the chamber different from the first deposition precursor under third vacuum conditions effective to form a second monolayer on the first monolayer and using the first non-roughing vacuum pump in fluid communication with the chamber during the second deposition precursor feeding.
25. The method of claim 18 comprising after feeding the purge gas, feeding a second deposition precursor to the chamber different from the first deposition precursor under third vacuum conditions effective to form a second monolayer on the first monolayer, the third vacuum conditions being maintained at least in part by a third non-roughing vacuum pump connected to the chamber which is different from the first and second non-roughing vacuum pumps.
26. The method of claim 18 wherein vacuum pressure within the chamber is different under the first and second vacuum conditions.
27. An atomic layer deposition apparatus, comprising:
an atomic layer deposition chamber having a substrate passageway communicating to externally of the chamber;
a first non-roughing vacuum pump in fluid communication with the chamber apart from the substrate passageway; and
a second non-roughing vacuum pump in fluid communication with the chamber apart from the substrate passageway.
28. The apparatus of claim 27 comprising a third non-roughing vacuum pump in fluid communication with the chamber apart from the substrate passageway.
29. The apparatus of claim 27 comprising a load chamber in fluid communication with the atomic layer deposition chamber through the substrate passageway, and a load chamber vacuum pump in fluid communication with the load chamber apart from the substrate passageway.
30. The apparatus of claim 27 wherein the first non-roughing vacuum pump is configured for feeding a deposition precursor to the chamber and the second non-roughing vacuum pump is configured for feeding a purge gas to the chamber.
31. The apparatus of claim 27 wherein the first and second non-roughing vacuum pumps have different rated throughputs over a given operating pressure range.
32. The apparatus of claim 31 wherein the first non-roughing vacuum pump is configured for feeding a deposition precursor to the chamber and the second non-roughing vacuum pump is configured for feeding a purge gas to the chamber, the second non-roughing vacuum pump having a higher rated throughput than the first non-roughing vacuum pump over the given operating pressure range.
33. The apparatus of claim 27 wherein the first and second non-roughing vacuum pumps have common rated throughputs over a given operating pressure range.
34. The apparatus of claim 27 wherein the first and second non-roughing vacuum pumps are configured for operating at variable speeds over a given operating pressure range.
35. The apparatus of claim 27 wherein the first and second non-roughing vacuum pumps are configured for operating at respective constant speeds over a given operating pressure range.
36. The apparatus of claim 27 wherein one of the first and second non-roughing vacuum pumps is configured for operating at a constant speed over a given operating pressure range, and the other of the first and second non-roughing vacuum pumps is configured for operating at variable speeds over a given operating pressure range.
37. The apparatus of claim 27 comprising a roughing vacuum pump in fluid communication with the chamber apart from the substrate passageway.
38. The apparatus of claim 27 wherein the chamber is provided with multiple outlets at the chamber, one of said outlets being in fluid communication with the first non-roughing vacuum pump, another of said outlets being in fluid communication with the second non-roughing vacuum pump.
39. The apparatus of claim 27 wherein the chamber is provided with one outlet at the chamber which is in fluid communication with both the first and second non-roughing vacuum pumps.
40. The apparatus of claim 39 comprising:
a conduit extending from the one outlet, the first and second non-roughing vacuum pumps being in fluid communication with the conduit; and
at least one first pump and second pump isolation valve.
41. The apparatus of claim 39 comprising:
a conduit extending from the one outlet, the first and second non-roughing vacuum pumps being in fluid communication with the conduit; and
one and only one first pump and second pump isolation valve.
