US20040077182A1 - Method for forming introgen-containing oxide thin film using plasma enhanced atomic layer deposition - Google Patents

Method for forming introgen-containing oxide thin film using plasma enhanced atomic layer deposition Download PDF

Info

Publication number
US20040077182A1
US20040077182A1 US10/377,471 US37747103A US2004077182A1 US 20040077182 A1 US20040077182 A1 US 20040077182A1 US 37747103 A US37747103 A US 37747103A US 2004077182 A1 US2004077182 A1 US 2004077182A1
Authority
US
United States
Prior art keywords
nitrogen
thin film
gas
metal
oxide thin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
US10/377,471
Other versions
US6723642B1 (en
Inventor
Jung-wook Lim
Sun-Jin Yun
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Electronics and Telecommunications Research Institute ETRI
Original Assignee
Electronics and Telecommunications Research Institute ETRI
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Electronics and Telecommunications Research Institute ETRI filed Critical Electronics and Telecommunications Research Institute ETRI
Assigned to ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTITUTE reassignment ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTITUTE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: LIM, JUNG-WOOK, YUN, SUN-JIN
Application granted granted Critical
Publication of US6723642B1 publication Critical patent/US6723642B1/en
Publication of US20040077182A1 publication Critical patent/US20040077182A1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/20—Deposition of semiconductor materials on a substrate, e.g. epitaxial growth solid phase epitaxy
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/308—Oxynitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • C23C16/45523—Pulsed gas flow or change of composition over time
    • C23C16/45525—Atomic layer deposition [ALD]
    • C23C16/45527—Atomic layer deposition [ALD] characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations
    • C23C16/45529—Atomic layer deposition [ALD] characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations specially adapted for making a layer stack of alternating different compositions or gradient compositions
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • C23C16/45523—Pulsed gas flow or change of composition over time
    • C23C16/45525—Atomic layer deposition [ALD]
    • C23C16/45527—Atomic layer deposition [ALD] characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations
    • C23C16/45536—Use of plasma, radiation or electromagnetic fields
    • C23C16/45542—Plasma being used non-continuously during the ALD reactions
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/50—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104—Forming layers
    • H01L21/02107—Forming insulating materials on a substrate
    • H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
    • H01L21/0226—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
    • H01L21/02263—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
    • H01L21/02271—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
    • H01L21/02274—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition in the presence of a plasma [PECVD]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104—Forming layers
    • H01L21/02107—Forming insulating materials on a substrate
    • H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
    • H01L21/0226—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
    • H01L21/02263—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
    • H01L21/02271—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
    • H01L21/0228—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition deposition by cyclic CVD, e.g. ALD, ALE, pulsed CVD
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/314—Inorganic layers
    • H01L21/3143—Inorganic layers composed of alternated layers or of mixtures of nitrides and oxides or of oxinitrides, e.g. formation of oxinitride by oxidation of nitride layers
    • H01L21/3145—Inorganic layers composed of alternated layers or of mixtures of nitrides and oxides or of oxinitrides, e.g. formation of oxinitride by oxidation of nitride layers formed by deposition from a gas or vapour
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104—Forming layers
    • H01L21/02107—Forming insulating materials on a substrate
    • H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
    • H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
    • H01L21/02172—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing at least one metal element, e.g. metal oxides, metal nitrides, metal oxynitrides or metal carbides
    • H01L21/02175—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing at least one metal element, e.g. metal oxides, metal nitrides, metal oxynitrides or metal carbides characterised by the metal
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/314—Inorganic layers
    • H01L21/316—Inorganic layers composed of oxides or glassy oxides or oxide based glass
    • H01L21/31604—Deposition from a gas or vapour
    • H01L21/31616—Deposition of Al2O3

Definitions

  • the present invention relates to a method for forming an insulating thin film in the manufacture of a variety of electronic devices, and more particularly, to a method for forming a metal oxide thin film using atomic layer deposition (ALD).
  • ALD atomic layer deposition
  • insulating films for electronic devices have been formed using physical vapor deposition (PVD) or chemical vapor deposition (CVD). Recently, the application of atomic layer deposition (ALD) in forming such insulating films is gradually increasing.
  • ALD atomic layer deposition
  • the source gases are supplied sequentially into a reactor at predetermined time intervals as pulses by timely opening and closing gas supply valves for the source gases positioned near the entrance of the reactor.
  • a purge gas is supplied following each pulsing source gases at a predetermined rate to remove the remaining, un-reacted gas from the reactor. More recently, plasma enhanced ALD has been suggested for film formation.
  • Various kinds of insulating films used in the semiconductor field and which can be formed by ALD include, for example, gate dielectrics having a very small thickness requirement, capacitor dielectric layers, and insulating oxide layers.
  • the use of Al 2 O 3 , ZrO 2 , or HfO 2 for gate dielectrics and Al 2 O 3 , Ta 2 O 5 , or (Ba, Sr)TiO 3 for capacitor dielectric layers have been investigated more actively in conjunction with the application of ALD. As a result, it was found that an Al 2 O 3 film having a very uniform thickness can be formed through accurate film thickness control using ALD (Journal of the Electrochemical Society, 149(6), pp. C306(2002)).
  • ALD has been applied in the display device field as well as in the semiconductor field. Research has been conducted on ALD for a large-sized, thin film display having good step coverage and easy thickness control requirements. For example, for an electroluminescence display (ELD) formed by sequentially depositing a phosphor layer and an insulating layer, ALD involving in situ sequential deposition of these layers within the same reactor is preferred. An Al 2 O 3 or an aluminum titanium oxide (ATO) layer is mostly used for the insulating layer. An Al 2 O 3 layer formed using ALD is known to be denser and more uniform in thickness as compared with that formed using PVD or CVD.
  • ELD electroluminescence display
  • ATO aluminum titanium oxide
  • the insulating layer deposited by ALD has a higher density and more uniform thickness, its electrical insulating properties should be strong enough to resist a high field strength for use in ELDs.
  • the thickness of the insulating layer is increased to prevent a breakdown, the threshold voltage for electroluminescenece may increase. Therefore, what is needed in the ELD field is a method for forming an insulating layer having a large dielectric constant and a high breakdown voltage even with a small thickness.
  • the present invention provides a method for forming an insulating layer, and more particularly, a metal oxide layer having a large dielectric constant and a high breakdown voltage even with a small thickness.
  • the metal oxide thin film is formed on a substrate by supplying a metal source compound and oxygen gas into a reactor in a cyclic fashion with sequential alternating pulses of the metal source compound and the oxygen gas, wherein the oxygen gas is activated into plasma in synchronization of the pulsing thereof, and a nitrogen source gas is further sequentially pulsed into the reactor and activated into plasma over the substrate in synchronization with the pulsing thereof.
  • the invention is directed to the formation of a metal oxide thin film containing a trace of nitrogen by plasma enhanced atomic layer deposition (PEALD).
  • PEALD plasma enhanced atomic layer deposition
  • the thin film formation method according to the present invention is based on ALD, the advantages of ALD, such as the ability to grow a dense, uniform thin film, are ensured.
  • the use of plasma in the present invention further increases the density of the thin film and the growth rate.
  • a trace of nitrogen atoms can be incorporated in situ into the thin film being grown, the resulting thin film is provided with improved breakdown characteristics. The added nitrogen atoms improve the passivation properties for the incorporation of moist or impurities as well as the electrical properties.
  • a nitrogen-containing Al 2 O 3 thin film may be formed.
  • the nitrogen-containing Al 2 O 3 thin film according to the present invention has a high dielectric constant and can be used as a dielectric film for gate dielectric or memory dielectric layers of next generation semiconductor devices.
  • the nitrogen-containing Al 2 O 3 thin film can be applied to a various kinds of electronic devices as passivation purposes in order to prevent the incorporation of moist or impurities.
  • the nitrogen-containing Al 2 O 3 thin film is very suitable to be used as an insulating layer that is deposited on or underneath the phosphor layer of an electroluminescence device.
  • FIGS. 1 through 4 are gas pulsing diagrams applied in forming a nitrogen-containing metal oxide film using plasma enhanced atomic layer deposition (PEALD) according to the present invention
  • FIG. 5 is a sectional view showing an example of a nitrogen-containing metal oxide thin film formed using the PEALD method according to the present invention as an insulating layer;
  • FIG. 6 is a sectional view showing another example of a nitrogen-containing metal oxide thin film formed using the PEALD method according to the present invention as an insulating layer;
  • FIG. 7 is a sectional view of an electroluminescence display that can be manufactured using the thin film formation method according to the present invention.
  • FIG. 8 is a graph comparatively showing the breakdown characteristics of a nitrogen-containing Al 2 O 3 thin film formed according to the present invention and an Al 2 O 3 thin film formed by a conventional ALD;
  • FIG. 9 is a graph comparatively showing the luminance of electroluminescence devices using Al 2 O 3 thin films containing and not containing nitrogen, respectively.
  • a metal source compound and oxygen gas as a reactant gas are supplied into the reactor in a cyclic fashion with sequential alternating pulses of the metal source compound and oxygen gas, wherein the oxygen gas is activated into plasma over the substrate in synchronization with the pulsing thereof.
  • the oxygen gas is decomposed into oxygen radicals or ions to activate reaction.
  • nitrogen source gas is further supplied, wherein the nitrogen source gas is activated into plasma over the substrate in synchronization with the pulsing thereof.
  • a metal oxide thin film having optimal properties can be formed by appropriately controlling the flow rates of the nitrogen source gas and the oxygen gas.
  • the nitrogen source gas may be nitrogen gas (N 2 ), ammonia gas (NH 3 ), nitrogen dioxide gas (NO 2 ), nitrogen hypooxide gase (N 2 O), or a mixture of the foregoing gases.
  • nitrogen gas nitrogen gas
  • NH 3 ammonia gas
  • NO 2 nitrogen dioxide gas
  • N 2 O nitrogen hypooxide gase
  • the pulsing cycle can be varied according to the way nitrogen source gas is added into the metal oxide layer.
  • FIGS. 1 through 4 are gas pulsing diagrams applied in forming a nitrogen-containing metal oxide film using plasma enhanced atomic layer deposition (PEALD) according to the present invention.
  • a variety of pulsing cycles illustrated in FIGS. 1 through 4 include both cases of supplying source gases into the reactor after and without dilution with inert carrier gas.
  • Suitable examples of carrier gases include helium gas as well as argon gas.
  • the carrier gas serves as a purging gas to remove the remaining unreacted gas from the reactor while the supply of the source gases is suspended, as well as serves as a carrier for the metal source compound.
  • the metal oxide may be Al 2 O 3 , Ta 2 O 5 , TiO 2 , ZrO 2 , HfO 2 , or lanthanide series oxide.
  • Suitable metal source compounds include chlorides and organic materials.
  • metal source compounds [(Ta(OC 2 H 5 ) 4 )(OCH 2 CH 2 N(CH 3 ) 2 )] known as TAE(dmae) may be used for a nitrogen-containing Ta 2 O 5 thin film, trimethylaluminum (TMA) may be used for a nitrogen-containing Al 2 O 3 thin film, tetrakis(dimethylamido)titanium known as TDMAT or titanium of tetra-isopropoxide may be used for a nitrogen-containing TiO 2 thin film.
  • TAE(dmae) trimethylaluminum
  • TDMAT tetrakis(dimethylamido)titanium
  • titanium of tetra-isopropoxide may be used for a nitrogen
  • a nitrogen source gas is supplied in synchronization with the supply of oxygen gas as reactant gases.
  • a metal precursor metal source compound
  • a metal source supply valve which is indicated as “ON” state in FIG. 1
  • a carrier gas supplied at a flow rate of 200 sccm through the top and/or sidewall of the reactor.
  • the metal source supply valve is closed, which is indicated as “OFF” state in FIG. 1, while the carrier gas is continuously supplied to purge a physisorbed metal source compound on the wafer or the unreacted, remaining metal source compound from the reactor.
  • oxygen gas at a rate of 30-100 sccm and nitrogen source gas at an appropriate rate are simultaneously supplied to generate plasma of these gases in a synchronous manner.
  • An RF source power for example, of 200-400W for a 12-inch wafer is applied.
  • the flow rate of the nitrogen source gas is adjusted according to the kind of nitrogen source gas used, for example, to about 5-15 sccm when nitrogen gas is selected. As described above, these gases may be supplied while being diluted with the carrier gas or may be supplied separately from the carrier gas.
  • the total flow rate of the carrier gas supplied into the reactor is controlled to a large quantity, for example 500-600 sccm, but needs to be varied appropriately for different reactors.
  • an oxygen gas supply valve and a nitrogen source gas supply valve are closed, and a source power switch is turned off, so that only the carrier gas is supplied to purge physisorbed or unreacted remaining gases from the reactor.
  • the metal source compound supply valve is opened, thereby terminating one cycle.
  • the duration of purging between each supply of source and reactant gases is adjusted according to the kind of metal source compound used.
  • One cycle period is about 6-7 seconds. This cycle is repeated until a metal oxide thin film having a desired thickness is obtained.
  • the reactant gases are activated into plasma, reactions with the metal source compound adsorbed on the wafer is facilitated, and activation energy is supplied to the resulting thin film, thereby greatly improving the crystalline and physical properties of the film.
  • the resulting metal oxide thin film further contains nitrogen atoms due to the supply of the nitrogen source gas. The nitrogen atoms in the metal oxide thin film increase the breakdown voltage of the metal oxide thin film.
  • the oxygen gas and the nitrogen source gas may be supplied separately to generate plasma in an asynchronous manner, as illustrated in FIGS. 2 and 3.
  • nitrogen source gas plasma is generated.
  • oxygen plasma is generated.
  • the amount of nitrogen atoms incorporated into the metal oxide thin film and its electrical properties differ according to the kind of nitrogen source gas used, even with the application of an equal intensity of RF source power.
  • the breakdown characteristics of the nitrogen-containing metal oxide thin film are always better than non-nitrogen containing metal oxide thin films. It is effective to use nitrogen gas, which is known to be less likely to decompose than ammonia gas, in order to incorporate a trace of nitrogen atoms into metal oxide thin films.
  • plasma can be generated from ammonia gas or nitrogen dioxide gas, instead of nitrogen gas.
  • nitrogen dioxide or nitrogen hypooxide gas is used for the nitrogen source gas
  • supplying oxygen gas to generate plasma may be omitted because these gases inherently contain both nitrogen and oxygen atoms, as illustrated in FIG. 4.
  • the oxygen gas may be supplied further together with or separately from nitrogen dioxide or nitrogen hypooxide gas.
  • a nitrogen-containing oxide thin film according to the present invention can be formed with uniformity in thickness and high density, which are advantages of conventional ALD, and at high growth rate.
  • the high density of the insulating layer increases the breakdown voltage, so that all pixels of an ELD can be protected from a breakdown even at a high voltage level, thereby improving the stability of the ELD and reducing the leakage current.
  • the nitrogen-containing oxide thin film according to the present invention instead of an Al 2 O 3 or ATO layer, is used as an insulating film for an ELD device, the stability to a high voltage is ensured, and all the pixels are highly likely to be protected without defect. Accordingly, the thickness of the insulating layer can be reduced, providing an effect of reducing the threshold voltage.
  • a nitrogen-containing metal oxide thin film formed using the method according to the present invention having a multi-layered structure, as shown in FIGS. 5 and 6, be applied as an insulating layer to be formed on the phosphor layer for an ELD.
  • a buffer layer 10 is formed on the phosphor layer 5 .
  • the buffer layer 10 is a metal oxide thin film formed by general ALD without using plasma. Accordingly, no plasma damage appears in the interface between the phosphor layer 5 and the buffer layer 10 .
  • a nitrogen-containing metal oxide thin film 20 having good breakdown properties is grown using PEALD. During the formation of the nitrogen-containing metal oxide thin film 20 , the phosphor layer 5 can be protected from plasma damage due to the buffer layer 10 covering the same.
  • the buffer layer 10 and the nitrogen-containing metal oxide thin film 20 may be grown in situ within the same reactor.
  • the substrate may be prepared to have a second metal oxide thin film by supplying in a cyclic fashion sequentially alternating pulses of a second metal source compound and oxygen gas into the reactor, followed by the formation of the nitrogen-containing metal oxide film 20 according to the present invention according to any pulsing scheme illustrated in FIGS. 1 through 4.
  • the buffer layer 10 may be the same kind or a different kind of metal oxide from the nitrogen-containing metal oxide layer 20 according to the present invention.
  • the buffer layer 10 may be formed in combination with the metal oxide layer 20 .
  • the buffer layer 10 may be a TiO 2 thin film grown using general ALD, whereas the nitrogen-containing method oxide thin film 20 may be a nitrogen-containing Al 2 O 3 thin film grown using PEALD.
  • the buffer layer 10 may be an Al 2 O 3 thin film grown using general ALD, whereas the nitrogen-containing metal oxide thin film 20 may be a nitrogen-containing Al 2 O 3 thin film grown using PEALD.
  • TMA may be used as a common metal source compound.
  • the order of depositing layers is reversed with respect to the order described with reference to FIG. 5.
  • the buffer layer 10 is grown thereon using general ALD, and then the phosphor layer 5 is formed on the buffer layer 10 .
  • the density of interface electron traps between the phosphor layer 5 and the buffer layer 10 can be maintained to be high.
  • the buffer layer 10 and the nitrogen-containing metal oxide thin film 20 may be formed alternately several times using general ALD and PEALD according to the present invention, respectively, to have a multi-layered structure on the phosphor layer 5 , as shown in FIG. 6.
  • the buffer layer 10 and the nitrogen-containing metal oxide thin film 20 may be formed of the same kind of metal oxide or different kinds of metal oxides.
  • the insulating layer having such a stacked structure as described with reference to FIGS. 5 and 6 is advantageous for the gate dielectric layer of a semiconductor device as well as an insulating layer for an ELD. Since the gate dielectric layer requires good interfacial properties, it should be protected from plasma damage. Therefore, an oxide film is formed near a wafer using general ALD, and a nitrogen-containing metal oxide thin film is grown on the oxide film using PEALD according to the present invention to increase breakdown resistance.
  • the physical thickness of the oxide film can be increased for a small equivalent oxide thickness of about 20 ⁇ , so that it is easy to control the thickness of the oxide film.
  • FIG. 7 is a sectional view of an ELD device that can be manufactured based on the concept described above.
  • a lower electrode 102 , a lower insulating layer 120 , a buffer insulating layer 110 , a phosphor layer 105 , a buffer layer 10 , an upper insulating layer 120 , and an upper electrode 103 are sequentially stacked on a substrate 101 .
  • the lower and upper insulating layers 120 are nitrogen-containing metal oxide thin films formed using the method according to the present invention.
  • nitrogen gas is used as a nitrogen source gas, it is preferable that the upper and lower insulating layers 120 be formed as Al 2 O 3 thin films containing nitrogen less than 1 atomic %.
  • the substrate 101 is preferably a glass substrate and has a thickness of about 1 mm.
  • the lower electrode 102 is a transparent electrode formed of, for example, indium tin oxide (ITO), zinc oxide (ZnO), etc., to have a thickness of about 1000-2000 ⁇ .
  • the buffer insulating layer 110 is formed of an insulating material, such as Al 2 O 3 , SiO 2 , TiO 2 , etc., using general ALD, as described above.
  • the phosphor layer 105 may be formed of a red-yellow phosphor, such as ZnS:Mn, or a blue-green phosphor, such as SrS:Ce or CaS:Pb.
  • the upper electrode 103 is an opaque metal electrode formed by depositing Al to a thickness of about 1000-2000 ⁇ . Therefore, luminescence can be observed through the transparent substrate 101 .
  • the substrate 101 may be a silicon substrate.
  • the lower electrode 102 is an opaque metal electrode
  • the upper electrode 103 is a transparent electrode, so that luminescence can be observed through the upper electrode 103 .
  • An insulating layer contacting the phosphor layer in an ELD determines the quantity of electrons entering the phosphor layer under an electric field applied.
  • the surface electron energy level in the interface between the insulating layer and the phosphor layer is a source to supply electrons into the phosphor layer.
  • a higher surface electron energy level results in a higher probability of electrons entering the phosphor layer.
  • the effective surface electron energy level is proportional to the dielectric constant of the insulating layer.
  • the breakdown spreads, causing current leakage and dispersing the electric field.
  • the nitrogen-containing metal oxide thin film according to the present invention has a high dielectric constant, a breakdown unlikely occurs, and no damage to the electric field occurs. This is considered because an electric path is blocked as the trace of nitrogen atoms added binds to an oxygen network of the oxide thin film.
  • a thick insulating layer is required to prevent a breakdown.
  • it causes the problem of an increase in the threshold voltage of devices.
  • the nitrogen-containing metal oxide thin film according to the present invention is formed to be as thin as 150-160 nm for a 1 ⁇ m-thick phosphor layer, no breakdown occurs.
  • the nitrogen-containing Al 2 O 3 thin film according to the present invention was deposited under the following experimental conditions.
  • TMA was used as a metal source compound.
  • Argon gas was flowed at a rate of 200 sccm to carry TMA while maintaining the total flow rate to 600 sccm.
  • the process was performed at an oxygen flow rate of 50 sccm, a nitrogen gas flow rate of 5-10 sccm, an RF source power of 300 W, a reactor pressure of 3 torr, and a temperature of 250-300° C.
  • One cycle period was controlled to 6-7 seconds, and oxygen gas and nitrogen gas were simultaneously supplied according to the gas pulsing scheme illustrated in FIG. 1.
  • Al 2 O 3 thin film was grown according to the conventional ALD method under the same conditions as for the nitrogen-containing Al 2 O 3 thin film according to the present invention, except that no plasma was generated and no nitrogen gas was supplied. In both cases, the Al 2 O 3 thin films were formed to a thickness of about 50 nm.
  • FIG. 8 is a graph comparatively showing the breakdown characteristics of the Al 2 O 3 thin films formed, respectively, using the ALD and PEALD methods.
  • graph (a) is for the Al 2 O 3 thin film formed using the general ALD method.
  • a soft breakdown 40 occurred at an electrical field strength of about 3 MV/cm.
  • the conventional Al 2 O 3 thin film was formed at 250° C.
  • the breakdown voltage decreases to 7 MV/cm.
  • Al 2 O 3 thin film formed by ALD is known to undergo a breakdown at an electrical field strength of 5-6 MV/cm or less.
  • the Al 2 O 3 thin film formed in the present experimental example using the ALD method for a comparison with the nitrogen-containing Al 2 O 3 thin film according to the present invention is considered to have better quality than average.
  • graph (b) shows the breakdown characteristics of the nitrogen-containing Al 2 O 3 thin film formed using the PEALD method according to the present invention.
  • This nitrogen-containing Al 2 O 3 thin film was formed at 300° C. Apparently, a breakdown occurred at an electrical field strength of about 9.5-10 MV/cm.
  • the breakdown voltage of the nitrogen-containing Al 2 O 3 thin film according to the present invention is higher than that of the conventional Al 2 O 3 thin film by about 2.5-3 MV/cm, which is an increase that is almost constant over the entire area. Accordingly, the nitrogen-containing Al 2 O 3 thin film according to the present invention shows stable resistance to a breakdown at every position on the substrate.
  • FIG. 9 is a graph comparatively showing the luminance of ELDs, one having an Al 2 O 3 thin film containing no nitrogen and grown only using TMA and oxygen gas by PELAD, and the other having a nitrogen-containing Al 2 O 3 thin film according to the present invention.
  • ZnS:Mn was used for the phosphor layer.
  • the phosphor layer was formed to be as thick as 1 ⁇ m, and the Al 2 O 3 thin film containing or not containing nitrogen was formed to be as thin as 150-160 nm.
  • graph (a) is for the ELD having the Al 2 O 3 thin film grown using PEALD not to contain nitrogen for a comparison with the present invention. This ELD was stable at a voltage 20 V higher than the threshold voltage.
  • Graph (b) is for the ELD having the nitrogen-containing Al 2 O 3 thin film grown using PEALD according to the present invention. This ELD was stable at a voltage 100 V higher than the threshold voltage.
  • the nitrogen-containing Al 2 O 3 thin film according to the present invention provides more improvements, when applied to a device, than just improving the breakdown voltage of the film as shown in FIG. 8.
  • the nitrogen-containing Al 2 O 3 thin film increased the luminance of the ELD.
  • the thickness of the insulating layer can be reduced, thereby further reducing the threshold voltage.
  • the metal oxide film containing no nitrogen is formed on a relatively thick phosphor layer using general ALD or PEALD, it is required to increase the thickness of the metal oxide film to be greater than that of the nitrogen-containing metal oxide thin film according to the present invention, in order to ensure stable operation of the device.
  • the threshold voltage increases.
  • the nitrogen-containing oxide thin film according to the present invention has improved electrical characteristics, particularly, in breakdown resistance, and can be applied to devices with improved operational stability.
  • a feature of the present invention lies in the improvement of the characteristics of films through the addition of nitrogen into an oxide thin film.
  • the various methods of adding nitrogen in situ, as taught above, to implement the present invention are more significant in the present invention than the fact of adding nitrogen itself.

Abstract

A method for forming a nitrogen-containing oxide thin film by using plasma enhanced atomic layer deposition is provided. In the method, the nitrogen-containing oxide thin film is deposited by supplying a metal source compound and oxygen gas into a reactor in a cyclic fashion with sequential alternating pulses of the metal source compound and the oxygen gas, wherein the oxygen gas is activated into plasma in synchronization of the pulsing thereof, and a nitrogen source gas is further sequentially pulsed into the reactor and activated into plasma over the substrate in synchronization with the pulsing thereof. According to the method, a dense nitrogen-containing oxide thin film can be deposited at a high rate, and a trace of nitrogen atoms can be incorporated in situ into the nitrogen-containing oxide thin film, thereby increasing the breakdown voltage of the film.

Description

    BACKGROUND OF THE INVENTION
  • This application claims priority from Korean Patent Application No. 2002-64524, filed on Oct. 22, 2002, in the Korean Intellectual Property Office, the disclosure of which is incorporated herein in its entirety by reference. [0001]
  • 1. Field of the Invention [0002]
  • The present invention relates to a method for forming an insulating thin film in the manufacture of a variety of electronic devices, and more particularly, to a method for forming a metal oxide thin film using atomic layer deposition (ALD). [0003]
  • 2. Description of the Related Art [0004]
  • Generally, insulating films for electronic devices have been formed using physical vapor deposition (PVD) or chemical vapor deposition (CVD). Recently, the application of atomic layer deposition (ALD) in forming such insulating films is gradually increasing. As is well known, rather than simultaneously supplying source gases into a reactor, ALD involves sequentially alternating pulses of different kinds of source gases to form a thin film. In particular, the source gases are supplied sequentially into a reactor at predetermined time intervals as pulses by timely opening and closing gas supply valves for the source gases positioned near the entrance of the reactor. In general, a purge gas is supplied following each pulsing source gases at a predetermined rate to remove the remaining, un-reacted gas from the reactor. More recently, plasma enhanced ALD has been suggested for film formation. [0005]
  • Various kinds of insulating films used in the semiconductor field and which can be formed by ALD include, for example, gate dielectrics having a very small thickness requirement, capacitor dielectric layers, and insulating oxide layers. The use of Al[0006] 2O3, ZrO2, or HfO2 for gate dielectrics and Al2O3, Ta2O5, or (Ba, Sr)TiO3 for capacitor dielectric layers have been investigated more actively in conjunction with the application of ALD. As a result, it was found that an Al2O3 film having a very uniform thickness can be formed through accurate film thickness control using ALD (Journal of the Electrochemical Society, 149(6), pp. C306(2002)).
  • ALD has been applied in the display device field as well as in the semiconductor field. Research has been conducted on ALD for a large-sized, thin film display having good step coverage and easy thickness control requirements. For example, for an electroluminescence display (ELD) formed by sequentially depositing a phosphor layer and an insulating layer, ALD involving in situ sequential deposition of these layers within the same reactor is preferred. An Al[0007] 2O3 or an aluminum titanium oxide (ATO) layer is mostly used for the insulating layer. An Al2O3 layer formed using ALD is known to be denser and more uniform in thickness as compared with that formed using PVD or CVD.
  • Although the insulating layer deposited by ALD has a higher density and more uniform thickness, its electrical insulating properties should be strong enough to resist a high field strength for use in ELDs. However, if the thickness of the insulating layer is increased to prevent a breakdown, the threshold voltage for electroluminescenece may increase. Therefore, what is needed in the ELD field is a method for forming an insulating layer having a large dielectric constant and a high breakdown voltage even with a small thickness. [0008]
    • SUMMARY OF THE INVENTION
  • The present invention provides a method for forming an insulating layer, and more particularly, a metal oxide layer having a large dielectric constant and a high breakdown voltage even with a small thickness. [0009]
  • According to an aspect of the present invention, there is provided a method for incorporating nitrogen atoms into a metal oxide thin film in situ using plasma based on conventional atomic layer deposition (ALD). In particular, the metal oxide thin film is formed on a substrate by supplying a metal source compound and oxygen gas into a reactor in a cyclic fashion with sequential alternating pulses of the metal source compound and the oxygen gas, wherein the oxygen gas is activated into plasma in synchronization of the pulsing thereof, and a nitrogen source gas is further sequentially pulsed into the reactor and activated into plasma over the substrate in synchronization with the pulsing thereof. In other words, the invention is directed to the formation of a metal oxide thin film containing a trace of nitrogen by plasma enhanced atomic layer deposition (PEALD). [0010]
  • Since the thin film formation method according to the present invention is based on ALD, the advantages of ALD, such as the ability to grow a dense, uniform thin film, are ensured. In addition, the use of plasma in the present invention further increases the density of the thin film and the growth rate. Furthermore, since a trace of nitrogen atoms can be incorporated in situ into the thin film being grown, the resulting thin film is provided with improved breakdown characteristics. The added nitrogen atoms improve the passivation properties for the incorporation of moist or impurities as well as the electrical properties. [0011]
  • In an embodiment of the present invention, a nitrogen-containing Al[0012] 2O3 thin film may be formed. The nitrogen-containing Al2O3 thin film according to the present invention has a high dielectric constant and can be used as a dielectric film for gate dielectric or memory dielectric layers of next generation semiconductor devices. In addition, the nitrogen-containing Al2O3 thin film can be applied to a various kinds of electronic devices as passivation purposes in order to prevent the incorporation of moist or impurities. In addition, the nitrogen-containing Al2O3 thin film is very suitable to be used as an insulating layer that is deposited on or underneath the phosphor layer of an electroluminescence device.
    •  BRIEF DESCRIPTION OF THE DRAWINGS
  • The above and other features and advantages of the present invention will become more apparent by describing in detail exemplary embodiments thereof with reference to the attached drawings in which: [0013]
  • FIGS. 1 through 4 are gas pulsing diagrams applied in forming a nitrogen-containing metal oxide film using plasma enhanced atomic layer deposition (PEALD) according to the present invention; [0014]
  • FIG. 5 is a sectional view showing an example of a nitrogen-containing metal oxide thin film formed using the PEALD method according to the present invention as an insulating layer; [0015]
  • FIG. 6 is a sectional view showing another example of a nitrogen-containing metal oxide thin film formed using the PEALD method according to the present invention as an insulating layer; [0016]
  • FIG. 7 is a sectional view of an electroluminescence display that can be manufactured using the thin film formation method according to the present invention; [0017]
  • FIG. 8 is a graph comparatively showing the breakdown characteristics of a nitrogen-containing Al[0018] 2O3 thin film formed according to the present invention and an Al2O3 thin film formed by a conventional ALD; and
  • FIG. 9 is a graph comparatively showing the luminance of electroluminescence devices using Al[0019] 2O3 thin films containing and not containing nitrogen, respectively.
    • DETAILED DESCRIPTION OF THE INVENTION
  • Embodiments of the present invention will be described in detail with reference to the accompanying drawings. This invention may, however, be embodied in many different forms and should not be construed as being limited to the embodiments set fourth herein; rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the concept of the invention to those skilled in the art. [0020]
  • In a thin film formation method according to the present invention, in order to form a metal oxide film on a substrate loaded into a reactor, a metal source compound and oxygen gas as a reactant gas are supplied into the reactor in a cyclic fashion with sequential alternating pulses of the metal source compound and oxygen gas, wherein the oxygen gas is activated into plasma over the substrate in synchronization with the pulsing thereof. The oxygen gas is decomposed into oxygen radicals or ions to activate reaction. Besides the metal source compound and oxygen gas, nitrogen source gas is further supplied, wherein the nitrogen source gas is activated into plasma over the substrate in synchronization with the pulsing thereof. A metal oxide thin film having optimal properties can be formed by appropriately controlling the flow rates of the nitrogen source gas and the oxygen gas. The nitrogen source gas may be nitrogen gas (N[0021] 2), ammonia gas (NH3), nitrogen dioxide gas (NO2), nitrogen hypooxide gase (N2O), or a mixture of the foregoing gases. When using nitrogen gas, less nitrogen atoms are incorporated into the metal oxide layer for the same level of RF source power as when using ammonia gas. This is considered to be related with the fact that ammonia is more likely to decompose than nitrogen gas for an equal level of source power. The pulsing cycle can be varied according to the way nitrogen source gas is added into the metal oxide layer.
  • FIGS. 1 through 4 are gas pulsing diagrams applied in forming a nitrogen-containing metal oxide film using plasma enhanced atomic layer deposition (PEALD) according to the present invention. A variety of pulsing cycles illustrated in FIGS. 1 through 4 include both cases of supplying source gases into the reactor after and without dilution with inert carrier gas. Suitable examples of carrier gases include helium gas as well as argon gas. The carrier gas serves as a purging gas to remove the remaining unreacted gas from the reactor while the supply of the source gases is suspended, as well as serves as a carrier for the metal source compound. The metal oxide may be Al[0022] 2O3, Ta2O5, TiO2, ZrO2, HfO2, or lanthanide series oxide. Suitable metal source compounds include chlorides and organic materials. For example, as metal source compounds, [(Ta(OC2H5)4)(OCH2CH2N(CH3)2)] known as TAE(dmae) may be used for a nitrogen-containing Ta2O5 thin film, trimethylaluminum (TMA) may be used for a nitrogen-containing Al2O3 thin film, tetrakis(dimethylamido)titanium known as TDMAT or titanium of tetra-isopropoxide may be used for a nitrogen-containing TiO2 thin film.
  • In the case illustrated in FIG. 1, after a metal source compound is supplied into the reactor, a nitrogen source gas is supplied in synchronization with the supply of oxygen gas as reactant gases. In particular, under the conditions of a wafer temperature of 250-400° C. and a reactor pressure of about 3 torr, a metal precursor (metal source compound) in vapor phase is supplied into the reactor by opening a metal source supply valve, which is indicated as “ON” state in FIG. 1, while being diluted with a carrier gas supplied at a flow rate of 200 sccm through the top and/or sidewall of the reactor. After supplying the metal source compound for about 1-2 seconds, only the metal source supply valve is closed, which is indicated as “OFF” state in FIG. 1, while the carrier gas is continuously supplied to purge a physisorbed metal source compound on the wafer or the unreacted, remaining metal source compound from the reactor. [0023]
  • After 2-3 seconds later, while the carrier gas is supplied into the reactor, oxygen gas at a rate of 30-100 sccm and nitrogen source gas at an appropriate rate are simultaneously supplied to generate plasma of these gases in a synchronous manner. An RF source power, for example, of 200-400W for a 12-inch wafer is applied. The flow rate of the nitrogen source gas is adjusted according to the kind of nitrogen source gas used, for example, to about 5-15 sccm when nitrogen gas is selected. As described above, these gases may be supplied while being diluted with the carrier gas or may be supplied separately from the carrier gas. However, in either case, the total flow rate of the carrier gas supplied into the reactor is controlled to a large quantity, for example 500-600 sccm, but needs to be varied appropriately for different reactors. After sustaining plasma generation for about 1-2 seconds, an oxygen gas supply valve and a nitrogen source gas supply valve are closed, and a source power switch is turned off, so that only the carrier gas is supplied to purge physisorbed or unreacted remaining gases from the reactor. After sustaining the purging duration for about 1-2 seconds, the metal source compound supply valve is opened, thereby terminating one cycle. The duration of purging between each supply of source and reactant gases is adjusted according to the kind of metal source compound used. One cycle period is about 6-7 seconds. This cycle is repeated until a metal oxide thin film having a desired thickness is obtained. [0024]
  • As the reactant gases are activated into plasma, reactions with the metal source compound adsorbed on the wafer is facilitated, and activation energy is supplied to the resulting thin film, thereby greatly improving the crystalline and physical properties of the film. The resulting metal oxide thin film further contains nitrogen atoms due to the supply of the nitrogen source gas. The nitrogen atoms in the metal oxide thin film increase the breakdown voltage of the metal oxide thin film. [0025]
  • Alternatively, the oxygen gas and the nitrogen source gas may be supplied separately to generate plasma in an asynchronous manner, as illustrated in FIGS. 2 and 3. In the case of FIG. 2, after the generation of oxygen plasma and purging, nitrogen source gas plasma is generated. In the case of FIG. 3, as opposite to the case of FIG. 2, after the generation of nitrogen source gas plasma, oxygen plasma is generated. [0026]
  • The amount of nitrogen atoms incorporated into the metal oxide thin film and its electrical properties differ according to the kind of nitrogen source gas used, even with the application of an equal intensity of RF source power. However, it was found that the breakdown characteristics of the nitrogen-containing metal oxide thin film are always better than non-nitrogen containing metal oxide thin films. It is effective to use nitrogen gas, which is known to be less likely to decompose than ammonia gas, in order to incorporate a trace of nitrogen atoms into metal oxide thin films. However, when more nitrogen atoms need to be incorporated into a metal oxide thin film, plasma can be generated from ammonia gas or nitrogen dioxide gas, instead of nitrogen gas. [0027]
  • When nitrogen dioxide or nitrogen hypooxide gas is used for the nitrogen source gas, supplying oxygen gas to generate plasma may be omitted because these gases inherently contain both nitrogen and oxygen atoms, as illustrated in FIG. 4. However, as described above with reference to FIGS. 1 through 3, the oxygen gas may be supplied further together with or separately from nitrogen dioxide or nitrogen hypooxide gas. [0028]
  • A nitrogen-containing oxide thin film according to the present invention can be formed with uniformity in thickness and high density, which are advantages of conventional ALD, and at high growth rate. The high density of the insulating layer increases the breakdown voltage, so that all pixels of an ELD can be protected from a breakdown even at a high voltage level, thereby improving the stability of the ELD and reducing the leakage current. When the nitrogen-containing oxide thin film according to the present invention, instead of an Al[0029] 2O3 or ATO layer, is used as an insulating film for an ELD device, the stability to a high voltage is ensured, and all the pixels are highly likely to be protected without defect. Accordingly, the thickness of the insulating layer can be reduced, providing an effect of reducing the threshold voltage.
  • In general, when using a high-dielectric thin film, the breakdown voltage becomes low, and the leakage current becomes high. However, these problems do not occur when using the nitrogen-containing metal oxide thin film according to the present invention, despite its high dielectric constant. These problems occurring in high-dielectric oxide films, such as a gate dielectric film or a capacitor oxide film of a memory device, can be eliminated when the nitrogen-containing metal oxide thin film formed using the PEALD method according to the present invention is applied to such high-dielectric oxide films. [0030]
  • When a thin film is formed using plasma, the resulting thin film becomes dense, and the breakdown voltage becomes high. However, in ELDs, the density of interface electron traps between the phosphor and insulating layers needs to be carefully managed and without causing plasma damage to the interface. Therefore, it is preferable that a nitrogen-containing metal oxide thin film formed using the method according to the present invention, having a multi-layered structure, as shown in FIGS. 5 and 6, be applied as an insulating layer to be formed on the phosphor layer for an ELD. [0031]
  • Referring to FIG. 5, after a [0032] phosphor layer 5 is formed on a substrate (not shown, usually formed of an insulating material), a buffer layer 10 is formed on the phosphor layer 5. The buffer layer 10 is a metal oxide thin film formed by general ALD without using plasma. Accordingly, no plasma damage appears in the interface between the phosphor layer 5 and the buffer layer 10. Next, a nitrogen-containing metal oxide thin film 20 having good breakdown properties is grown using PEALD. During the formation of the nitrogen-containing metal oxide thin film 20, the phosphor layer 5 can be protected from plasma damage due to the buffer layer 10 covering the same. The buffer layer 10 and the nitrogen-containing metal oxide thin film 20 may be grown in situ within the same reactor. Therefore, prior to the formation of the nitrogen-containing metal oxide layer according to the present invention using the method as described above, the substrate may be prepared to have a second metal oxide thin film by supplying in a cyclic fashion sequentially alternating pulses of a second metal source compound and oxygen gas into the reactor, followed by the formation of the nitrogen-containing metal oxide film 20 according to the present invention according to any pulsing scheme illustrated in FIGS. 1 through 4.
  • The [0033] buffer layer 10 may be the same kind or a different kind of metal oxide from the nitrogen-containing metal oxide layer 20 according to the present invention. Alternatively, the buffer layer 10 may be formed in combination with the metal oxide layer 20. For example, the buffer layer 10 may be a TiO2 thin film grown using general ALD, whereas the nitrogen-containing method oxide thin film 20 may be a nitrogen-containing Al2O3 thin film grown using PEALD. Alternatively, the buffer layer 10 may be an Al2O3 thin film grown using general ALD, whereas the nitrogen-containing metal oxide thin film 20 may be a nitrogen-containing Al2O3 thin film grown using PEALD. In this case, for both the buffer layer 10 and the nitrogen-containing metal oxide thin film 20 commonly containing Al as a metal component, TMA may be used as a common metal source compound.
  • For an ELD having an insulating layer underneath a phosphor layer, the order of depositing layers is reversed with respect to the order described with reference to FIG. 5. In particular, after the nitrogen-containing metal oxide [0034] thin film 20 is formed, the buffer layer 10 is grown thereon using general ALD, and then the phosphor layer 5 is formed on the buffer layer 10. As a result, the density of interface electron traps between the phosphor layer 5 and the buffer layer 10 can be maintained to be high.
  • Alternatively, the [0035] buffer layer 10 and the nitrogen-containing metal oxide thin film 20 may be formed alternately several times using general ALD and PEALD according to the present invention, respectively, to have a multi-layered structure on the phosphor layer 5, as shown in FIG. 6. The buffer layer 10 and the nitrogen-containing metal oxide thin film 20 may be formed of the same kind of metal oxide or different kinds of metal oxides.
  • The insulating layer having such a stacked structure as described with reference to FIGS. 5 and 6 is advantageous for the gate dielectric layer of a semiconductor device as well as an insulating layer for an ELD. Since the gate dielectric layer requires good interfacial properties, it should be protected from plasma damage. Therefore, an oxide film is formed near a wafer using general ALD, and a nitrogen-containing metal oxide thin film is grown on the oxide film using PEALD according to the present invention to increase breakdown resistance. When the oxide film and the nitrogen-containing metal oxide film are formed using Al[0036] 2O3, ZrO2, or HfO2, having a greater dielectric constant than conventional silicon oxides, the physical thickness of the oxide film can be increased for a small equivalent oxide thickness of about 20 Å, so that it is easy to control the thickness of the oxide film.
  • FIG. 7 is a sectional view of an ELD device that can be manufactured based on the concept described above. Referring to FIG. 7, a [0037] lower electrode 102, a lower insulating layer 120, a buffer insulating layer 110, a phosphor layer 105, a buffer layer 10, an upper insulating layer 120, and an upper electrode 103 are sequentially stacked on a substrate 101. As described above, the lower and upper insulating layers 120 are nitrogen-containing metal oxide thin films formed using the method according to the present invention. When nitrogen gas is used as a nitrogen source gas, it is preferable that the upper and lower insulating layers 120 be formed as Al2O3 thin films containing nitrogen less than 1 atomic %.
  • The [0038] substrate 101 is preferably a glass substrate and has a thickness of about 1 mm. The lower electrode 102 is a transparent electrode formed of, for example, indium tin oxide (ITO), zinc oxide (ZnO), etc., to have a thickness of about 1000-2000 Å. The buffer insulating layer 110 is formed of an insulating material, such as Al2O3, SiO2, TiO2, etc., using general ALD, as described above. The phosphor layer 105 may be formed of a red-yellow phosphor, such as ZnS:Mn, or a blue-green phosphor, such as SrS:Ce or CaS:Pb. The upper electrode 103 is an opaque metal electrode formed by depositing Al to a thickness of about 1000-2000 Å. Therefore, luminescence can be observed through the transparent substrate 101. Alternatively, the substrate 101 may be a silicon substrate. In this case, the lower electrode 102 is an opaque metal electrode, and the upper electrode 103 is a transparent electrode, so that luminescence can be observed through the upper electrode 103.
  • An insulating layer contacting the phosphor layer in an ELD determines the quantity of electrons entering the phosphor layer under an electric field applied. The surface electron energy level in the interface between the insulating layer and the phosphor layer is a source to supply electrons into the phosphor layer. A higher surface electron energy level results in a higher probability of electrons entering the phosphor layer. The effective surface electron energy level is proportional to the dielectric constant of the insulating layer. However, when a breakdown occurs in an insulating layer having a high dielectric constant by a high electric field applied to induce luminescence, the breakdown spreads, causing current leakage and dispersing the electric field. Meanwhile, although the nitrogen-containing metal oxide thin film according to the present invention has a high dielectric constant, a breakdown unlikely occurs, and no damage to the electric field occurs. This is considered because an electric path is blocked as the trace of nitrogen atoms added binds to an oxygen network of the oxide thin film. [0039]
  • Conventionally, a thick insulating layer is required to prevent a breakdown. However, it causes the problem of an increase in the threshold voltage of devices. However, although the nitrogen-containing metal oxide thin film according to the present invention is formed to be as thin as 150-160 nm for a 1 μm-thick phosphor layer, no breakdown occurs. [0040]
  • Experimental Example [0041]
  • In order to verify the improved breakdown characteristics of the nitrogen-containing metal oxide thin film according to the present invention, a nitrogen-containing Al[0042] 2O3 thin film was grown using PEALD. For comparison, Al2O3 thin films containing no nitrogen were grown by ALD and PEALD, respectively. The results are shown in FIGS. 8 and 9.
  • The nitrogen-containing Al[0043] 2O3 thin film according to the present invention was deposited under the following experimental conditions. TMA was used as a metal source compound. Argon gas was flowed at a rate of 200 sccm to carry TMA while maintaining the total flow rate to 600 sccm. The process was performed at an oxygen flow rate of 50 sccm, a nitrogen gas flow rate of 5-10 sccm, an RF source power of 300 W, a reactor pressure of 3 torr, and a temperature of 250-300° C. One cycle period was controlled to 6-7 seconds, and oxygen gas and nitrogen gas were simultaneously supplied according to the gas pulsing scheme illustrated in FIG. 1.
  • An Al[0044] 2O3 thin film was grown according to the conventional ALD method under the same conditions as for the nitrogen-containing Al2O3 thin film according to the present invention, except that no plasma was generated and no nitrogen gas was supplied. In both cases, the Al2O3 thin films were formed to a thickness of about 50 nm.
  • FIG. 8 is a graph comparatively showing the breakdown characteristics of the Al[0045] 2O3 thin films formed, respectively, using the ALD and PEALD methods. In FIG. 8, graph (a) is for the Al2O3 thin film formed using the general ALD method. In this case, prior to the occurrence of a breakdown 30 at an electrical field strength of 8 MV/cm, a soft breakdown 40 occurred at an electrical field strength of about 3 MV/cm. The conventional Al2O3 thin film was formed at 250° C. When the processing temperature is increased to 300° C, the breakdown voltage decreases to 7 MV/cm. Although it depends on the kind of precursor used and the processing conditions, a general Al2O3 thin film formed by ALD is known to undergo a breakdown at an electrical field strength of 5-6 MV/cm or less. In view of this, the Al2O3 thin film formed in the present experimental example using the ALD method for a comparison with the nitrogen-containing Al2O3 thin film according to the present invention is considered to have better quality than average.
  • In FIG. 8, graph (b) shows the breakdown characteristics of the nitrogen-containing Al[0046] 2O3 thin film formed using the PEALD method according to the present invention. This nitrogen-containing Al2O3 thin film was formed at 300° C. Apparently, a breakdown occurred at an electrical field strength of about 9.5-10 MV/cm. In comparison with the Al2O3 thin film formed at 300° C. by general ALD, the breakdown voltage of the nitrogen-containing Al2O3 thin film according to the present invention is higher than that of the conventional Al2O3 thin film by about 2.5-3 MV/cm, which is an increase that is almost constant over the entire area. Accordingly, the nitrogen-containing Al2O3 thin film according to the present invention shows stable resistance to a breakdown at every position on the substrate. When plasma was generated from nitrogen gas in order to form a nitrogen-containing Al2O3 thin film, a very small amount of nitrogen, much less than 1 atomic %, was incorporated into the resulting nitrogen-containing Al2O3 thin film. Nevertheless, the electrical characteristics of the nitrogen-containing Al2O3 thin film were considerably improved. Since nitrogen gas is so stable that it hardly decomposes at 300-400 W, and only 1 atomic % of nitrogen is incorporated into the nitrogen-containing Al2O3 thin film. However, when ammonia or nitrogen dioxide gas is used as a nitrogen source gas, a greater amount of nitrogen can be incorporated into the nitrogen-containing Al2O3 thin film according to the present invention for the same power level.
  • FIG. 9 is a graph comparatively showing the luminance of ELDs, one having an Al[0047] 2O3 thin film containing no nitrogen and grown only using TMA and oxygen gas by PELAD, and the other having a nitrogen-containing Al2O3 thin film according to the present invention. In both the ELDs, ZnS:Mn was used for the phosphor layer. The phosphor layer was formed to be as thick as 1 μm, and the Al2O3 thin film containing or not containing nitrogen was formed to be as thin as 150-160 nm.
  • In FIG. 9, graph (a) is for the ELD having the Al[0048] 2O3 thin film grown using PEALD not to contain nitrogen for a comparison with the present invention. This ELD was stable at a voltage 20 V higher than the threshold voltage. Graph (b) is for the ELD having the nitrogen-containing Al2O3 thin film grown using PEALD according to the present invention. This ELD was stable at a voltage 100 V higher than the threshold voltage. The nitrogen-containing Al2O3 thin film according to the present invention provides more improvements, when applied to a device, than just improving the breakdown voltage of the film as shown in FIG. 8. The nitrogen-containing Al2O3 thin film increased the luminance of the ELD. Accordingly, when the nitrogen-containing metal oxide thin film formed using the PEALD method according to the present invention is used as an insulating layer for an ELD, the thickness of the insulating layer can be reduced, thereby further reducing the threshold voltage. In contrast, when the metal oxide film containing no nitrogen is formed on a relatively thick phosphor layer using general ALD or PEALD, it is required to increase the thickness of the metal oxide film to be greater than that of the nitrogen-containing metal oxide thin film according to the present invention, in order to ensure stable operation of the device. As a result, undesirably the threshold voltage increases. As is evident from the above example, the nitrogen-containing oxide thin film according to the present invention has improved electrical characteristics, particularly, in breakdown resistance, and can be applied to devices with improved operational stability.
  • A feature of the present invention lies in the improvement of the characteristics of films through the addition of nitrogen into an oxide thin film. However, the various methods of adding nitrogen in situ, as taught above, to implement the present invention are more significant in the present invention than the fact of adding nitrogen itself. [0049]
  • While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the present invention as defined by the following claims. [0050]