42. The apparatus of claim 39 comprising:
a conduit extending from the one outlet, the first and second non-roughing vacuum pumps being in fluid communication with the conduit; and
a pivotable flap valve received within the conduit configured for selectively isolating the first and second pumps from fluid communication with the conduit.
43. The apparatus of claim 39 comprising:
a conduit extending from the one outlet, the first and second non-roughing vacuum pumps being in fluid communication with the conduit; and
a rotatable valve received within the conduit configured for selectively isolating the first and second pumps from fluid communication with the conduit.
44. The apparatus of claim 39 comprising:
a conduit extending from the one outlet, the first and second non-roughing vacuum pumps being in fluid communication with the conduit; and
a slidable valve received within the conduit configured for selectively isolating the first and second pumps from fluid communication with the conduit.
45. An atomic layer deposition apparatus, comprising:
an atomic layer deposition chamber having a substrate passageway communicating to externally of the chamber;
a first non-roughing vacuum pump in fluid communication with the chamber apart from the substrate passageway, the first non-roughing vacuum pump being configured with the chamber for feeding a first deposition precursor to the chamber;
a second non-roughing vacuum pump in fluid communication with the chamber apart from the substrate passageway, the second non-roughing vacuum pump being configured with the chamber for feeding a purge gas to the chamber; and
a third non-roughing vacuum pump in fluid communication with the chamber apart from the substrate passageway, the third non-roughing vacuum pump being configured with the chamber for feeding a second deposition precursor to the chamber.
46. The apparatus of claim 45 comprising a load chamber in fluid communication with the atomic layer deposition chamber through the substrate passageway, and a load chamber vacuum pump in fluid communication with the load chamber apart from the substrate passageway.
47. The apparatus of claim 45 comprising a roughing vacuum pump in fluid communication with the chamber apart from the substrate passageway.
48. The apparatus of claim 45 wherein the first and third non-roughing vacuum pumps have different rated throughputs over a given operating pressure range as compared to the second non-roughing vacuum pump.
49. The apparatus of claim 48 wherein the second non-roughing vacuum pump has a higher rated throughput than either of the first and second non-roughing vacuum pumps.
50. The apparatus of claim 45 wherein the first and third non-roughing vacuum pumps have a common rated throughput over a given operating pressure range and which is different as compared to the second non-roughing vacuum pump.
51. The apparatus of claim 50 wherein the second non-roughing vacuum pump has a higher rated throughput than that of the first and second non-roughing vacuum pumps.
52. The apparatus of claim 45 wherein the chamber is provided with multiple outlets at the chamber, one of said outlets being in fluid communication with the first non-roughing vacuum pump, another of said outlets being in fluid communication with the second non-roughing vacuum pump, still another of said outlets being in fluid communication with the third non-roughing vacuum pump.
53. The apparatus of claim 45 wherein the chamber is provided with one outlet at the chamber which is in fluid communication with each of the first, second and third non-roughing vacuum pumps.
US10/741,300 2002-03-11 2003-12-17 Atomic layer deposition apparatus and method Abandoned US20040129219A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US10/741,300 US20040129219A1 (en) 2002-03-11 2003-12-17 Atomic layer deposition apparatus and method
US11/055,487 US7030037B2 (en) 2002-03-11 2005-02-11 Atomic layer deposition apparatus and method
US11/364,738 US7431773B2 (en) 2002-03-11 2006-02-28 Atomic layer deposition apparatus and method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/097,025 US6893506B2 (en) 2002-03-11 2002-03-11 Atomic layer deposition apparatus and method
US10/741,300 US20040129219A1 (en) 2002-03-11 2003-12-17 Atomic layer deposition apparatus and method