Claims (20)

What is claimed is:
1. A method for forming a nitrogen-containing metal oxide thin film on a substrate by supplying a source metal compound and oxygen gas into a reactor in a cyclic fashion with sequential alternating pulses of the source metal compound and the oxygen gas, wherein the oxygen gas is activated into plasma over the substrate in synchronization with the pulsing thereof, and a nitrogen source gas is further sequentially pulsed into the reactor and activated into plasma over the substrate in synchronization with the pulsing thereof.
2. The method of claim 1, wherein the oxygen gas and the nitrogen source gas are supplied at the same pulsing cycle.
3. The method of claim 1, wherein the nitrogen source gas is supplied after the oxygen gas.
4. The method of claim 1, wherein the oxygen gas is supplied after the nitrogen source gas.
5. The method of claim 1, wherein the nitrogen source gas is one selected from the group consisting of N2, NH3, NO2, N2O, and a mixture of the forgoing gases.
6. The method of claim 1, wherein at least one of the metal source compound, the oxygen gas, and the nitrogen source gas is supplied while being diluted with an inert carrier gas.
7. The method of claim 1, wherein the metal oxide is one selected from the group consisting of Al2O3, Ta2O5, TiO2, ZrO2, HfO2, and lanthanide series oxide.
8. The method of claim 1, wherein nitrogen atoms are incorporated into the metal oxide thin film as the nitrogen source gas is supplied.
9. The method of claim 1, wherein the substrate is prepared to have a second metal oxide thin film by supplying a second metal source compound and oxygen gas into the reactor in a cyclic fashion with sequential alternating pulses of the second metal source compound and the oxygen gas.
10. The method of claim 9, wherein the second metal source compound and the metal source compound are the same.
11. The method of claim 10, wherein the second metal source compound and the metal source compound are trimethylalumminum.
12. The method of claim 1, wherein after the metal oxide thin film has been formed, a second metal oxide thin film is additionally formed by supplying a second metal source compound and oxygen gas into the reactor in a cyclic fashion with sequential alternating pulses of the second metal source compound and the oxygen gas.
13. The method of claim 12, wherein the second metal source compound and the metal source compound are the same.
14. The method of claim 13, wherein the second metal source compound and the metal source compound are trimethylalumminum.
15. A method for forming a nitrogen-containing metal oxide thin film on a substrate by supplying a source metal compound and a reactant gas into a reactor in a cyclic fashion with sequential alternating pulses of the source metal compound and the reactant gas, wherein the reactant gas is activated into plasma over the substrate in synchronization with the pulsing thereof, and the reactant gas contains both nitrogen and oxygen atoms.
16. The method of claim 15, wherein the nitrogen source gas is one selected from the group consisting of NO2, N2O, and a mixture of the forgoing gases.
17. The method of claim 15, wherein the substrate is prepared to have a second metal oxide thin film by supplying a second metal source compound and oxygen gas into the reactor in a cyclic fashion with sequential alternating pulses of the second metal source compound and the oxygen gas.
18. The method of claim 17, wherein the second metal source compound and the metal source compound are the same.
19. The method of claim 15, wherein after the metal oxide thin film has been formed, a second metal oxide thin film is additionally formed by supplying a second metal source compound and oxygen gas into the reactor in a cyclic fashion with sequential alternating pulses of the second metal source compound and the oxygen gas.
20. The method of claim 15, wherein the metal oxide is one selected from the group consisting of Al2O3, Ta2O5, TiO2, ZrO2, HfO2, and lanthanide series oxide.
US10/377,471 2002-10-22 2003-02-27 Method for forming nitrogen-containing oxide thin film using plasma enhanced atomic layer deposition Expired - Fee Related US6723642B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR10-2002-0064524 2002-10-22
KR10-2002-0064524A KR100460841B1 (en) 2002-10-22 2002-10-22 Method for forming nitrogen containing oxide thin film by plasma enhanced atomic layer deposition
KR2002-64524 2002-10-22

Publications (2)

Publication Number Publication Date
US6723642B1 US6723642B1 (en) 2004-04-20
US20040077182A1 true US20040077182A1 (en) 2004-04-22

Family

ID=32064969

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/377,471 Expired - Fee Related US6723642B1 (en) 2002-10-22 2003-02-27 Method for forming nitrogen-containing oxide thin film using plasma enhanced atomic layer deposition

Country Status (2)

Country Link
US (1) US6723642B1 (en)
KR (1) KR100460841B1 (en)

Cited By (362)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030232501A1 (en) * 2002-06-14 2003-12-18 Kher Shreyas S. Surface pre-treatment for enhancement of nucleation of high dielectric constant materials
US20040198069A1 (en) * 2003-04-04 2004-10-07 Applied Materials, Inc. Method for hafnium nitride deposition
US20050008779A1 (en) * 2002-04-08 2005-01-13 Yang Michael Xi Multiple precursor cyclical depositon system
US20050009371A1 (en) * 2002-06-14 2005-01-13 Metzner Craig R. System and method for forming a gate dielectric
US20050153571A1 (en) * 2003-11-17 2005-07-14 Yoshihide Senzaki Nitridation of high-k dielectric films
WO2005117086A1 (en) * 2004-05-21 2005-12-08 Applied Materials, Inc. Stabilization of high-k dielectric materials
US20050271812A1 (en) * 2004-05-12 2005-12-08 Myo Nyi O Apparatuses and methods for atomic layer deposition of hafnium-containing high-k dielectric materials
US20060008999A1 (en) * 2004-01-21 2006-01-12 Nima Mohklesi Creating a dielectric layer using ALD to deposit multiple components
US20060062917A1 (en) * 2004-05-21 2006-03-23 Shankar Muthukrishnan Vapor deposition of hafnium silicate materials with tris(dimethylamino)silane
US20070049043A1 (en) * 2005-08-23 2007-03-01 Applied Materials, Inc. Nitrogen profile engineering in HI-K nitridation for device performance enhancement and reliability improvement
US20070059945A1 (en) * 2005-09-12 2007-03-15 Nima Mohklesi Atomic layer deposition with nitridation and oxidation
US20070082468A1 (en) * 2005-10-06 2007-04-12 Blalock Guy T Atomic layer deposition methods
US20070207624A1 (en) * 2006-03-02 2007-09-06 Applied Materials, Inc. Multiple nitrogen plasma treatments for thin SiON dielectrics
EP1856724A2 (en) * 2005-02-25 2007-11-21 Freescale Semiconductor, Inc. Method of making a nitrided gate dielectric
US7659158B2 (en) 2008-03-31 2010-02-09 Applied Materials, Inc. Atomic layer deposition processes for non-volatile memory devices
US20100062149A1 (en) * 2008-09-08 2010-03-11 Applied Materials, Inc. Method for tuning a deposition rate during an atomic layer deposition process
US7798096B2 (en) 2006-05-05 2010-09-21 Applied Materials, Inc. Plasma, UV and ion/neutral assisted ALD or CVD in a batch tool
CN102082087A (en) * 2009-11-30 2011-06-01 海力士半导体有限公司 Semiconductor device including carbon-containing electrode and method for fabricating the same
US7972978B2 (en) 2005-08-26 2011-07-05 Applied Materials, Inc. Pretreatment processes within a batch ALD reactor
US8119210B2 (en) 2004-05-21 2012-02-21 Applied Materials, Inc. Formation of a silicon oxynitride layer on a high-k dielectric material
JP2012184499A (en) * 2011-02-18 2012-09-27 Hitachi Kokusai Electric Inc Manufacturing method, substrate processing device, and substrate processing method of semiconductor device
JP2013026479A (en) * 2011-07-21 2013-02-04 Mitsui Eng & Shipbuild Co Ltd Atomic layer growth method and atomic layer growth apparatus
US8491967B2 (en) 2008-09-08 2013-07-23 Applied Materials, Inc. In-situ chamber treatment and deposition process
US20140346650A1 (en) * 2009-08-14 2014-11-27 Asm Ip Holding B.V. Systems and methods for thin-film deposition of metal oxides using excited nitrogen-oxygen species
US9005539B2 (en) 2011-11-23 2015-04-14 Asm Ip Holding B.V. Chamber sealing member
US9017481B1 (en) 2011-10-28 2015-04-28 Asm America, Inc. Process feed management for semiconductor substrate processing
US9018111B2 (en) 2013-07-22 2015-04-28 Asm Ip Holding B.V. Semiconductor reaction chamber with plasma capabilities
US9021985B2 (en) 2012-09-12 2015-05-05 Asm Ip Holdings B.V. Process gas management for an inductively-coupled plasma deposition reactor
US9029253B2 (en) 2012-05-02 2015-05-12 Asm Ip Holding B.V. Phase-stabilized thin films, structures and devices including the thin films, and methods of forming same
US9096931B2 (en) 2011-10-27 2015-08-04 Asm America, Inc Deposition valve assembly and method of heating the same
US9117866B2 (en) 2012-07-31 2015-08-25 Asm Ip Holding B.V. Apparatus and method for calculating a wafer position in a processing chamber under process conditions
US9167625B2 (en) 2011-11-23 2015-10-20 Asm Ip Holding B.V. Radiation shielding for a substrate holder
US9169975B2 (en) 2012-08-28 2015-10-27 Asm Ip Holding B.V. Systems and methods for mass flow controller verification
US9177784B2 (en) 2012-05-07 2015-11-03 Asm Ip Holdings B.V. Semiconductor device dielectric interface layer
US9202727B2 (en) 2012-03-02 2015-12-01 ASM IP Holding Susceptor heater shim
US9228259B2 (en) 2013-02-01 2016-01-05 Asm Ip Holding B.V. Method for treatment of deposition reactor
US9240412B2 (en) 2013-09-27 2016-01-19 Asm Ip Holding B.V. Semiconductor structure and device and methods of forming same using selective epitaxial process
US9299595B2 (en) 2012-06-27 2016-03-29 Asm Ip Holding B.V. Susceptor heater and method of heating a substrate
US9324811B2 (en) 2012-09-26 2016-04-26 Asm Ip Holding B.V. Structures and devices including a tensile-stressed silicon arsenic layer and methods of forming same
US9341296B2 (en) 2011-10-27 2016-05-17 Asm America, Inc. Heater jacket for a fluid line
US9384987B2 (en) 2012-04-04 2016-07-05 Asm Ip Holding B.V. Metal oxide protective layer for a semiconductor device
US9394608B2 (en) 2009-04-06 2016-07-19 Asm America, Inc. Semiconductor processing reactor and components thereof
US9396934B2 (en) 2013-08-14 2016-07-19 Asm Ip Holding B.V. Methods of forming films including germanium tin and structures and devices including the films
US9404587B2 (en) 2014-04-24 2016-08-02 ASM IP Holding B.V Lockout tagout for semiconductor vacuum valve
US9447498B2 (en) 2014-03-18 2016-09-20 Asm Ip Holding B.V. Method for performing uniform processing in gas system-sharing multiple reaction chambers
US9455138B1 (en) 2015-11-10 2016-09-27 Asm Ip Holding B.V. Method for forming dielectric film in trenches by PEALD using H-containing gas
US9466574B2 (en) * 2009-02-02 2016-10-11 Asm America, Inc. Plasma-enhanced atomic layer deposition of conductive material over dielectric layers
US9478415B2 (en) 2015-02-13 2016-10-25 Asm Ip Holding B.V. Method for forming film having low resistance and shallow junction depth
US9484191B2 (en) 2013-03-08 2016-11-01 Asm Ip Holding B.V. Pulsed remote plasma method and system
US9543180B2 (en) 2014-08-01 2017-01-10 Asm Ip Holding B.V. Apparatus and method for transporting wafers between wafer carrier and process tool under vacuum
US9558931B2 (en) 2012-07-27 2017-01-31 Asm Ip Holding B.V. System and method for gas-phase sulfur passivation of a semiconductor surface
US9556516B2 (en) 2013-10-09 2017-01-31 ASM IP Holding B.V Method for forming Ti-containing film by PEALD using TDMAT or TDEAT
US20170040560A1 (en) * 2015-08-05 2017-02-09 Uchicago Argonne, Llc Non-hydrolytic metal oxide films for perovskite halide overcoating and stabilization
JP2017038088A (en) * 2016-11-09 2017-02-16 東京エレクトロン株式会社 Deposition method and deposition device
US9589770B2 (en) 2013-03-08 2017-03-07 Asm Ip Holding B.V. Method and systems for in-situ formation of intermediate reactive species
US9605343B2 (en) 2013-11-13 2017-03-28 Asm Ip Holding B.V. Method for forming conformal carbon films, structures conformal carbon film, and system of forming same
US9607837B1 (en) 2015-12-21 2017-03-28 Asm Ip Holding B.V. Method for forming silicon oxide cap layer for solid state diffusion process
US9627221B1 (en) 2015-12-28 2017-04-18 Asm Ip Holding B.V. Continuous process incorporating atomic layer etching
US9640416B2 (en) 2012-12-26 2017-05-02 Asm Ip Holding B.V. Single-and dual-chamber module-attachable wafer-handling chamber
US9647114B2 (en) 2015-08-14 2017-05-09 Asm Ip Holding B.V. Methods of forming highly p-type doped germanium tin films and structures and devices including the films
US9657845B2 (en) 2014-10-07 2017-05-23 Asm Ip Holding B.V. Variable conductance gas distribution apparatus and method
US9659799B2 (en) 2012-08-28 2017-05-23 Asm Ip Holding B.V. Systems and methods for dynamic semiconductor process scheduling
US9711345B2 (en) 2015-08-25 2017-07-18 Asm Ip Holding B.V. Method for forming aluminum nitride-based film by PEALD
US9735024B2 (en) 2015-12-28 2017-08-15 Asm Ip Holding B.V. Method of atomic layer etching using functional group-containing fluorocarbon
US9754779B1 (en) 2016-02-19 2017-09-05 Asm Ip Holding B.V. Method for forming silicon nitride film selectively on sidewalls or flat surfaces of trenches
US9793135B1 (en) 2016-07-14 2017-10-17 ASM IP Holding B.V Method of cyclic dry etching using etchant film
US9793148B2 (en) 2011-06-22 2017-10-17 Asm Japan K.K. Method for positioning wafers in multiple wafer transport
US9793115B2 (en) 2013-08-14 2017-10-17 Asm Ip Holding B.V. Structures and devices including germanium-tin films and methods of forming same
US9790595B2 (en) 2013-07-12 2017-10-17 Asm Ip Holding B.V. Method and system to reduce outgassing in a reaction chamber
US9812320B1 (en) 2016-07-28 2017-11-07 Asm Ip Holding B.V. Method and apparatus for filling a gap
US9859151B1 (en) 2016-07-08 2018-01-02 Asm Ip Holding B.V. Selective film deposition method to form air gaps
US9887082B1 (en) 2016-07-28 2018-02-06 Asm Ip Holding B.V. Method and apparatus for filling a gap
US9890456B2 (en) 2014-08-21 2018-02-13 Asm Ip Holding B.V. Method and system for in situ formation of gas-phase compounds
US9891521B2 (en) 2014-11-19 2018-02-13 Asm Ip Holding B.V. Method for depositing thin film
US9899405B2 (en) 2014-12-22 2018-02-20 Asm Ip Holding B.V. Semiconductor device and manufacturing method thereof
US9899291B2 (en) 2015-07-13 2018-02-20 Asm Ip Holding B.V. Method for protecting layer by forming hydrocarbon-based extremely thin film
US9905420B2 (en) 2015-12-01 2018-02-27 Asm Ip Holding B.V. Methods of forming silicon germanium tin films and structures and devices including the films
US9909214B2 (en) 2015-10-15 2018-03-06 Asm Ip Holding B.V. Method for depositing dielectric film in trenches by PEALD
US9916980B1 (en) 2016-12-15 2018-03-13 Asm Ip Holding B.V. Method of forming a structure on a substrate
US9960072B2 (en) 2015-09-29 2018-05-01 Asm Ip Holding B.V. Variable adjustment for precise matching of multiple chamber cavity housings
US10032628B2 (en) 2016-05-02 2018-07-24 Asm Ip Holding B.V. Source/drain performance through conformal solid state doping
US10043661B2 (en) 2015-07-13 2018-08-07 Asm Ip Holding B.V. Method for protecting layer by forming hydrocarbon-based extremely thin film
US10083836B2 (en) 2015-07-24 2018-09-25 Asm Ip Holding B.V. Formation of boron-doped titanium metal films with high work function
US10090316B2 (en) 2016-09-01 2018-10-02 Asm Ip Holding B.V. 3D stacked multilayer semiconductor memory using doped select transistor channel
US10087522B2 (en) 2016-04-21 2018-10-02 Asm Ip Holding B.V. Deposition of metal borides
US10087525B2 (en) 2015-08-04 2018-10-02 Asm Ip Holding B.V. Variable gap hard stop design
US10103040B1 (en) 2017-03-31 2018-10-16 Asm Ip Holding B.V. Apparatus and method for manufacturing a semiconductor device
USD830981S1 (en) 2017-04-07 2018-10-16 Asm Ip Holding B.V. Susceptor for semiconductor substrate processing apparatus
US10134757B2 (en) 2016-11-07 2018-11-20 Asm Ip Holding B.V. Method of processing a substrate and a device manufactured by using the method
US10167557B2 (en) 2014-03-18 2019-01-01 Asm Ip Holding B.V. Gas distribution system, reactor including the system, and methods of using the same
US10177025B2 (en) 2016-07-28 2019-01-08 Asm Ip Holding B.V. Method and apparatus for filling a gap
US10179947B2 (en) 2013-11-26 2019-01-15 Asm Ip Holding B.V. Method for forming conformal nitrided, oxidized, or carbonized dielectric film by atomic layer deposition
US10190213B2 (en) 2016-04-21 2019-01-29 Asm Ip Holding B.V. Deposition of metal borides
US10211308B2 (en) 2015-10-21 2019-02-19 Asm Ip Holding B.V. NbMC layers
US10229833B2 (en) 2016-11-01 2019-03-12 Asm Ip Holding B.V. Methods for forming a transition metal nitride film on a substrate by atomic layer deposition and related semiconductor device structures
US10236177B1 (en) 2017-08-22 2019-03-19 ASM IP Holding B.V.. Methods for depositing a doped germanium tin semiconductor and related semiconductor device structures
US10249524B2 (en) 2017-08-09 2019-04-02 Asm Ip Holding B.V. Cassette holder assembly for a substrate cassette and holding member for use in such assembly
US10249577B2 (en) 2016-05-17 2019-04-02 Asm Ip Holding B.V. Method of forming metal interconnection and method of fabricating semiconductor apparatus using the method
US10262859B2 (en) 2016-03-24 2019-04-16 Asm Ip Holding B.V. Process for forming a film on a substrate using multi-port injection assemblies
US10269558B2 (en) 2016-12-22 2019-04-23 Asm Ip Holding B.V. Method of forming a structure on a substrate
US10276355B2 (en) 2015-03-12 2019-04-30 Asm Ip Holding B.V. Multi-zone reactor, system including the reactor, and method of using the same
US10283353B2 (en) 2017-03-29 2019-05-07 Asm Ip Holding B.V. Method of reforming insulating film deposited on substrate with recess pattern
US10290508B1 (en) 2017-12-05 2019-05-14 Asm Ip Holding B.V. Method for forming vertical spacers for spacer-defined patterning
US10312055B2 (en) 2017-07-26 2019-06-04 Asm Ip Holding B.V. Method of depositing film by PEALD using negative bias
US10319588B2 (en) 2017-10-10 2019-06-11 Asm Ip Holding B.V. Method for depositing a metal chalcogenide on a substrate by cyclical deposition
US10322384B2 (en) 2015-11-09 2019-06-18 Asm Ip Holding B.V. Counter flow mixer for process chamber
US10340135B2 (en) 2016-11-28 2019-07-02 Asm Ip Holding B.V. Method of topologically restricted plasma-enhanced cyclic deposition of silicon or metal nitride
US10343920B2 (en) 2016-03-18 2019-07-09 Asm Ip Holding B.V. Aligned carbon nanotubes
US10364496B2 (en) 2011-06-27 2019-07-30 Asm Ip Holding B.V. Dual section module having shared and unshared mass flow controllers
US10367080B2 (en) 2016-05-02 2019-07-30 Asm Ip Holding B.V. Method of forming a germanium oxynitride film
US10381219B1 (en) 2018-10-25 2019-08-13 Asm Ip Holding B.V. Methods for forming a silicon nitride film
US10378106B2 (en) 2008-11-14 2019-08-13 Asm Ip Holding B.V. Method of forming insulation film by modified PEALD
US10381226B2 (en) 2016-07-27 2019-08-13 Asm Ip Holding B.V. Method of processing substrate
US10388509B2 (en) 2016-06-28 2019-08-20 Asm Ip Holding B.V. Formation of epitaxial layers via dislocation filtering
US10388513B1 (en) 2018-07-03 2019-08-20 Asm Ip Holding B.V. Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition
US10395919B2 (en) 2016-07-28 2019-08-27 Asm Ip Holding B.V. Method and apparatus for filling a gap
US10403504B2 (en) 2017-10-05 2019-09-03 Asm Ip Holding B.V. Method for selectively depositing a metallic film on a substrate
US10410943B2 (en) 2016-10-13 2019-09-10 Asm Ip Holding B.V. Method for passivating a surface of a semiconductor and related systems
US10435790B2 (en) 2016-11-01 2019-10-08 Asm Ip Holding B.V. Method of subatmospheric plasma-enhanced ALD using capacitively coupled electrodes with narrow gap
US10446393B2 (en) 2017-05-08 2019-10-15 Asm Ip Holding B.V. Methods for forming silicon-containing epitaxial layers and related semiconductor device structures
US10458018B2 (en) 2015-06-26 2019-10-29 Asm Ip Holding B.V. Structures including metal carbide material, devices including the structures, and methods of forming same
US10468251B2 (en) 2016-02-19 2019-11-05 Asm Ip Holding B.V. Method for forming spacers using silicon nitride film for spacer-defined multiple patterning
US10468262B2 (en) 2017-02-15 2019-11-05 Asm Ip Holding B.V. Methods for forming a metallic film on a substrate by a cyclical deposition and related semiconductor device structures
US10483099B1 (en) 2018-07-26 2019-11-19 Asm Ip Holding B.V. Method for forming thermally stable organosilicon polymer film
US10504742B2 (en) 2017-05-31 2019-12-10 Asm Ip Holding B.V. Method of atomic layer etching using hydrogen plasma
US10501866B2 (en) 2016-03-09 2019-12-10 Asm Ip Holding B.V. Gas distribution apparatus for improved film uniformity in an epitaxial system
US10510536B2 (en) 2018-03-29 2019-12-17 Asm Ip Holding B.V. Method of depositing a co-doped polysilicon film on a surface of a substrate within a reaction chamber
US10529542B2 (en) 2015-03-11 2020-01-07 Asm Ip Holdings B.V. Cross-flow reactor and method
US10529554B2 (en) 2016-02-19 2020-01-07 Asm Ip Holding B.V. Method for forming silicon nitride film selectively on sidewalls or flat surfaces of trenches
US10529563B2 (en) 2017-03-29 2020-01-07 Asm Ip Holdings B.V. Method for forming doped metal oxide films on a substrate by cyclical deposition and related semiconductor device structures
US10535516B2 (en) 2018-02-01 2020-01-14 Asm Ip Holdings B.V. Method for depositing a semiconductor structure on a surface of a substrate and related semiconductor structures
US10541333B2 (en) 2017-07-19 2020-01-21 Asm Ip Holding B.V. Method for depositing a group IV semiconductor and related semiconductor device structures
US10559458B1 (en) 2018-11-26 2020-02-11 Asm Ip Holding B.V. Method of forming oxynitride film
US10593880B2 (en) 2017-07-03 2020-03-17 Arm Limited Method for the manufacture of a correlated electron material device
US10590535B2 (en) 2017-07-26 2020-03-17 Asm Ip Holdings B.V. Chemical treatment, deposition and/or infiltration apparatus and method for using the same
US10600673B2 (en) 2015-07-07 2020-03-24 Asm Ip Holding B.V. Magnetic susceptor to baseplate seal
US10605530B2 (en) 2017-07-26 2020-03-31 Asm Ip Holding B.V. Assembly of a liner and a flange for a vertical furnace as well as the liner and the vertical furnace
US10607895B2 (en) 2017-09-18 2020-03-31 Asm Ip Holdings B.V. Method for forming a semiconductor device structure comprising a gate fill metal
USD880437S1 (en) 2018-02-01 2020-04-07 Asm Ip Holding B.V. Gas supply plate for semiconductor manufacturing apparatus
US10612137B2 (en) 2016-07-08 2020-04-07 Asm Ip Holdings B.V. Organic reactants for atomic layer deposition
US10612136B2 (en) 2018-06-29 2020-04-07 ASM IP Holding, B.V. Temperature-controlled flange and reactor system including same
US10643904B2 (en) 2016-11-01 2020-05-05 Asm Ip Holdings B.V. Methods for forming a semiconductor device and related semiconductor device structures
US10643826B2 (en) 2016-10-26 2020-05-05 Asm Ip Holdings B.V. Methods for thermally calibrating reaction chambers
US10658181B2 (en) 2018-02-20 2020-05-19 Asm Ip Holding B.V. Method of spacer-defined direct patterning in semiconductor fabrication
US10658205B2 (en) 2017-09-28 2020-05-19 Asm Ip Holdings B.V. Chemical dispensing apparatus and methods for dispensing a chemical to a reaction chamber
US10655221B2 (en) 2017-02-09 2020-05-19 Asm Ip Holding B.V. Method for depositing oxide film by thermal ALD and PEALD
US10683571B2 (en) 2014-02-25 2020-06-16 Asm Ip Holding B.V. Gas supply manifold and method of supplying gases to chamber using same
US10685834B2 (en) 2017-07-05 2020-06-16 Asm Ip Holdings B.V. Methods for forming a silicon germanium tin layer and related semiconductor device structures
US10692741B2 (en) 2017-08-08 2020-06-23 Asm Ip Holdings B.V. Radiation shield
US10707106B2 (en) 2011-06-06 2020-07-07 Asm Ip Holding B.V. High-throughput semiconductor-processing apparatus equipped with multiple dual-chamber modules
US10714335B2 (en) 2017-04-25 2020-07-14 Asm Ip Holding B.V. Method of depositing thin film and method of manufacturing semiconductor device
US10714350B2 (en) 2016-11-01 2020-07-14 ASM IP Holdings, B.V. Methods for forming a transition metal niobium nitride film on a substrate by atomic layer deposition and related semiconductor device structures
US10714385B2 (en) 2016-07-19 2020-07-14 Asm Ip Holding B.V. Selective deposition of tungsten
US10714315B2 (en) 2012-10-12 2020-07-14 Asm Ip Holdings B.V. Semiconductor reaction chamber showerhead
US10731249B2 (en) 2018-02-15 2020-08-04 Asm Ip Holding B.V. Method of forming a transition metal containing film on a substrate by a cyclical deposition process, a method for supplying a transition metal halide compound to a reaction chamber, and related vapor deposition apparatus
US10734497B2 (en) 2017-07-18 2020-08-04 Asm Ip Holding B.V. Methods for forming a semiconductor device structure and related semiconductor device structures
US10734244B2 (en) 2017-11-16 2020-08-04 Asm Ip Holding B.V. Method of processing a substrate and a device manufactured by the same
US10755922B2 (en) 2018-07-03 2020-08-25 Asm Ip Holding B.V. Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition
US10770286B2 (en) 2017-05-08 2020-09-08 Asm Ip Holdings B.V. Methods for selectively forming a silicon nitride film on a substrate and related semiconductor device structures
US10767789B2 (en) 2018-07-16 2020-09-08 Asm Ip Holding B.V. Diaphragm valves, valve components, and methods for forming valve components
US10770336B2 (en) 2017-08-08 2020-09-08 Asm Ip Holding B.V. Substrate lift mechanism and reactor including same
US10797238B2 (en) 2016-01-26 2020-10-06 Arm Ltd. Fabricating correlated electron material (CEM) devices
US10797133B2 (en) 2018-06-21 2020-10-06 Asm Ip Holding B.V. Method for depositing a phosphorus doped silicon arsenide film and related semiconductor device structures
US10811256B2 (en) 2018-10-16 2020-10-20 Asm Ip Holding B.V. Method for etching a carbon-containing feature
US10818758B2 (en) 2018-11-16 2020-10-27 Asm Ip Holding B.V. Methods for forming a metal silicate film on a substrate in a reaction chamber and related semiconductor device structures
USD900036S1 (en) 2017-08-24 2020-10-27 Asm Ip Holding B.V. Heater electrical connector and adapter
US10829852B2 (en) 2018-08-16 2020-11-10 Asm Ip Holding B.V. Gas distribution device for a wafer processing apparatus
US10844484B2 (en) 2017-09-22 2020-11-24 Asm Ip Holding B.V. Apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods
US10847371B2 (en) 2018-03-27 2020-11-24 Asm Ip Holding B.V. Method of forming an electrode on a substrate and a semiconductor device structure including an electrode
US10847366B2 (en) 2018-11-16 2020-11-24 Asm Ip Holding B.V. Methods for depositing a transition metal chalcogenide film on a substrate by a cyclical deposition process
US10847365B2 (en) 2018-10-11 2020-11-24 Asm Ip Holding B.V. Method of forming conformal silicon carbide film by cyclic CVD
US10854498B2 (en) 2011-07-15 2020-12-01 Asm Ip Holding B.V. Wafer-supporting device and method for producing same
USD903477S1 (en) 2018-01-24 2020-12-01 Asm Ip Holdings B.V. Metal clamp
US10858737B2 (en) 2014-07-28 2020-12-08 Asm Ip Holding B.V. Showerhead assembly and components thereof
US10867788B2 (en) 2016-12-28 2020-12-15 Asm Ip Holding B.V. Method of forming a structure on a substrate
US10867786B2 (en) 2018-03-30 2020-12-15 Asm Ip Holding B.V. Substrate processing method
US10865475B2 (en) 2016-04-21 2020-12-15 Asm Ip Holding B.V. Deposition of metal borides and silicides
US10872771B2 (en) 2018-01-16 2020-12-22 Asm Ip Holding B. V. Method for depositing a material film on a substrate within a reaction chamber by a cyclical deposition process and related device structures