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US10/097,025 Division US6893506B2 (en) 2002-03-11 2002-03-11 Atomic layer deposition apparatus and method

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US11/055,487 Continuation US7030037B2 (en) 2002-03-11 2005-02-11 Atomic layer deposition apparatus and method

Publications (1)

Publication Number Publication Date
US20040129219A1 true US20040129219A1 (en) 2004-07-08

Family

ID=27788306

Family Applications (4)

Application Number Title Priority Date Filing Date
US10/097,025 Expired - Lifetime US6893506B2 (en) 2002-03-11 2002-03-11 Atomic layer deposition apparatus and method
US10/741,300 Abandoned US20040129219A1 (en) 2002-03-11 2003-12-17 Atomic layer deposition apparatus and method
US11/055,487 Expired - Fee Related US7030037B2 (en) 2002-03-11 2005-02-11 Atomic layer deposition apparatus and method
US11/364,738 Expired - Fee Related US7431773B2 (en) 2002-03-11 2006-02-28 Atomic layer deposition apparatus and method

Family Applications Before (1)

Application Number Title Priority Date Filing Date
US10/097,025 Expired - Lifetime US6893506B2 (en) 2002-03-11 2002-03-11 Atomic layer deposition apparatus and method

Family Applications After (2)

Application Number Title Priority Date Filing Date
US11/055,487 Expired - Fee Related US7030037B2 (en) 2002-03-11 2005-02-11 Atomic layer deposition apparatus and method
US11/364,738 Expired - Fee Related US7431773B2 (en) 2002-03-11 2006-02-28 Atomic layer deposition apparatus and method

Country Status (1)

Country Link
US (4) US6893506B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006111617A1 (en) * 2005-04-22 2006-10-26 Beneq Oy Reactor
WO2020131193A1 (en) * 2018-12-21 2020-06-25 Applied Materials, Inc. Ald process and hardware with improved purge efficiency

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG114529A1 (en) * 2001-02-23 2005-09-28 Semiconductor Energy Lab Method of manufacturing a semiconductor device
AUPR412801A0 (en) * 2001-03-30 2001-05-03 Starpharma Limited Agent for the prevention and treatment of sexually transmitted disease s - I
US6893506B2 (en) * 2002-03-11 2005-05-17 Micron Technology, Inc. Atomic layer deposition apparatus and method
US7160577B2 (en) 2002-05-02 2007-01-09 Micron Technology, Inc. Methods for atomic-layer deposition of aluminum oxides in integrated circuits
US6921702B2 (en) 2002-07-30 2005-07-26 Micron Technology Inc. Atomic layer deposited nanolaminates of HfO2/ZrO2 films as gate dielectrics
CN1671884A (en) * 2002-07-31 2005-09-21 东京毅力科创株式会社 Reduced volume, high conductance process chamber
US20040058293A1 (en) * 2002-08-06 2004-03-25 Tue Nguyen Assembly line processing system
KR100498467B1 (en) * 2002-12-05 2005-07-01 삼성전자주식회사 Apparatus for atomic layer deposition with preventing powder generation in exhaust paths
US7081421B2 (en) 2004-08-26 2006-07-25 Micron Technology, Inc. Lanthanide oxide dielectric layer
US7588988B2 (en) 2004-08-31 2009-09-15 Micron Technology, Inc. Method of forming apparatus having oxide films formed using atomic layer deposition
US7494939B2 (en) 2004-08-31 2009-02-24 Micron Technology, Inc. Methods for forming a lanthanum-metal oxide dielectric layer
US7687409B2 (en) 2005-03-29 2010-03-30 Micron Technology, Inc. Atomic layer deposited titanium silicon oxide films
US7662729B2 (en) 2005-04-28 2010-02-16 Micron Technology, Inc. Atomic layer deposition of a ruthenium layer to a lanthanide oxide dielectric layer
FI121543B (en) * 2005-11-17 2010-12-31 Beneq Oy Arrangement in connection with the ALD reactor
JP2009544842A (en) * 2006-07-21 2009-12-17 リンデ・インコーポレーテッド Method and apparatus for vaporizing and delivering precursor solutions for atomic layer deposition
US7692222B2 (en) * 2006-11-07 2010-04-06 Raytheon Company Atomic layer deposition in the formation of gate structures for III-V semiconductor
US8043430B2 (en) * 2006-12-20 2011-10-25 Lam Research Corporation Methods and apparatuses for controlling gas flow conductance in a capacitively-coupled plasma processing chamber
US8067061B2 (en) 2007-10-25 2011-11-29 Asm America, Inc. Reaction apparatus having multiple adjustable exhaust ports
KR100949914B1 (en) * 2007-11-28 2010-03-30 주식회사 케이씨텍 Atomic layer deposition apparatus
JP2015512471A (en) * 2012-03-23 2015-04-27 ピコサン オーワイPicosun Oy Atomic layer deposition method and apparatus
JP6363408B2 (en) * 2014-06-23 2018-07-25 東京エレクトロン株式会社 Film forming apparatus and film forming method
CN108715999A (en) * 2018-08-07 2018-10-30 嘉兴科民电子设备技术有限公司 Apparatus for atomic layer deposition
TW202234623A (en) * 2021-02-24 2022-09-01 日商國際電氣股份有限公司 Substrate processing device, substrate processing method, method for manufacturing semiconductor device, program, and exhaust system
CN117646193B (en) * 2024-01-30 2024-03-26 辽宁拓邦鸿基半导体材料股份有限公司 Atomic layer deposition device

Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4793283A (en) * 1987-12-10 1988-12-27 Sarkozy Robert F Apparatus for chemical vapor deposition with clean effluent and improved product yield
US5000225A (en) * 1989-11-17 1991-03-19 Applied Materials, Inc. Low profile, combination throttle/gate valve for a multi-pump chamber
US5242539A (en) * 1991-04-04 1993-09-07 Hitachi, Ltd. Plasma treatment method and apparatus
US5286296A (en) * 1991-01-10 1994-02-15 Sony Corporation Multi-chamber wafer process equipment having plural, physically communicating transfer means
US5391260A (en) * 1992-03-27 1995-02-21 Hitachi, Ltd. Vacuum processing apparatus
US5746581A (en) * 1994-06-28 1998-05-05 Ebara Corporation Method and apparatus for evacuating vacuum system
US6206970B1 (en) * 1997-09-03 2001-03-27 Micron Technology, Inc. Semiconductor wafer processor, semiconductor processor gas filtering system and semiconductor processing methods
US6214120B1 (en) * 1999-08-27 2001-04-10 Innovac Corporation High throughput multi-vacuum chamber system for processing wafers and method of processing wafers using the same
US6270572B1 (en) * 1998-08-07 2001-08-07 Samsung Electronics Co., Ltd. Method for manufacturing thin film using atomic layer deposition
US6316045B1 (en) * 2000-04-20 2001-11-13 Alcatel Method and apparatus for conditioning the atmosphere in a process chamber
US6391803B1 (en) * 2001-06-20 2002-05-21 Samsung Electronics Co., Ltd. Method of forming silicon containing thin films by atomic layer deposition utilizing trisdimethylaminosilane
US6461436B1 (en) * 2001-10-15 2002-10-08 Micron Technology, Inc. Apparatus and process of improving atomic layer deposition chamber performance
US6511539B1 (en) * 1999-09-08 2003-01-28 Asm America, Inc. Apparatus and method for growth of a thin film
US20030153177A1 (en) * 2002-02-11 2003-08-14 Applied Materials, Inc. Variable flow deposition apparatus and method in semiconductor substrate processing
US6630201B2 (en) * 2001-04-05 2003-10-07 Angstron Systems, Inc. Adsorption process for atomic layer deposition
US6635965B1 (en) * 2001-05-22 2003-10-21 Novellus Systems, Inc. Method for producing ultra-thin tungsten layers with improved step coverage
US6730367B2 (en) * 2002-03-05 2004-05-04 Micron Technology, Inc. Atomic layer deposition method with point of use generated reactive gas species