US10886123B2 (en) 2017-06-02 2021-01-05 Asm Ip Holding B.V. Methods for forming low temperature semiconductor layers and related semiconductor device structures
US10883175B2 (en) 2018-08-09 2021-01-05 Asm Ip Holding B.V. Vertical furnace for processing substrates and a liner for use therein
US10892156B2 (en) 2017-05-08 2021-01-12 Asm Ip Holding B.V. Methods for forming a silicon nitride film on a substrate and related semiconductor device structures
US10896820B2 (en) 2018-02-14 2021-01-19 Asm Ip Holding B.V. Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process
US10910262B2 (en) 2017-11-16 2021-02-02 Asm Ip Holding B.V. Method of selectively depositing a capping layer structure on a semiconductor device structure
US10914004B2 (en) 2018-06-29 2021-02-09 Asm Ip Holding B.V. Thin-film deposition method and manufacturing method of semiconductor device
US10923344B2 (en) 2017-10-30 2021-02-16 Asm Ip Holding B.V. Methods for forming a semiconductor structure and related semiconductor structures
US10928731B2 (en) 2017-09-21 2021-02-23 Asm Ip Holding B.V. Method of sequential infiltration synthesis treatment of infiltrateable material and structures and devices formed using same
US10934619B2 (en) 2016-11-15 2021-03-02 Asm Ip Holding B.V. Gas supply unit and substrate processing apparatus including the gas supply unit
US10941490B2 (en) 2014-10-07 2021-03-09 Asm Ip Holding B.V. Multiple temperature range susceptor, assembly, reactor and system including the susceptor, and methods of using the same
US10975470B2 (en) 2018-02-23 2021-04-13 Asm Ip Holding B.V. Apparatus for detecting or monitoring for a chemical precursor in a high temperature environment
US11001925B2 (en) 2016-12-19 2021-05-11 Asm Ip Holding B.V. Substrate processing apparatus
US11018047B2 (en) 2018-01-25 2021-05-25 Asm Ip Holding B.V. Hybrid lift pin
US11018002B2 (en) 2017-07-19 2021-05-25 Asm Ip Holding B.V. Method for selectively depositing a Group IV semiconductor and related semiconductor device structures
US11015245B2 (en) 2014-03-19 2021-05-25 Asm Ip Holding B.V. Gas-phase reactor and system having exhaust plenum and components thereof
US11022879B2 (en) 2017-11-24 2021-06-01 Asm Ip Holding B.V. Method of forming an enhanced unexposed photoresist layer
US11024523B2 (en) 2018-09-11 2021-06-01 Asm Ip Holding B.V. Substrate processing apparatus and method
US11031242B2 (en) 2018-11-07 2021-06-08 Asm Ip Holding B.V. Methods for depositing a boron doped silicon germanium film
USD922229S1 (en) 2019-06-05 2021-06-15 Asm Ip Holding B.V. Device for controlling a temperature of a gas supply unit
US11049751B2 (en) 2018-09-14 2021-06-29 Asm Ip Holding B.V. Cassette supply system to store and handle cassettes and processing apparatus equipped therewith
US11056567B2 (en) 2018-05-11 2021-07-06 Asm Ip Holding B.V. Method of forming a doped metal carbide film on a substrate and related semiconductor device structures
US11053591B2 (en) 2018-08-06 2021-07-06 Asm Ip Holding B.V. Multi-port gas injection system and reactor system including same
US11056344B2 (en) 2017-08-30 2021-07-06 Asm Ip Holding B.V. Layer forming method
US11069510B2 (en) 2017-08-30 2021-07-20 Asm Ip Holding B.V. Substrate processing apparatus
US11081345B2 (en) 2018-02-06 2021-08-03 Asm Ip Holding B.V. Method of post-deposition treatment for silicon oxide film
US11087997B2 (en) 2018-10-31 2021-08-10 Asm Ip Holding B.V. Substrate processing apparatus for processing substrates
US11088002B2 (en) 2018-03-29 2021-08-10 Asm Ip Holding B.V. Substrate rack and a substrate processing system and method
US11114294B2 (en) 2019-03-08 2021-09-07 Asm Ip Holding B.V. Structure including SiOC layer and method of forming same
US11114283B2 (en) 2018-03-16 2021-09-07 Asm Ip Holding B.V. Reactor, system including the reactor, and methods of manufacturing and using same
USD930782S1 (en) 2019-08-22 2021-09-14 Asm Ip Holding B.V. Gas distributor
US11127589B2 (en) 2019-02-01 2021-09-21 Asm Ip Holding B.V. Method of topology-selective film formation of silicon oxide
US11127617B2 (en) 2017-11-27 2021-09-21 Asm Ip Holding B.V. Storage device for storing wafer cassettes for use with a batch furnace
USD931978S1 (en) 2019-06-27 2021-09-28 Asm Ip Holding B.V. Showerhead vacuum transport
US11139308B2 (en) 2015-12-29 2021-10-05 Asm Ip Holding B.V. Atomic layer deposition of III-V compounds to form V-NAND devices
US11139191B2 (en) 2017-08-09 2021-10-05 Asm Ip Holding B.V. Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith
US11142683B2 (en) * 2014-09-17 2021-10-12 Koninklijke Philips N.V. Phosphor with hybrid coating and method of production
US11158513B2 (en) 2018-12-13 2021-10-26 Asm Ip Holding B.V. Methods for forming a rhenium-containing film on a substrate by a cyclical deposition process and related semiconductor device structures
US11171025B2 (en) 2019-01-22 2021-11-09 Asm Ip Holding B.V. Substrate processing device
USD935572S1 (en) 2019-05-24 2021-11-09 Asm Ip Holding B.V. Gas channel plate
US11205585B2 (en) 2016-07-28 2021-12-21 Asm Ip Holding B.V. Substrate processing apparatus and method of operating the same
US11217444B2 (en) 2018-11-30 2022-01-04 Asm Ip Holding B.V. Method for forming an ultraviolet radiation responsive metal oxide-containing film
US11222772B2 (en) 2016-12-14 2022-01-11 Asm Ip Holding B.V. Substrate processing apparatus
USD940837S1 (en) 2019-08-22 2022-01-11 Asm Ip Holding B.V. Electrode
US11227782B2 (en) 2019-07-31 2022-01-18 Asm Ip Holding B.V. Vertical batch furnace assembly
US11227789B2 (en) 2019-02-20 2022-01-18 Asm Ip Holding B.V. Method and apparatus for filling a recess formed within a substrate surface
US11230766B2 (en) 2018-03-29 2022-01-25 Asm Ip Holding B.V. Substrate processing apparatus and method
US11232963B2 (en) 2018-10-03 2022-01-25 Asm Ip Holding B.V. Substrate processing apparatus and method
US11251068B2 (en) 2018-10-19 2022-02-15 Asm Ip Holding B.V. Substrate processing apparatus and substrate processing method
US11251040B2 (en) 2019-02-20 2022-02-15 Asm Ip Holding B.V. Cyclical deposition method including treatment step and apparatus for same
USD944946S1 (en) 2019-06-14 2022-03-01 Asm Ip Holding B.V. Shower plate
US11270899B2 (en) 2018-06-04 2022-03-08 Asm Ip Holding B.V. Wafer handling chamber with moisture reduction
US11274369B2 (en) 2018-09-11 2022-03-15 Asm Ip Holding B.V. Thin film deposition method
US11282698B2 (en) 2019-07-19 2022-03-22 Asm Ip Holding B.V. Method of forming topology-controlled amorphous carbon polymer film
US11289326B2 (en) 2019-05-07 2022-03-29 Asm Ip Holding B.V. Method for reforming amorphous carbon polymer film
US11286562B2 (en) 2018-06-08 2022-03-29 Asm Ip Holding B.V. Gas-phase chemical reactor and method of using same
US11286558B2 (en) 2019-08-23 2022-03-29 Asm Ip Holding B.V. Methods for depositing a molybdenum nitride film on a surface of a substrate by a cyclical deposition process and related semiconductor device structures including a molybdenum nitride film
USD947913S1 (en) 2019-05-17 2022-04-05 Asm Ip Holding B.V. Susceptor shaft
US11295980B2 (en) 2017-08-30 2022-04-05 Asm Ip Holding B.V. Methods for depositing a molybdenum metal film over a dielectric surface of a substrate by a cyclical deposition process and related semiconductor device structures
USD948463S1 (en) 2018-10-24 2022-04-12 Asm Ip Holding B.V. Susceptor for semiconductor substrate supporting apparatus
USD949319S1 (en) 2019-08-22 2022-04-19 Asm Ip Holding B.V. Exhaust duct
US11306395B2 (en) 2017-06-28 2022-04-19 Asm Ip Holding B.V. Methods for depositing a transition metal nitride film on a substrate by atomic layer deposition and related deposition apparatus
US11315794B2 (en) 2019-10-21 2022-04-26 Asm Ip Holding B.V. Apparatus and methods for selectively etching films
US11339476B2 (en) 2019-10-08 2022-05-24 Asm Ip Holding B.V. Substrate processing device having connection plates, substrate processing method
US11342216B2 (en) 2019-02-20 2022-05-24 Asm Ip Holding B.V. Cyclical deposition method and apparatus for filling a recess formed within a substrate surface
US11345999B2 (en) 2019-06-06 2022-05-31 Asm Ip Holding B.V. Method of using a gas-phase reactor system including analyzing exhausted gas
US11355338B2 (en) 2019-05-10 2022-06-07 Asm Ip Holding B.V. Method of depositing material onto a surface and structure formed according to the method
US11361990B2 (en) 2018-05-28 2022-06-14 Asm Ip Holding B.V. Substrate processing method and device manufactured by using the same
US11374112B2 (en) 2017-07-19 2022-06-28 Asm Ip Holding B.V. Method for depositing a group IV semiconductor and related semiconductor device structures
US11378337B2 (en) 2019-03-28 2022-07-05 Asm Ip Holding B.V. Door opener and substrate processing apparatus provided therewith
US11390945B2 (en) 2019-07-03 2022-07-19 Asm Ip Holding B.V. Temperature control assembly for substrate processing apparatus and method of using same
US11390950B2 (en) 2017-01-10 2022-07-19 Asm Ip Holding B.V. Reactor system and method to reduce residue buildup during a film deposition process
US11393690B2 (en) 2018-01-19 2022-07-19 Asm Ip Holding B.V. Deposition method
US11390946B2 (en) 2019-01-17 2022-07-19 Asm Ip Holding B.V. Methods of forming a transition metal containing film on a substrate by a cyclical deposition process
US11401605B2 (en) 2019-11-26 2022-08-02 Asm Ip Holding B.V. Substrate processing apparatus
US11414760B2 (en) 2018-10-08 2022-08-16 Asm Ip Holding B.V. Substrate support unit, thin film deposition apparatus including the same, and substrate processing apparatus including the same
US11424119B2 (en) 2019-03-08 2022-08-23 Asm Ip Holding B.V. Method for selective deposition of silicon nitride layer and structure including selectively-deposited silicon nitride layer
US11430674B2 (en) 2018-08-22 2022-08-30 Asm Ip Holding B.V. Sensor array, apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods
US11430640B2 (en) 2019-07-30 2022-08-30 Asm Ip Holding B.V. Substrate processing apparatus
US11437241B2 (en) 2020-04-08 2022-09-06 Asm Ip Holding B.V. Apparatus and methods for selectively etching silicon oxide films
US11443926B2 (en) 2019-07-30 2022-09-13 Asm Ip Holding B.V. Substrate processing apparatus
US11447861B2 (en) 2016-12-15 2022-09-20 Asm Ip Holding B.V. Sequential infiltration synthesis apparatus and a method of forming a patterned structure
US11447864B2 (en) 2019-04-19 2022-09-20 Asm Ip Holding B.V. Layer forming method and apparatus
USD965044S1 (en) 2019-08-19 2022-09-27 Asm Ip Holding B.V. Susceptor shaft
US11453943B2 (en) 2016-05-25 2022-09-27 Asm Ip Holding B.V. Method for forming carbon-containing silicon/metal oxide or nitride film by ALD using silicon precursor and hydrocarbon precursor
USD965524S1 (en) 2019-08-19 2022-10-04 Asm Ip Holding B.V. Susceptor support
US11469098B2 (en) 2018-05-08 2022-10-11 Asm Ip Holding B.V. Methods for depositing an oxide film on a substrate by a cyclical deposition process and related device structures
US11476109B2 (en) 2019-06-11 2022-10-18 Asm Ip Holding B.V. Method of forming an electronic structure using reforming gas, system for performing the method, and structure formed using the method
US11473195B2 (en) 2018-03-01 2022-10-18 Asm Ip Holding B.V. Semiconductor processing apparatus and a method for processing a substrate
US11482533B2 (en) 2019-02-20 2022-10-25 Asm Ip Holding B.V. Apparatus and methods for plug fill deposition in 3-D NAND applications
US11482412B2 (en) 2018-01-19 2022-10-25 Asm Ip Holding B.V. Method for depositing a gap-fill layer by plasma-assisted deposition
US11482418B2 (en) 2018-02-20 2022-10-25 Asm Ip Holding B.V. Substrate processing method and apparatus
US11488819B2 (en) 2018-12-04 2022-11-01 Asm Ip Holding B.V. Method of cleaning substrate processing apparatus
US11488854B2 (en) 2020-03-11 2022-11-01 Asm Ip Holding B.V. Substrate handling device with adjustable joints
US11495459B2 (en) 2019-09-04 2022-11-08 Asm Ip Holding B.V. Methods for selective deposition using a sacrificial capping layer
US11492703B2 (en) 2018-06-27 2022-11-08 Asm Ip Holding B.V. Cyclic deposition methods for forming metal-containing material and films and structures including the metal-containing material
US11499222B2 (en) 2018-06-27 2022-11-15 Asm Ip Holding B.V. Cyclic deposition methods for forming metal-containing material and films and structures including the metal-containing material
US11501968B2 (en) 2019-11-15 2022-11-15 Asm Ip Holding B.V. Method for providing a semiconductor device with silicon filled gaps
US11499226B2 (en) 2018-11-02 2022-11-15 Asm Ip Holding B.V. Substrate supporting unit and a substrate processing device including the same
US11515188B2 (en) 2019-05-16 2022-11-29 Asm Ip Holding B.V. Wafer boat handling device, vertical batch furnace and method
US11515187B2 (en) 2020-05-01 2022-11-29 Asm Ip Holding B.V. Fast FOUP swapping with a FOUP handler
US11521851B2 (en) 2020-02-03 2022-12-06 Asm Ip Holding B.V. Method of forming structures including a vanadium or indium layer
US11527400B2 (en) 2019-08-23 2022-12-13 Asm Ip Holding B.V. Method for depositing silicon oxide film having improved quality by peald using bis(diethylamino)silane
US11527403B2 (en) 2019-12-19 2022-12-13 Asm Ip Holding B.V. Methods for filling a gap feature on a substrate surface and related semiconductor structures
US11530483B2 (en) 2018-06-21 2022-12-20 Asm Ip Holding B.V. Substrate processing system
US11530876B2 (en) 2020-04-24 2022-12-20 Asm Ip Holding B.V. Vertical batch furnace assembly comprising a cooling gas supply
US11532757B2 (en) 2016-10-27 2022-12-20 Asm Ip Holding B.V. Deposition of charge trapping layers
US11551912B2 (en) 2020-01-20 2023-01-10 Asm Ip Holding B.V. Method of forming thin film and method of modifying surface of thin film
US11551925B2 (en) 2019-04-01 2023-01-10 Asm Ip Holding B.V. Method for manufacturing a semiconductor device
US11557474B2 (en) 2019-07-29 2023-01-17 Asm Ip Holding B.V. Methods for selective deposition utilizing n-type dopants and/or alternative dopants to achieve high dopant incorporation
USD975665S1 (en) 2019-05-17 2023-01-17 Asm Ip Holding B.V. Susceptor shaft
US11562901B2 (en) 2019-09-25 2023-01-24 Asm Ip Holding B.V. Substrate processing method
US11572620B2 (en) 2018-11-06 2023-02-07 Asm Ip Holding B.V. Methods for selectively depositing an amorphous silicon film on a substrate
US11581186B2 (en) 2016-12-15 2023-02-14 Asm Ip Holding B.V. Sequential infiltration synthesis apparatus
US11587814B2 (en) 2019-07-31 2023-02-21 Asm Ip Holding B.V. Vertical batch furnace assembly
US11587815B2 (en) 2019-07-31 2023-02-21 Asm Ip Holding B.V. Vertical batch furnace assembly
US11594600B2 (en) 2019-11-05 2023-02-28 Asm Ip Holding B.V. Structures with doped semiconductor layers and methods and systems for forming same
USD979506S1 (en) 2019-08-22 2023-02-28 Asm Ip Holding B.V. Insulator
US11594450B2 (en) 2019-08-22 2023-02-28 Asm Ip Holding B.V. Method for forming a structure with a hole
USD980813S1 (en) 2021-05-11 2023-03-14 Asm Ip Holding B.V. Gas flow control plate for substrate processing apparatus
USD980814S1 (en) 2021-05-11 2023-03-14 Asm Ip Holding B.V. Gas distributor for substrate processing apparatus
US11605528B2 (en) 2019-07-09 2023-03-14 Asm Ip Holding B.V. Plasma device using coaxial waveguide, and substrate treatment method
US11610774B2 (en) 2019-10-02 2023-03-21 Asm Ip Holding B.V. Methods for forming a topographically selective silicon oxide film by a cyclical plasma-enhanced deposition process
US11615970B2 (en) 2019-07-17 2023-03-28 Asm Ip Holding B.V. Radical assist ignition plasma system and method
USD981973S1 (en) 2021-05-11 2023-03-28 Asm Ip Holding B.V. Reactor wall for substrate processing apparatus
US11626308B2 (en) 2020-05-13 2023-04-11 Asm Ip Holding B.V. Laser alignment fixture for a reactor system
US11626316B2 (en) 2019-11-20 2023-04-11 Asm Ip Holding B.V. Method of depositing carbon-containing material on a surface of a substrate, structure formed using the method, and system for forming the structure
US11629407B2 (en) 2019-02-22 2023-04-18 Asm Ip Holding B.V. Substrate processing apparatus and method for processing substrates
US11629406B2 (en) 2018-03-09 2023-04-18 Asm Ip Holding B.V. Semiconductor processing apparatus comprising one or more pyrometers for measuring a temperature of a substrate during transfer of the substrate
US11637011B2 (en) 2019-10-16 2023-04-25 Asm Ip Holding B.V. Method of topology-selective film formation of silicon oxide
US11637014B2 (en) 2019-10-17 2023-04-25 Asm Ip Holding B.V. Methods for selective deposition of doped semiconductor material
US11639811B2 (en) 2017-11-27 2023-05-02 Asm Ip Holding B.V. Apparatus including a clean mini environment
US11639548B2 (en) 2019-08-21 2023-05-02 Asm Ip Holding B.V. Film-forming material mixed-gas forming device and film forming device
US11644758B2 (en) 2020-07-17 2023-05-09 Asm Ip Holding B.V. Structures and methods for use in photolithography
US11646184B2 (en) 2019-11-29 2023-05-09 Asm Ip Holding B.V. Substrate processing apparatus
US11643724B2 (en) 2019-07-18 2023-05-09 Asm Ip Holding B.V. Method of forming structures using a neutral beam
US11646204B2 (en) 2020-06-24 2023-05-09 Asm Ip Holding B.V. Method for forming a layer provided with silicon
US11646205B2 (en) 2019-10-29 2023-05-09 Asm Ip Holding B.V. Methods of selectively forming n-type doped material on a surface, systems for selectively forming n-type doped material, and structures formed using same
US11658029B2 (en) 2018-12-14 2023-05-23 Asm Ip Holding B.V. Method of forming a device structure using selective deposition of gallium nitride and system for same
US11658035B2 (en) 2020-06-30 2023-05-23 Asm Ip Holding B.V. Substrate processing method
US11664245B2 (en) 2019-07-16 2023-05-30 Asm Ip Holding B.V. Substrate processing device
US11664199B2 (en) 2018-10-19 2023-05-30 Asm Ip Holding B.V. Substrate processing apparatus and substrate processing method
US11664267B2 (en) 2019-07-10 2023-05-30 Asm Ip Holding B.V. Substrate support assembly and substrate processing device including the same
US11674220B2 (en) 2020-07-20 2023-06-13 Asm Ip Holding B.V. Method for depositing molybdenum layers using an underlayer
US11680839B2 (en) 2019-08-05 2023-06-20 Asm Ip Holding B.V. Liquid level sensor for a chemical source vessel
US11685991B2 (en) 2018-02-14 2023-06-27 Asm Ip Holding B.V. Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process
USD990441S1 (en) 2021-09-07 2023-06-27 Asm Ip Holding B.V. Gas flow control plate
US11688603B2 (en) 2019-07-17 2023-06-27 Asm Ip Holding B.V. Methods of forming silicon germanium structures
USD990534S1 (en) 2020-09-11 2023-06-27 Asm Ip Holding B.V. Weighted lift pin
US11705333B2 (en) 2020-05-21 2023-07-18 Asm Ip Holding B.V. Structures including multiple carbon layers and methods of forming and using same
US11718913B2 (en) 2018-06-04 2023-08-08 Asm Ip Holding B.V. Gas distribution system and reactor system including same
US11725277B2 (en) 2011-07-20 2023-08-15 Asm Ip Holding B.V. Pressure transmitter for a semiconductor processing environment
US11725280B2 (en) 2020-08-26 2023-08-15 Asm Ip Holding B.V. Method for forming metal silicon oxide and metal silicon oxynitride layers
US11735422B2 (en) 2019-10-10 2023-08-22 Asm Ip Holding B.V. Method of forming a photoresist underlayer and structure including same
US11742198B2 (en) 2019-03-08 2023-08-29 Asm Ip Holding B.V. Structure including SiOCN layer and method of forming same
US11767589B2 (en) 2020-05-29 2023-09-26 Asm Ip Holding B.V. Substrate processing device
US11769682B2 (en) 2017-08-09 2023-09-26 Asm Ip Holding B.V. Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith
US11776846B2 (en) 2020-02-07 2023-10-03 Asm Ip Holding B.V. Methods for depositing gap filling fluids and related systems and devices
US11781221B2 (en) 2019-05-07 2023-10-10 Asm Ip Holding B.V. Chemical source vessel with dip tube
US11781243B2 (en) 2020-02-17 2023-10-10 Asm Ip Holding B.V. Method for depositing low temperature phosphorous-doped silicon
US11804364B2 (en) 2020-05-19 2023-10-31 Asm Ip Holding B.V. Substrate processing apparatus
US11814747B2 (en) 2019-04-24 2023-11-14 Asm Ip Holding B.V. Gas-phase reactor system-with a reaction chamber, a solid precursor source vessel, a gas distribution system, and a flange assembly
US11821078B2 (en) 2020-04-15 2023-11-21 Asm Ip Holding B.V. Method for forming precoat film and method for forming silicon-containing film
US11823876B2 (en) 2019-09-05 2023-11-21 Asm Ip Holding B.V. Substrate processing apparatus
US11823866B2 (en) 2020-04-02 2023-11-21 Asm Ip Holding B.V. Thin film forming method
US11828707B2 (en) 2020-02-04 2023-11-28 Asm Ip Holding B.V. Method and apparatus for transmittance measurements of large articles
US11827981B2 (en) 2020-10-14 2023-11-28 Asm Ip Holding B.V. Method of depositing material on stepped structure
US11830730B2 (en) 2017-08-29 2023-11-28 Asm Ip Holding B.V. Layer forming method and apparatus
US11830738B2 (en) 2020-04-03 2023-11-28 Asm Ip Holding B.V. Method for forming barrier layer and method for manufacturing semiconductor device
US11840761B2 (en) 2019-12-04 2023-12-12 Asm Ip Holding B.V. Substrate processing apparatus
US11873557B2 (en) 2020-10-22 2024-01-16 Asm Ip Holding B.V. Method of depositing vanadium metal
US11876356B2 (en) 2020-03-11 2024-01-16 Asm Ip Holding B.V. Lockout tagout assembly and system and method of using same
US11885023B2 (en) 2018-10-01 2024-01-30 Asm Ip Holding B.V. Substrate retaining apparatus, system including the apparatus, and method of using same
US11885020B2 (en) 2020-12-22 2024-01-30 Asm Ip Holding B.V. Transition metal deposition method
USD1012873S1 (en) 2020-09-24 2024-01-30 Asm Ip Holding B.V. Electrode for semiconductor processing apparatus
US11885013B2 (en) 2019-12-17 2024-01-30 Asm Ip Holding B.V. Method of forming vanadium nitride layer and structure including the vanadium nitride layer
US11887857B2 (en) 2020-04-24 2024-01-30 Asm Ip Holding B.V. Methods and systems for depositing a layer comprising vanadium, nitrogen, and a further element
US11891696B2 (en) 2020-11-30 2024-02-06 Asm Ip Holding B.V. Injector configured for arrangement within a reaction chamber of a substrate processing apparatus
US11898243B2 (en) 2020-04-24 2024-02-13 Asm Ip Holding B.V. Method of forming vanadium nitride-containing layer
US11901179B2 (en) 2020-10-28 2024-02-13 Asm Ip Holding B.V. Method and device for depositing silicon onto substrates
US11915929B2 (en) 2019-11-26 2024-02-27 Asm Ip Holding B.V. Methods for selectively forming a target film on a substrate comprising a first dielectric surface and a second metallic surface
US11923181B2 (en) 2019-11-29 2024-03-05 Asm Ip Holding B.V. Substrate processing apparatus for minimizing the effect of a filling gas during substrate processing
US11929251B2 (en) 2019-12-02 2024-03-12 Asm Ip Holding B.V. Substrate processing apparatus having electrostatic chuck and substrate processing method
US11946137B2 (en) 2020-12-16 2024-04-02 Asm Ip Holding B.V. Runout and wobble measurement fixtures
US11959168B2 (en) 2021-04-26 2024-04-16 Asm Ip Holding B.V. Solid source precursor vessel

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2293322A1 (en) * 2000-06-08 2011-03-09 Genitech, Inc. Method for forming a metal nitride layer
DE10111938A1 (en) * 2001-03-13 2002-09-26 Merck Patent Gmbh Production of high-temperature superconductor powders in a pulsation reactor
KR100760291B1 (en) * 2001-11-08 2007-09-19 에이에스엠지니텍코리아 주식회사 Method for forming thin film
US20040036129A1 (en) * 2002-08-22 2004-02-26 Micron Technology, Inc. Atomic layer deposition of CMOS gates with variable work functions
US6967154B2 (en) 2002-08-26 2005-11-22 Micron Technology, Inc. Enhanced atomic layer deposition
KR20050028980A (en) * 2003-09-19 2005-03-24 한국전자통신연구원 Inorganic thin film electroluminescent device and method for manufacturing the same
US20050181535A1 (en) * 2004-02-17 2005-08-18 Yun Sun J. Method of fabricating passivation layer for organic devices
US7435454B2 (en) * 2005-03-21 2008-10-14 Tokyo Electron Limited Plasma enhanced atomic layer deposition system and method
US7341959B2 (en) * 2005-03-21 2008-03-11 Tokyo Electron Limited Plasma enhanced atomic layer deposition system and method
US7473637B2 (en) 2005-07-20 2009-01-06 Micron Technology, Inc. ALD formed titanium nitride films
KR100706810B1 (en) * 2006-02-07 2007-04-12 삼성전자주식회사 Cleaning of a thin film deposition apparatus forming of a thin film using the cleaning
US7709402B2 (en) 2006-02-16 2010-05-04 Micron Technology, Inc. Conductive layers for hafnium silicon oxynitride films
US7692222B2 (en) * 2006-11-07 2010-04-06 Raytheon Company Atomic layer deposition in the formation of gate structures for III-V semiconductor
US7939932B2 (en) * 2007-06-20 2011-05-10 Analog Devices, Inc. Packaged chip devices with atomic layer deposition protective films
US7910497B2 (en) * 2007-07-30 2011-03-22 Applied Materials, Inc. Method of forming dielectric layers on a substrate and apparatus therefor
US20090035946A1 (en) * 2007-07-31 2009-02-05 Asm International N.V. In situ deposition of different metal-containing films using cyclopentadienyl metal precursors
US7737458B2 (en) * 2008-02-25 2010-06-15 Panasonic Corporation Light emitting device having a straight-line shape
US8383525B2 (en) * 2008-04-25 2013-02-26 Asm America, Inc. Plasma-enhanced deposition process for forming a metal oxide thin film and related structures
CN104746045B (en) * 2013-12-26 2018-03-06 北京北方华创微电子装备有限公司 Chemical gaseous phase depositing process and device
KR102293494B1 (en) * 2015-04-27 2021-08-26 주성엔지니어링(주) Film for preventing humidity from percolation and Method for manufacturing the same
US9523148B1 (en) * 2015-08-25 2016-12-20 Asm Ip Holdings B.V. Process for deposition of titanium oxynitride for use in integrated circuit fabrication
US20170237001A1 (en) * 2016-02-17 2017-08-17 Arm Ltd. Fabrication of correlated electron material devices comprising nitrogen
KR102483915B1 (en) * 2017-10-12 2023-01-04 주성엔지니어링(주) Method for forming thin film
KR102102609B1 (en) * 2019-09-24 2020-04-21 서울대학교 산학협력단 Forming method for dielectric film, manufacturing method for semiconductor device, and semiconductor device manufactured thereby