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US662517A (en) * 1900-06-28 1900-11-27 James Barlow Valve.
SE393967B (en) * 1974-11-29 1977-05-31 Sateko Oy PROCEDURE AND PERFORMANCE OF LAYING BETWEEN THE STORAGE IN A LABOR PACKAGE
JPS6219582A (en) 1985-07-19 1987-01-28 Agency Of Ind Science & Technol Production of gamma-thiobutyrolactone derivative
JPS62192582A (en) * 1986-02-19 1987-08-24 Hitachi Ltd Vacuum evacuation device
JPS6421080A (en) * 1987-07-17 1989-01-24 Sumitomo Metal Ind Plasma cvd device
JPH01187380A (en) * 1988-01-19 1989-07-26 Seiko Epson Corp Vacuum processor
JPH01189114A (en) * 1988-01-25 1989-07-28 Nec Corp Vapor growth apparatus
JPH02220367A (en) * 1989-02-20 1990-09-03 Furukawa Electric Co Ltd:The Secondary battery
NO166460C (en) * 1989-05-23 1991-07-31 Amund Lie Three-way butterfly valves.
US5266296A (en) * 1991-01-22 1993-11-30 General Chemical Corporation Cocurrent flow process for the manufacture of sodium sulfite and bisulfite solutions
JP3130374B2 (en) * 1992-06-17 2001-01-31 株式会社日立製作所 Method for manufacturing semiconductor device
JP3107275B2 (en) * 1994-08-22 2000-11-06 東京エレクトロン株式会社 Semiconductor manufacturing apparatus and semiconductor manufacturing apparatus cleaning method
KR0183912B1 (en) * 1996-08-08 1999-05-01 김광호 Pumping facility connected to the multi-reaction chamber and method thereof
JPH11222677A (en) 1998-02-03 1999-08-17 Shimadzu Corp Film forming device
JPH11222678A (en) * 1998-02-03 1999-08-17 Shimadzu Corp Film forming device
US6572924B1 (en) * 1999-11-18 2003-06-03 Asm America, Inc. Exhaust system for vapor deposition reactor and method of using the same
JP4174941B2 (en) * 2000-02-03 2008-11-05 株式会社デンソー Thin film manufacturing method and thin film manufacturing apparatus
US6306247B1 (en) * 2000-04-19 2001-10-23 Taiwan Semiconductor Manufacturing Company, Ltd Apparatus and method for preventing etch chamber contamination
US6503379B1 (en) * 2000-05-22 2003-01-07 Basic Research, Inc. Mobile plating system and method
JP3989205B2 (en) * 2000-08-31 2007-10-10 松下電器産業株式会社 Method for forming CVD film
US6852167B2 (en) * 2001-03-01 2005-02-08 Micron Technology, Inc. Methods, systems, and apparatus for uniform chemical-vapor depositions
US6893506B2 (en) * 2002-03-11 2005-05-17 Micron Technology, Inc. Atomic layer deposition apparatus and method
KR100498467B1 (en) * 2002-12-05 2005-07-01 삼성전자주식회사 Apparatus for atomic layer deposition with preventing powder generation in exhaust paths
US20040178175A1 (en) * 2003-03-12 2004-09-16 Pellin Michael J. Atomic layer deposition for high temperature superconductor material synthesis
US7647886B2 (en) * 2003-10-15 2010-01-19 Micron Technology, Inc. Systems for depositing material onto workpieces in reaction chambers and methods for removing byproducts from reaction chambers

Patent Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4793283A (en) * 1987-12-10 1988-12-27 Sarkozy Robert F Apparatus for chemical vapor deposition with clean effluent and improved product yield
US5000225A (en) * 1989-11-17 1991-03-19 Applied Materials, Inc. Low profile, combination throttle/gate valve for a multi-pump chamber
US5286296A (en) * 1991-01-10 1994-02-15 Sony Corporation Multi-chamber wafer process equipment having plural, physically communicating transfer means
US5242539A (en) * 1991-04-04 1993-09-07 Hitachi, Ltd. Plasma treatment method and apparatus
US5391260A (en) * 1992-03-27 1995-02-21 Hitachi, Ltd. Vacuum processing apparatus
US5607510A (en) * 1992-03-27 1997-03-04 Hitachi, Ltd. Vacuum processing apparatus
US5746581A (en) * 1994-06-28 1998-05-05 Ebara Corporation Method and apparatus for evacuating vacuum system
US6206970B1 (en) * 1997-09-03 2001-03-27 Micron Technology, Inc. Semiconductor wafer processor, semiconductor processor gas filtering system and semiconductor processing methods
US6270572B1 (en) * 1998-08-07 2001-08-07 Samsung Electronics Co., Ltd. Method for manufacturing thin film using atomic layer deposition
US6214120B1 (en) * 1999-08-27 2001-04-10 Innovac Corporation High throughput multi-vacuum chamber system for processing wafers and method of processing wafers using the same
US6511539B1 (en) * 1999-09-08 2003-01-28 Asm America, Inc. Apparatus and method for growth of a thin film
US6316045B1 (en) * 2000-04-20 2001-11-13 Alcatel Method and apparatus for conditioning the atmosphere in a process chamber
US6630201B2 (en) * 2001-04-05 2003-10-07 Angstron Systems, Inc. Adsorption process for atomic layer deposition
US6635965B1 (en) * 2001-05-22 2003-10-21 Novellus Systems, Inc. Method for producing ultra-thin tungsten layers with improved step coverage
US6391803B1 (en) * 2001-06-20 2002-05-21 Samsung Electronics Co., Ltd. Method of forming silicon containing thin films by atomic layer deposition utilizing trisdimethylaminosilane
US6461436B1 (en) * 2001-10-15 2002-10-08 Micron Technology, Inc. Apparatus and process of improving atomic layer deposition chamber performance
US20030153177A1 (en) * 2002-02-11 2003-08-14 Applied Materials, Inc. Variable flow deposition apparatus and method in semiconductor substrate processing
US6730367B2 (en) * 2002-03-05 2004-05-04 Micron Technology, Inc. Atomic layer deposition method with point of use generated reactive gas species