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100273473B1 (en) * 1999-04-06 2000-11-15 이경수 Method for forming a thin film
KR100721503B1 (en) * 2000-06-08 2007-05-23 에이에스엠지니텍코리아 주식회사 Method for forming a thin film
KR100384850B1 (en) * 2000-12-14 2003-05-22 주식회사 하이닉스반도체 Method for forming Ta2O5 dielectric layer
KR20020065245A (en) * 2001-02-06 2002-08-13 주식회사 하이닉스반도체 thin film deposition method using Plasma Enhanced Atomic Layer Deposition method
US6960537B2 (en) * 2001-10-02 2005-11-01 Asm America, Inc. Incorporation of nitrogen into high k dielectric film

Cited By (480)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050008779A1 (en) * 2002-04-08 2005-01-13 Yang Michael Xi Multiple precursor cyclical depositon system
US8071167B2 (en) 2002-06-14 2011-12-06 Applied Materials, Inc. Surface pre-treatment for enhancement of nucleation of high dielectric constant materials
US20060264067A1 (en) * 2002-06-14 2006-11-23 Kher Shreyas S Surface pre-treatment for enhancement of nucleation of high dielectric constant materials
US20050009371A1 (en) * 2002-06-14 2005-01-13 Metzner Craig R. System and method for forming a gate dielectric
US20100239758A1 (en) * 2002-06-14 2010-09-23 Kher Shreyas S Surface pre-treatment for enhancement of nucleation of high dielectric constant materials
US20030232501A1 (en) * 2002-06-14 2003-12-18 Kher Shreyas S. Surface pre-treatment for enhancement of nucleation of high dielectric constant materials
US20080057737A1 (en) * 2002-06-14 2008-03-06 Metzner Craig R System and method for forming a gate dielectric
US20040198069A1 (en) * 2003-04-04 2004-10-07 Applied Materials, Inc. Method for hafnium nitride deposition
US20050153571A1 (en) * 2003-11-17 2005-07-14 Yoshihide Senzaki Nitridation of high-k dielectric films
US20060027882A1 (en) * 2004-01-21 2006-02-09 Nima Mokhlesi Dielectric layer created using ALD to deposit multiple components
US20060008999A1 (en) * 2004-01-21 2006-01-12 Nima Mohklesi Creating a dielectric layer using ALD to deposit multiple components
US7794544B2 (en) 2004-05-12 2010-09-14 Applied Materials, Inc. Control of gas flow and delivery to suppress the formation of particles in an MOCVD/ALD system
US20050271812A1 (en) * 2004-05-12 2005-12-08 Myo Nyi O Apparatuses and methods for atomic layer deposition of hafnium-containing high-k dielectric materials
US8282992B2 (en) 2004-05-12 2012-10-09 Applied Materials, Inc. Methods for atomic layer deposition of hafnium-containing high-K dielectric materials
US8343279B2 (en) 2004-05-12 2013-01-01 Applied Materials, Inc. Apparatuses for atomic layer deposition
US8119210B2 (en) 2004-05-21 2012-02-21 Applied Materials, Inc. Formation of a silicon oxynitride layer on a high-k dielectric material
WO2005117086A1 (en) * 2004-05-21 2005-12-08 Applied Materials, Inc. Stabilization of high-k dielectric materials
US8323754B2 (en) 2004-05-21 2012-12-04 Applied Materials, Inc. Stabilization of high-k dielectric materials
US20060062917A1 (en) * 2004-05-21 2006-03-23 Shankar Muthukrishnan Vapor deposition of hafnium silicate materials with tris(dimethylamino)silane
EP1856724A2 (en) * 2005-02-25 2007-11-21 Freescale Semiconductor, Inc. Method of making a nitrided gate dielectric
EP1856724A4 (en) * 2005-02-25 2009-03-11 Freescale Semiconductor Inc Method of making a nitrided gate dielectric
US20070049043A1 (en) * 2005-08-23 2007-03-01 Applied Materials, Inc. Nitrogen profile engineering in HI-K nitridation for device performance enhancement and reliability improvement
US7972978B2 (en) 2005-08-26 2011-07-05 Applied Materials, Inc. Pretreatment processes within a batch ALD reactor
US20070059945A1 (en) * 2005-09-12 2007-03-15 Nima Mohklesi Atomic layer deposition with nitridation and oxidation
WO2007033003A1 (en) * 2005-09-12 2007-03-22 Sandisk Corporation Atomic layer deposition with nitridation and oxidation
US8163648B2 (en) 2005-10-06 2012-04-24 Micron Technology, Inc. Atomic layer deposition methods
US7582562B2 (en) * 2005-10-06 2009-09-01 Micron Technology, Inc. Atomic layer deposition methods
US7985679B2 (en) * 2005-10-06 2011-07-26 Micron Technology, Inc. Atomic layer deposition methods
US20090280639A1 (en) * 2005-10-06 2009-11-12 Micron Technology, Inc. Atomic Layer Deposition Methods
US20070082468A1 (en) * 2005-10-06 2007-04-12 Blalock Guy T Atomic layer deposition methods
US20070207624A1 (en) * 2006-03-02 2007-09-06 Applied Materials, Inc. Multiple nitrogen plasma treatments for thin SiON dielectrics
US7798096B2 (en) 2006-05-05 2010-09-21 Applied Materials, Inc. Plasma, UV and ion/neutral assisted ALD or CVD in a batch tool
US8043907B2 (en) 2008-03-31 2011-10-25 Applied Materials, Inc. Atomic layer deposition processes for non-volatile memory devices
US7659158B2 (en) 2008-03-31 2010-02-09 Applied Materials, Inc. Atomic layer deposition processes for non-volatile memory devices
US8491967B2 (en) 2008-09-08 2013-07-23 Applied Materials, Inc. In-situ chamber treatment and deposition process
US20100062149A1 (en) * 2008-09-08 2010-03-11 Applied Materials, Inc. Method for tuning a deposition rate during an atomic layer deposition process
US9418890B2 (en) 2008-09-08 2016-08-16 Applied Materials, Inc. Method for tuning a deposition rate during an atomic layer deposition process
US10378106B2 (en) 2008-11-14 2019-08-13 Asm Ip Holding B.V. Method of forming insulation film by modified PEALD
US9466574B2 (en) * 2009-02-02 2016-10-11 Asm America, Inc. Plasma-enhanced atomic layer deposition of conductive material over dielectric layers
US10480072B2 (en) 2009-04-06 2019-11-19 Asm Ip Holding B.V. Semiconductor processing reactor and components thereof
US10844486B2 (en) 2009-04-06 2020-11-24 Asm Ip Holding B.V. Semiconductor processing reactor and components thereof
US9394608B2 (en) 2009-04-06 2016-07-19 Asm America, Inc. Semiconductor processing reactor and components thereof
US20140346650A1 (en) * 2009-08-14 2014-11-27 Asm Ip Holding B.V. Systems and methods for thin-film deposition of metal oxides using excited nitrogen-oxygen species
US10804098B2 (en) * 2009-08-14 2020-10-13 Asm Ip Holding B.V. Systems and methods for thin-film deposition of metal oxides using excited nitrogen-oxygen species
CN102082087A (en) * 2009-11-30 2011-06-01 海力士半导体有限公司 Semiconductor device including carbon-containing electrode and method for fabricating the same
JP2012184499A (en) * 2011-02-18 2012-09-27 Hitachi Kokusai Electric Inc Manufacturing method, substrate processing device, and substrate processing method of semiconductor device
US9650715B2 (en) 2011-02-18 2017-05-16 Hitachi Kokusai Electric Inc. Method of forming metal-containing film
US10707106B2 (en) 2011-06-06 2020-07-07 Asm Ip Holding B.V. High-throughput semiconductor-processing apparatus equipped with multiple dual-chamber modules
US9793148B2 (en) 2011-06-22 2017-10-17 Asm Japan K.K. Method for positioning wafers in multiple wafer transport
US10364496B2 (en) 2011-06-27 2019-07-30 Asm Ip Holding B.V. Dual section module having shared and unshared mass flow controllers
US10854498B2 (en) 2011-07-15 2020-12-01 Asm Ip Holding B.V. Wafer-supporting device and method for producing same
US11725277B2 (en) 2011-07-20 2023-08-15 Asm Ip Holding B.V. Pressure transmitter for a semiconductor processing environment
JP2013026479A (en) * 2011-07-21 2013-02-04 Mitsui Eng & Shipbuild Co Ltd Atomic layer growth method and atomic layer growth apparatus
US9341296B2 (en) 2011-10-27 2016-05-17 Asm America, Inc. Heater jacket for a fluid line
US9096931B2 (en) 2011-10-27 2015-08-04 Asm America, Inc Deposition valve assembly and method of heating the same
US9892908B2 (en) 2011-10-28 2018-02-13 Asm America, Inc. Process feed management for semiconductor substrate processing
US9017481B1 (en) 2011-10-28 2015-04-28 Asm America, Inc. Process feed management for semiconductor substrate processing
US10832903B2 (en) 2011-10-28 2020-11-10 Asm Ip Holding B.V. Process feed management for semiconductor substrate processing
US9167625B2 (en) 2011-11-23 2015-10-20 Asm Ip Holding B.V. Radiation shielding for a substrate holder
US9005539B2 (en) 2011-11-23 2015-04-14 Asm Ip Holding B.V. Chamber sealing member
US9340874B2 (en) 2011-11-23 2016-05-17 Asm Ip Holding B.V. Chamber sealing member
US9202727B2 (en) 2012-03-02 2015-12-01 ASM IP Holding Susceptor heater shim
US9384987B2 (en) 2012-04-04 2016-07-05 Asm Ip Holding B.V. Metal oxide protective layer for a semiconductor device
US9029253B2 (en) 2012-05-02 2015-05-12 Asm Ip Holding B.V. Phase-stabilized thin films, structures and devices including the thin films, and methods of forming same
US9177784B2 (en) 2012-05-07 2015-11-03 Asm Ip Holdings B.V. Semiconductor device dielectric interface layer
US9299595B2 (en) 2012-06-27 2016-03-29 Asm Ip Holding B.V. Susceptor heater and method of heating a substrate
US9558931B2 (en) 2012-07-27 2017-01-31 Asm Ip Holding B.V. System and method for gas-phase sulfur passivation of a semiconductor surface
US9117866B2 (en) 2012-07-31 2015-08-25 Asm Ip Holding B.V. Apparatus and method for calculating a wafer position in a processing chamber under process conditions
US10566223B2 (en) 2012-08-28 2020-02-18 Asm Ip Holdings B.V. Systems and methods for dynamic semiconductor process scheduling
US9659799B2 (en) 2012-08-28 2017-05-23 Asm Ip Holding B.V. Systems and methods for dynamic semiconductor process scheduling
US9169975B2 (en) 2012-08-28 2015-10-27 Asm Ip Holding B.V. Systems and methods for mass flow controller verification
US10023960B2 (en) 2012-09-12 2018-07-17 Asm Ip Holdings B.V. Process gas management for an inductively-coupled plasma deposition reactor
US9021985B2 (en) 2012-09-12 2015-05-05 Asm Ip Holdings B.V. Process gas management for an inductively-coupled plasma deposition reactor
US9605342B2 (en) 2012-09-12 2017-03-28 Asm Ip Holding B.V. Process gas management for an inductively-coupled plasma deposition reactor
US9324811B2 (en) 2012-09-26 2016-04-26 Asm Ip Holding B.V. Structures and devices including a tensile-stressed silicon arsenic layer and methods of forming same
US11501956B2 (en) 2012-10-12 2022-11-15 Asm Ip Holding B.V. Semiconductor reaction chamber showerhead
US10714315B2 (en) 2012-10-12 2020-07-14 Asm Ip Holdings B.V. Semiconductor reaction chamber showerhead
US9640416B2 (en) 2012-12-26 2017-05-02 Asm Ip Holding B.V. Single-and dual-chamber module-attachable wafer-handling chamber
US9228259B2 (en) 2013-02-01 2016-01-05 Asm Ip Holding B.V. Method for treatment of deposition reactor
US9484191B2 (en) 2013-03-08 2016-11-01 Asm Ip Holding B.V. Pulsed remote plasma method and system
US10340125B2 (en) 2013-03-08 2019-07-02 Asm Ip Holding B.V. Pulsed remote plasma method and system
US10366864B2 (en) 2013-03-08 2019-07-30 Asm Ip Holding B.V. Method and system for in-situ formation of intermediate reactive species
US9589770B2 (en) 2013-03-08 2017-03-07 Asm Ip Holding B.V. Method and systems for in-situ formation of intermediate reactive species
US9790595B2 (en) 2013-07-12 2017-10-17 Asm Ip Holding B.V. Method and system to reduce outgassing in a reaction chamber
US9412564B2 (en) 2013-07-22 2016-08-09 Asm Ip Holding B.V. Semiconductor reaction chamber with plasma capabilities
US9018111B2 (en) 2013-07-22 2015-04-28 Asm Ip Holding B.V. Semiconductor reaction chamber with plasma capabilities
US9793115B2 (en) 2013-08-14 2017-10-17 Asm Ip Holding B.V. Structures and devices including germanium-tin films and methods of forming same
US9396934B2 (en) 2013-08-14 2016-07-19 Asm Ip Holding B.V. Methods of forming films including germanium tin and structures and devices including the films
US9240412B2 (en) 2013-09-27 2016-01-19 Asm Ip Holding B.V. Semiconductor structure and device and methods of forming same using selective epitaxial process
US10361201B2 (en) 2013-09-27 2019-07-23 Asm Ip Holding B.V. Semiconductor structure and device formed using selective epitaxial process
US9556516B2 (en) 2013-10-09 2017-01-31 ASM IP Holding B.V Method for forming Ti-containing film by PEALD using TDMAT or TDEAT
US9605343B2 (en) 2013-11-13 2017-03-28 Asm Ip Holding B.V. Method for forming conformal carbon films, structures conformal carbon film, and system of forming same
US10179947B2 (en) 2013-11-26 2019-01-15 Asm Ip Holding B.V. Method for forming conformal nitrided, oxidized, or carbonized dielectric film by atomic layer deposition
US10683571B2 (en) 2014-02-25 2020-06-16 Asm Ip Holding B.V. Gas supply manifold and method of supplying gases to chamber using same
US10604847B2 (en) 2014-03-18 2020-03-31 Asm Ip Holding B.V. Gas distribution system, reactor including the system, and methods of using the same
US9447498B2 (en) 2014-03-18 2016-09-20 Asm Ip Holding B.V. Method for performing uniform processing in gas system-sharing multiple reaction chambers
US10167557B2 (en) 2014-03-18 2019-01-01 Asm Ip Holding B.V. Gas distribution system, reactor including the system, and methods of using the same
US11015245B2 (en) 2014-03-19 2021-05-25 Asm Ip Holding B.V. Gas-phase reactor and system having exhaust plenum and components thereof
US9404587B2 (en) 2014-04-24 2016-08-02 ASM IP Holding B.V Lockout tagout for semiconductor vacuum valve
US10858737B2 (en) 2014-07-28 2020-12-08 Asm Ip Holding B.V. Showerhead assembly and components thereof
US9543180B2 (en) 2014-08-01 2017-01-10 Asm Ip Holding B.V. Apparatus and method for transporting wafers between wafer carrier and process tool under vacuum
US9890456B2 (en) 2014-08-21 2018-02-13 Asm Ip Holding B.V. Method and system for in situ formation of gas-phase compounds
US10787741B2 (en) 2014-08-21 2020-09-29 Asm Ip Holding B.V. Method and system for in situ formation of gas-phase compounds
US11142683B2 (en) * 2014-09-17 2021-10-12 Koninklijke Philips N.V. Phosphor with hybrid coating and method of production
US9657845B2 (en) 2014-10-07 2017-05-23 Asm Ip Holding B.V. Variable conductance gas distribution apparatus and method
US10941490B2 (en) 2014-10-07 2021-03-09 Asm Ip Holding B.V. Multiple temperature range susceptor, assembly, reactor and system including the susceptor, and methods of using the same
US10561975B2 (en) 2014-10-07 2020-02-18 Asm Ip Holdings B.V. Variable conductance gas distribution apparatus and method
US11795545B2 (en) 2014-10-07 2023-10-24 Asm Ip Holding B.V. Multiple temperature range susceptor, assembly, reactor and system including the susceptor, and methods of using the same
US9891521B2 (en) 2014-11-19 2018-02-13 Asm Ip Holding B.V. Method for depositing thin film
US10438965B2 (en) 2014-12-22 2019-10-08 Asm Ip Holding B.V. Semiconductor device and manufacturing method thereof
US9899405B2 (en) 2014-12-22 2018-02-20 Asm Ip Holding B.V. Semiconductor device and manufacturing method thereof
US9478415B2 (en) 2015-02-13 2016-10-25 Asm Ip Holding B.V. Method for forming film having low resistance and shallow junction depth
US10529542B2 (en) 2015-03-11 2020-01-07 Asm Ip Holdings B.V. Cross-flow reactor and method
US10276355B2 (en) 2015-03-12 2019-04-30 Asm Ip Holding B.V. Multi-zone reactor, system including the reactor, and method of using the same
US11742189B2 (en) 2015-03-12 2023-08-29 Asm Ip Holding B.V. Multi-zone reactor, system including the reactor, and method of using the same
US10458018B2 (en) 2015-06-26 2019-10-29 Asm Ip Holding B.V. Structures including metal carbide material, devices including the structures, and methods of forming same
US11242598B2 (en) 2015-06-26 2022-02-08 Asm Ip Holding B.V. Structures including metal carbide material, devices including the structures, and methods of forming same
US10600673B2 (en) 2015-07-07 2020-03-24 Asm Ip Holding B.V. Magnetic susceptor to baseplate seal
US10043661B2 (en) 2015-07-13 2018-08-07 Asm Ip Holding B.V. Method for protecting layer by forming hydrocarbon-based extremely thin film
US9899291B2 (en) 2015-07-13 2018-02-20 Asm Ip Holding B.V. Method for protecting layer by forming hydrocarbon-based extremely thin film
US10083836B2 (en) 2015-07-24 2018-09-25 Asm Ip Holding B.V. Formation of boron-doped titanium metal films with high work function
US10087525B2 (en) 2015-08-04 2018-10-02 Asm Ip Holding B.V. Variable gap hard stop design
US9773991B2 (en) * 2015-08-05 2017-09-26 Uchicago Argonne, Llc Non-hydrolytic metal oxide films for perovskite halide overcoating and stabilization
US20170040560A1 (en) * 2015-08-05 2017-02-09 Uchicago Argonne, Llc Non-hydrolytic metal oxide films for perovskite halide overcoating and stabilization
US9647114B2 (en) 2015-08-14 2017-05-09 Asm Ip Holding B.V. Methods of forming highly p-type doped germanium tin films and structures and devices including the films
US9711345B2 (en) 2015-08-25 2017-07-18 Asm Ip Holding B.V. Method for forming aluminum nitride-based film by PEALD
US10312129B2 (en) 2015-09-29 2019-06-04 Asm Ip Holding B.V. Variable adjustment for precise matching of multiple chamber cavity housings
US9960072B2 (en) 2015-09-29 2018-05-01 Asm Ip Holding B.V. Variable adjustment for precise matching of multiple chamber cavity housings
US9909214B2 (en) 2015-10-15 2018-03-06 Asm Ip Holding B.V. Method for depositing dielectric film in trenches by PEALD
US10211308B2 (en) 2015-10-21 2019-02-19 Asm Ip Holding B.V. NbMC layers
US11233133B2 (en) 2015-10-21 2022-01-25 Asm Ip Holding B.V. NbMC layers
US10322384B2 (en) 2015-11-09 2019-06-18 Asm Ip Holding B.V. Counter flow mixer for process chamber
US9455138B1 (en) 2015-11-10 2016-09-27 Asm Ip Holding B.V. Method for forming dielectric film in trenches by PEALD using H-containing gas
US9905420B2 (en) 2015-12-01 2018-02-27 Asm Ip Holding B.V. Methods of forming silicon germanium tin films and structures and devices including the films
US9607837B1 (en) 2015-12-21 2017-03-28 Asm Ip Holding B.V. Method for forming silicon oxide cap layer for solid state diffusion process
US9735024B2 (en) 2015-12-28 2017-08-15 Asm Ip Holding B.V. Method of atomic layer etching using functional group-containing fluorocarbon
US9627221B1 (en) 2015-12-28 2017-04-18 Asm Ip Holding B.V. Continuous process incorporating atomic layer etching
US11956977B2 (en) 2015-12-29 2024-04-09 Asm Ip Holding B.V. Atomic layer deposition of III-V compounds to form V-NAND devices
US11139308B2 (en) 2015-12-29 2021-10-05 Asm Ip Holding B.V. Atomic layer deposition of III-V compounds to form V-NAND devices
US10797238B2 (en) 2016-01-26 2020-10-06 Arm Ltd. Fabricating correlated electron material (CEM) devices
US11450804B2 (en) 2016-01-26 2022-09-20 Cerfe Labs, Inc. Fabricating correlated electron material (CEM) devices
US10468251B2 (en) 2016-02-19 2019-11-05 Asm Ip Holding B.V. Method for forming spacers using silicon nitride film for spacer-defined multiple patterning
US10720322B2 (en) 2016-02-19 2020-07-21 Asm Ip Holding B.V. Method for forming silicon nitride film selectively on top surface
US10529554B2 (en) 2016-02-19 2020-01-07 Asm Ip Holding B.V. Method for forming silicon nitride film selectively on sidewalls or flat surfaces of trenches
US9754779B1 (en) 2016-02-19 2017-09-05 Asm Ip Holding B.V. Method for forming silicon nitride film selectively on sidewalls or flat surfaces of trenches
US11676812B2 (en) 2016-02-19 2023-06-13 Asm Ip Holding B.V. Method for forming silicon nitride film selectively on top/bottom portions
US10501866B2 (en) 2016-03-09 2019-12-10 Asm Ip Holding B.V. Gas distribution apparatus for improved film uniformity in an epitaxial system
US10343920B2 (en) 2016-03-18 2019-07-09 Asm Ip Holding B.V. Aligned carbon nanotubes
US10262859B2 (en) 2016-03-24 2019-04-16 Asm Ip Holding B.V. Process for forming a film on a substrate using multi-port injection assemblies
US10865475B2 (en) 2016-04-21 2020-12-15 Asm Ip Holding B.V. Deposition of metal borides and silicides
US10851456B2 (en) 2016-04-21 2020-12-01 Asm Ip Holding B.V. Deposition of metal borides
US10190213B2 (en) 2016-04-21 2019-01-29 Asm Ip Holding B.V. Deposition of metal borides
US10087522B2 (en) 2016-04-21 2018-10-02 Asm Ip Holding B.V. Deposition of metal borides
US10367080B2 (en) 2016-05-02 2019-07-30 Asm Ip Holding B.V. Method of forming a germanium oxynitride film
US11101370B2 (en) 2016-05-02 2021-08-24 Asm Ip Holding B.V. Method of forming a germanium oxynitride film
US10665452B2 (en) 2016-05-02 2020-05-26 Asm Ip Holdings B.V. Source/drain performance through conformal solid state doping
US10032628B2 (en) 2016-05-02 2018-07-24 Asm Ip Holding B.V. Source/drain performance through conformal solid state doping
US10249577B2 (en) 2016-05-17 2019-04-02 Asm Ip Holding B.V. Method of forming metal interconnection and method of fabricating semiconductor apparatus using the method
US11453943B2 (en) 2016-05-25 2022-09-27 Asm Ip Holding B.V. Method for forming carbon-containing silicon/metal oxide or nitride film by ALD using silicon precursor and hydrocarbon precursor