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006111617A1 (en) * 2005-04-22 2006-10-26 Beneq Oy Reactor
US20090031947A1 (en) * 2005-04-22 2009-02-05 Beneq Oy Reactor
WO2020131193A1 (en) * 2018-12-21 2020-06-25 Applied Materials, Inc. Ald process and hardware with improved purge efficiency
US10964533B2 (en) 2018-12-21 2021-03-30 Applied Materials, Inc. ALD process and hardware with improved purge efficiency
US11664216B2 (en) 2018-12-21 2023-05-30 Applied Materials, Inc. ALD process and hardware with improved purge efficiency

Also Published As

Publication number Publication date
US20030170403A1 (en) 2003-09-11
US7030037B2 (en) 2006-04-18
US20060144333A1 (en) 2006-07-06
US20050142890A1 (en) 2005-06-30
US7431773B2 (en) 2008-10-07
US6893506B2 (en) 2005-05-17

Similar Documents

Publication Publication Date Title
US7030037B2 (en) Atomic layer deposition apparatus and method
US7000636B2 (en) Valve assemblies for use with a reactive precursor in semiconductor processing
US20060175012A1 (en) Semiconductor fabrication equipment and method for controlling pressure
EP1817500B1 (en) Fore-line preconditioning for vacuum pumps
EP0903769B1 (en) Spatially uniform gas supply and pump configuration for large wafer diameters
JP4979763B2 (en) Vacuum exhaust system
US20160222509A1 (en) Substrate processing apparatus
US8067061B2 (en) Reaction apparatus having multiple adjustable exhaust ports
CN105765697A (en) Tilted plate for batch processing and methods of use
JP2007247066A (en) Semiconductor-processing apparatus with rotating susceptor
US11437249B2 (en) Showerhead device for semiconductor processing system
KR20050114234A (en) Methods and apparatus for atomic layer deposition
WO2000053928A1 (en) Vacuum device
US20010001950A1 (en) Vacuum exhaust system
CN101665920A (en) Film deposition apparatus, substrate process apparatus, and turntable
US11244822B2 (en) Apparatus for manufacturing a thin film and a method therefor
US8671965B2 (en) Methods for enhanced fluid delivery on bevel etch applications
US20180197760A1 (en) Dual PVD Chamber And Hybrid PVD-CVD Chambers
JP2007109685A (en) Apparatus and method for manufacturing compound semiconductor
US20030226500A1 (en) Atomic layer deposition apparatus and methods
US20240047232A1 (en) High conductance divert line architecture
US20230381701A1 (en) Particle remover and method
US20210032747A1 (en) Semiconductor processing chambers and methods for cleaning the same
CN112640078A (en) Gas input system for substrate processing chamber
KR20010019991A (en) Thin film deposition system

Legal Events

Date Code Title Description
STCB Information on status: application discontinuation

Free format text: EXPRESSLY ABANDONED -- DURING PUBLICATION PROCESS