US10388509B2 (en) 2016-06-28 2019-08-20 Asm Ip Holding B.V. Formation of epitaxial layers via dislocation filtering
US10541173B2 (en) 2016-07-08 2020-01-21 Asm Ip Holding B.V. Selective deposition method to form air gaps
US9859151B1 (en) 2016-07-08 2018-01-02 Asm Ip Holding B.V. Selective film deposition method to form air gaps
US11649546B2 (en) 2016-07-08 2023-05-16 Asm Ip Holding B.V. Organic reactants for atomic layer deposition
US11749562B2 (en) 2016-07-08 2023-09-05 Asm Ip Holding B.V. Selective deposition method to form air gaps
US10612137B2 (en) 2016-07-08 2020-04-07 Asm Ip Holdings B.V. Organic reactants for atomic layer deposition
US11094582B2 (en) 2016-07-08 2021-08-17 Asm Ip Holding B.V. Selective deposition method to form air gaps
US9793135B1 (en) 2016-07-14 2017-10-17 ASM IP Holding B.V Method of cyclic dry etching using etchant film
US10714385B2 (en) 2016-07-19 2020-07-14 Asm Ip Holding B.V. Selective deposition of tungsten
US10381226B2 (en) 2016-07-27 2019-08-13 Asm Ip Holding B.V. Method of processing substrate
US9887082B1 (en) 2016-07-28 2018-02-06 Asm Ip Holding B.V. Method and apparatus for filling a gap
US9812320B1 (en) 2016-07-28 2017-11-07 Asm Ip Holding B.V. Method and apparatus for filling a gap
US10741385B2 (en) 2016-07-28 2020-08-11 Asm Ip Holding B.V. Method and apparatus for filling a gap
US10177025B2 (en) 2016-07-28 2019-01-08 Asm Ip Holding B.V. Method and apparatus for filling a gap
US11694892B2 (en) 2016-07-28 2023-07-04 Asm Ip Holding B.V. Method and apparatus for filling a gap
US11107676B2 (en) 2016-07-28 2021-08-31 Asm Ip Holding B.V. Method and apparatus for filling a gap
US10395919B2 (en) 2016-07-28 2019-08-27 Asm Ip Holding B.V. Method and apparatus for filling a gap
US11610775B2 (en) 2016-07-28 2023-03-21 Asm Ip Holding B.V. Method and apparatus for filling a gap
US11205585B2 (en) 2016-07-28 2021-12-21 Asm Ip Holding B.V. Substrate processing apparatus and method of operating the same
US10090316B2 (en) 2016-09-01 2018-10-02 Asm Ip Holding B.V. 3D stacked multilayer semiconductor memory using doped select transistor channel
US10410943B2 (en) 2016-10-13 2019-09-10 Asm Ip Holding B.V. Method for passivating a surface of a semiconductor and related systems
US10943771B2 (en) 2016-10-26 2021-03-09 Asm Ip Holding B.V. Methods for thermally calibrating reaction chambers
US10643826B2 (en) 2016-10-26 2020-05-05 Asm Ip Holdings B.V. Methods for thermally calibrating reaction chambers
US11532757B2 (en) 2016-10-27 2022-12-20 Asm Ip Holding B.V. Deposition of charge trapping layers
US10720331B2 (en) 2016-11-01 2020-07-21 ASM IP Holdings, B.V. Methods for forming a transition metal nitride film on a substrate by atomic layer deposition and related semiconductor device structures
US10714350B2 (en) 2016-11-01 2020-07-14 ASM IP Holdings, B.V. Methods for forming a transition metal niobium nitride film on a substrate by atomic layer deposition and related semiconductor device structures
US10435790B2 (en) 2016-11-01 2019-10-08 Asm Ip Holding B.V. Method of subatmospheric plasma-enhanced ALD using capacitively coupled electrodes with narrow gap
US10643904B2 (en) 2016-11-01 2020-05-05 Asm Ip Holdings B.V. Methods for forming a semiconductor device and related semiconductor device structures
US11810788B2 (en) 2016-11-01 2023-11-07 Asm Ip Holding B.V. Methods for forming a transition metal niobium nitride film on a substrate by atomic layer deposition and related semiconductor device structures
US10229833B2 (en) 2016-11-01 2019-03-12 Asm Ip Holding B.V. Methods for forming a transition metal nitride film on a substrate by atomic layer deposition and related semiconductor device structures
US10644025B2 (en) 2016-11-07 2020-05-05 Asm Ip Holding B.V. Method of processing a substrate and a device manufactured by using the method
US10134757B2 (en) 2016-11-07 2018-11-20 Asm Ip Holding B.V. Method of processing a substrate and a device manufactured by using the method
US10622375B2 (en) 2016-11-07 2020-04-14 Asm Ip Holding B.V. Method of processing a substrate and a device manufactured by using the method
JP2017038088A (en) * 2016-11-09 2017-02-16 東京エレクトロン株式会社 Deposition method and deposition device
US11396702B2 (en) 2016-11-15 2022-07-26 Asm Ip Holding B.V. Gas supply unit and substrate processing apparatus including the gas supply unit
US10934619B2 (en) 2016-11-15 2021-03-02 Asm Ip Holding B.V. Gas supply unit and substrate processing apparatus including the gas supply unit
US10340135B2 (en) 2016-11-28 2019-07-02 Asm Ip Holding B.V. Method of topologically restricted plasma-enhanced cyclic deposition of silicon or metal nitride
US11222772B2 (en) 2016-12-14 2022-01-11 Asm Ip Holding B.V. Substrate processing apparatus
US9916980B1 (en) 2016-12-15 2018-03-13 Asm Ip Holding B.V. Method of forming a structure on a substrate
US11851755B2 (en) 2016-12-15 2023-12-26 Asm Ip Holding B.V. Sequential infiltration synthesis apparatus and a method of forming a patterned structure
US11581186B2 (en) 2016-12-15 2023-02-14 Asm Ip Holding B.V. Sequential infiltration synthesis apparatus
US11447861B2 (en) 2016-12-15 2022-09-20 Asm Ip Holding B.V. Sequential infiltration synthesis apparatus and a method of forming a patterned structure
US11001925B2 (en) 2016-12-19 2021-05-11 Asm Ip Holding B.V. Substrate processing apparatus
US11251035B2 (en) 2016-12-22 2022-02-15 Asm Ip Holding B.V. Method of forming a structure on a substrate
US10784102B2 (en) 2016-12-22 2020-09-22 Asm Ip Holding B.V. Method of forming a structure on a substrate
US10269558B2 (en) 2016-12-22 2019-04-23 Asm Ip Holding B.V. Method of forming a structure on a substrate
US10867788B2 (en) 2016-12-28 2020-12-15 Asm Ip Holding B.V. Method of forming a structure on a substrate
US11390950B2 (en) 2017-01-10 2022-07-19 Asm Ip Holding B.V. Reactor system and method to reduce residue buildup during a film deposition process
US10655221B2 (en) 2017-02-09 2020-05-19 Asm Ip Holding B.V. Method for depositing oxide film by thermal ALD and PEALD
US10468261B2 (en) 2017-02-15 2019-11-05 Asm Ip Holding B.V. Methods for forming a metallic film on a substrate by cyclical deposition and related semiconductor device structures
US11410851B2 (en) 2017-02-15 2022-08-09 Asm Ip Holding B.V. Methods for forming a metallic film on a substrate by cyclical deposition and related semiconductor device structures
US10468262B2 (en) 2017-02-15 2019-11-05 Asm Ip Holding B.V. Methods for forming a metallic film on a substrate by a cyclical deposition and related semiconductor device structures
US10529563B2 (en) 2017-03-29 2020-01-07 Asm Ip Holdings B.V. Method for forming doped metal oxide films on a substrate by cyclical deposition and related semiconductor device structures
US10283353B2 (en) 2017-03-29 2019-05-07 Asm Ip Holding B.V. Method of reforming insulating film deposited on substrate with recess pattern
US11658030B2 (en) 2017-03-29 2023-05-23 Asm Ip Holding B.V. Method for forming doped metal oxide films on a substrate by cyclical deposition and related semiconductor device structures
US10103040B1 (en) 2017-03-31 2018-10-16 Asm Ip Holding B.V. Apparatus and method for manufacturing a semiconductor device
USD830981S1 (en) 2017-04-07 2018-10-16 Asm Ip Holding B.V. Susceptor for semiconductor substrate processing apparatus
US10714335B2 (en) 2017-04-25 2020-07-14 Asm Ip Holding B.V. Method of depositing thin film and method of manufacturing semiconductor device
US10950432B2 (en) 2017-04-25 2021-03-16 Asm Ip Holding B.V. Method of depositing thin film and method of manufacturing semiconductor device
US10770286B2 (en) 2017-05-08 2020-09-08 Asm Ip Holdings B.V. Methods for selectively forming a silicon nitride film on a substrate and related semiconductor device structures
US10446393B2 (en) 2017-05-08 2019-10-15 Asm Ip Holding B.V. Methods for forming silicon-containing epitaxial layers and related semiconductor device structures
US11848200B2 (en) 2017-05-08 2023-12-19 Asm Ip Holding B.V. Methods for selectively forming a silicon nitride film on a substrate and related semiconductor device structures
US10892156B2 (en) 2017-05-08 2021-01-12 Asm Ip Holding B.V. Methods for forming a silicon nitride film on a substrate and related semiconductor device structures
US10504742B2 (en) 2017-05-31 2019-12-10 Asm Ip Holding B.V. Method of atomic layer etching using hydrogen plasma
US10886123B2 (en) 2017-06-02 2021-01-05 Asm Ip Holding B.V. Methods for forming low temperature semiconductor layers and related semiconductor device structures
US11306395B2 (en) 2017-06-28 2022-04-19 Asm Ip Holding B.V. Methods for depositing a transition metal nitride film on a substrate by atomic layer deposition and related deposition apparatus
US10593880B2 (en) 2017-07-03 2020-03-17 Arm Limited Method for the manufacture of a correlated electron material device
US10685834B2 (en) 2017-07-05 2020-06-16 Asm Ip Holdings B.V. Methods for forming a silicon germanium tin layer and related semiconductor device structures
US11695054B2 (en) 2017-07-18 2023-07-04 Asm Ip Holding B.V. Methods for forming a semiconductor device structure and related semiconductor device structures
US11164955B2 (en) 2017-07-18 2021-11-02 Asm Ip Holding B.V. Methods for forming a semiconductor device structure and related semiconductor device structures
US10734497B2 (en) 2017-07-18 2020-08-04 Asm Ip Holding B.V. Methods for forming a semiconductor device structure and related semiconductor device structures
US11004977B2 (en) 2017-07-19 2021-05-11 Asm Ip Holding B.V. Method for depositing a group IV semiconductor and related semiconductor device structures
US11374112B2 (en) 2017-07-19 2022-06-28 Asm Ip Holding B.V. Method for depositing a group IV semiconductor and related semiconductor device structures
US10541333B2 (en) 2017-07-19 2020-01-21 Asm Ip Holding B.V. Method for depositing a group IV semiconductor and related semiconductor device structures
US11018002B2 (en) 2017-07-19 2021-05-25 Asm Ip Holding B.V. Method for selectively depositing a Group IV semiconductor and related semiconductor device structures
US10605530B2 (en) 2017-07-26 2020-03-31 Asm Ip Holding B.V. Assembly of a liner and a flange for a vertical furnace as well as the liner and the vertical furnace
US10312055B2 (en) 2017-07-26 2019-06-04 Asm Ip Holding B.V. Method of depositing film by PEALD using negative bias
US11802338B2 (en) 2017-07-26 2023-10-31 Asm Ip Holding B.V. Chemical treatment, deposition and/or infiltration apparatus and method for using the same
US10590535B2 (en) 2017-07-26 2020-03-17 Asm Ip Holdings B.V. Chemical treatment, deposition and/or infiltration apparatus and method for using the same
US10770336B2 (en) 2017-08-08 2020-09-08 Asm Ip Holding B.V. Substrate lift mechanism and reactor including same
US11587821B2 (en) 2017-08-08 2023-02-21 Asm Ip Holding B.V. Substrate lift mechanism and reactor including same
US10692741B2 (en) 2017-08-08 2020-06-23 Asm Ip Holdings B.V. Radiation shield
US11417545B2 (en) 2017-08-08 2022-08-16 Asm Ip Holding B.V. Radiation shield
US10672636B2 (en) 2017-08-09 2020-06-02 Asm Ip Holding B.V. Cassette holder assembly for a substrate cassette and holding member for use in such assembly
US11139191B2 (en) 2017-08-09 2021-10-05 Asm Ip Holding B.V. Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith
US10249524B2 (en) 2017-08-09 2019-04-02 Asm Ip Holding B.V. Cassette holder assembly for a substrate cassette and holding member for use in such assembly
US11769682B2 (en) 2017-08-09 2023-09-26 Asm Ip Holding B.V. Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith
US10236177B1 (en) 2017-08-22 2019-03-19 ASM IP Holding B.V.. Methods for depositing a doped germanium tin semiconductor and related semiconductor device structures
USD900036S1 (en) 2017-08-24 2020-10-27 Asm Ip Holding B.V. Heater electrical connector and adapter
US11830730B2 (en) 2017-08-29 2023-11-28 Asm Ip Holding B.V. Layer forming method and apparatus
US11581220B2 (en) 2017-08-30 2023-02-14 Asm Ip Holding B.V. Methods for depositing a molybdenum metal film over a dielectric surface of a substrate by a cyclical deposition process and related semiconductor device structures
US11295980B2 (en) 2017-08-30 2022-04-05 Asm Ip Holding B.V. Methods for depositing a molybdenum metal film over a dielectric surface of a substrate by a cyclical deposition process and related semiconductor device structures
US11056344B2 (en) 2017-08-30 2021-07-06 Asm Ip Holding B.V. Layer forming method
US11069510B2 (en) 2017-08-30 2021-07-20 Asm Ip Holding B.V. Substrate processing apparatus
US10607895B2 (en) 2017-09-18 2020-03-31 Asm Ip Holdings B.V. Method for forming a semiconductor device structure comprising a gate fill metal
US10928731B2 (en) 2017-09-21 2021-02-23 Asm Ip Holding B.V. Method of sequential infiltration synthesis treatment of infiltrateable material and structures and devices formed using same
US10844484B2 (en) 2017-09-22 2020-11-24 Asm Ip Holding B.V. Apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods
US11387120B2 (en) 2017-09-28 2022-07-12 Asm Ip Holding B.V. Chemical dispensing apparatus and methods for dispensing a chemical to a reaction chamber
US10658205B2 (en) 2017-09-28 2020-05-19 Asm Ip Holdings B.V. Chemical dispensing apparatus and methods for dispensing a chemical to a reaction chamber
US11094546B2 (en) 2017-10-05 2021-08-17 Asm Ip Holding B.V. Method for selectively depositing a metallic film on a substrate
US10403504B2 (en) 2017-10-05 2019-09-03 Asm Ip Holding B.V. Method for selectively depositing a metallic film on a substrate
US10319588B2 (en) 2017-10-10 2019-06-11 Asm Ip Holding B.V. Method for depositing a metal chalcogenide on a substrate by cyclical deposition
US10734223B2 (en) 2017-10-10 2020-08-04 Asm Ip Holding B.V. Method for depositing a metal chalcogenide on a substrate by cyclical deposition
US10923344B2 (en) 2017-10-30 2021-02-16 Asm Ip Holding B.V. Methods for forming a semiconductor structure and related semiconductor structures
US10734244B2 (en) 2017-11-16 2020-08-04 Asm Ip Holding B.V. Method of processing a substrate and a device manufactured by the same
US10910262B2 (en) 2017-11-16 2021-02-02 Asm Ip Holding B.V. Method of selectively depositing a capping layer structure on a semiconductor device structure
US11022879B2 (en) 2017-11-24 2021-06-01 Asm Ip Holding B.V. Method of forming an enhanced unexposed photoresist layer
US11639811B2 (en) 2017-11-27 2023-05-02 Asm Ip Holding B.V. Apparatus including a clean mini environment
US11682572B2 (en) 2017-11-27 2023-06-20 Asm Ip Holdings B.V. Storage device for storing wafer cassettes for use with a batch furnace
US11127617B2 (en) 2017-11-27 2021-09-21 Asm Ip Holding B.V. Storage device for storing wafer cassettes for use with a batch furnace
US10290508B1 (en) 2017-12-05 2019-05-14 Asm Ip Holding B.V. Method for forming vertical spacers for spacer-defined patterning
US10872771B2 (en) 2018-01-16 2020-12-22 Asm Ip Holding B. V. Method for depositing a material film on a substrate within a reaction chamber by a cyclical deposition process and related device structures
US11501973B2 (en) 2018-01-16 2022-11-15 Asm Ip Holding B.V. Method for depositing a material film on a substrate within a reaction chamber by a cyclical deposition process and related device structures
US11393690B2 (en) 2018-01-19 2022-07-19 Asm Ip Holding B.V. Deposition method
US11482412B2 (en) 2018-01-19 2022-10-25 Asm Ip Holding B.V. Method for depositing a gap-fill layer by plasma-assisted deposition
USD903477S1 (en) 2018-01-24 2020-12-01 Asm Ip Holdings B.V. Metal clamp
US11018047B2 (en) 2018-01-25 2021-05-25 Asm Ip Holding B.V. Hybrid lift pin
USD913980S1 (en) 2018-02-01 2021-03-23 Asm Ip Holding B.V. Gas supply plate for semiconductor manufacturing apparatus
USD880437S1 (en) 2018-02-01 2020-04-07 Asm Ip Holding B.V. Gas supply plate for semiconductor manufacturing apparatus
US10535516B2 (en) 2018-02-01 2020-01-14 Asm Ip Holdings B.V. Method for depositing a semiconductor structure on a surface of a substrate and related semiconductor structures
US11081345B2 (en) 2018-02-06 2021-08-03 Asm Ip Holding B.V. Method of post-deposition treatment for silicon oxide film
US11735414B2 (en) 2018-02-06 2023-08-22 Asm Ip Holding B.V. Method of post-deposition treatment for silicon oxide film
US10896820B2 (en) 2018-02-14 2021-01-19 Asm Ip Holding B.V. Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process
US11387106B2 (en) 2018-02-14 2022-07-12 Asm Ip Holding B.V. Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process
US11685991B2 (en) 2018-02-14 2023-06-27 Asm Ip Holding B.V. Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process
US10731249B2 (en) 2018-02-15 2020-08-04 Asm Ip Holding B.V. Method of forming a transition metal containing film on a substrate by a cyclical deposition process, a method for supplying a transition metal halide compound to a reaction chamber, and related vapor deposition apparatus
US11482418B2 (en) 2018-02-20 2022-10-25 Asm Ip Holding B.V. Substrate processing method and apparatus
US10658181B2 (en) 2018-02-20 2020-05-19 Asm Ip Holding B.V. Method of spacer-defined direct patterning in semiconductor fabrication
US11939673B2 (en) 2018-02-23 2024-03-26 Asm Ip Holding B.V. Apparatus for detecting or monitoring for a chemical precursor in a high temperature environment
US10975470B2 (en) 2018-02-23 2021-04-13 Asm Ip Holding B.V. Apparatus for detecting or monitoring for a chemical precursor in a high temperature environment
US11473195B2 (en) 2018-03-01 2022-10-18 Asm Ip Holding B.V. Semiconductor processing apparatus and a method for processing a substrate
US11629406B2 (en) 2018-03-09 2023-04-18 Asm Ip Holding B.V. Semiconductor processing apparatus comprising one or more pyrometers for measuring a temperature of a substrate during transfer of the substrate
US11114283B2 (en) 2018-03-16 2021-09-07 Asm Ip Holding B.V. Reactor, system including the reactor, and methods of manufacturing and using same
US10847371B2 (en) 2018-03-27 2020-11-24 Asm Ip Holding B.V. Method of forming an electrode on a substrate and a semiconductor device structure including an electrode
US11398382B2 (en) 2018-03-27 2022-07-26 Asm Ip Holding B.V. Method of forming an electrode on a substrate and a semiconductor device structure including an electrode
US10510536B2 (en) 2018-03-29 2019-12-17 Asm Ip Holding B.V. Method of depositing a co-doped polysilicon film on a surface of a substrate within a reaction chamber
US11230766B2 (en) 2018-03-29 2022-01-25 Asm Ip Holding B.V. Substrate processing apparatus and method
US11088002B2 (en) 2018-03-29 2021-08-10 Asm Ip Holding B.V. Substrate rack and a substrate processing system and method
US10867786B2 (en) 2018-03-30 2020-12-15 Asm Ip Holding B.V. Substrate processing method
US11469098B2 (en) 2018-05-08 2022-10-11 Asm Ip Holding B.V. Methods for depositing an oxide film on a substrate by a cyclical deposition process and related device structures
US11056567B2 (en) 2018-05-11 2021-07-06 Asm Ip Holding B.V. Method of forming a doped metal carbide film on a substrate and related semiconductor device structures
US11908733B2 (en) 2018-05-28 2024-02-20 Asm Ip Holding B.V. Substrate processing method and device manufactured by using the same
US11361990B2 (en) 2018-05-28 2022-06-14 Asm Ip Holding B.V. Substrate processing method and device manufactured by using the same
US11837483B2 (en) 2018-06-04 2023-12-05 Asm Ip Holding B.V. Wafer handling chamber with moisture reduction
US11718913B2 (en) 2018-06-04 2023-08-08 Asm Ip Holding B.V. Gas distribution system and reactor system including same
US11270899B2 (en) 2018-06-04 2022-03-08 Asm Ip Holding B.V. Wafer handling chamber with moisture reduction
US11286562B2 (en) 2018-06-08 2022-03-29 Asm Ip Holding B.V. Gas-phase chemical reactor and method of using same
US11530483B2 (en) 2018-06-21 2022-12-20 Asm Ip Holding B.V. Substrate processing system
US10797133B2 (en) 2018-06-21 2020-10-06 Asm Ip Holding B.V. Method for depositing a phosphorus doped silicon arsenide film and related semiconductor device structures
US11296189B2 (en) 2018-06-21 2022-04-05 Asm Ip Holding B.V. Method for depositing a phosphorus doped silicon arsenide film and related semiconductor device structures
US11952658B2 (en) 2018-06-27 2024-04-09 Asm Ip Holding B.V. Cyclic deposition methods for forming metal-containing material and films and structures including the metal-containing material
US11499222B2 (en) 2018-06-27 2022-11-15 Asm Ip Holding B.V. Cyclic deposition methods for forming metal-containing material and films and structures including the metal-containing material
US11492703B2 (en) 2018-06-27 2022-11-08 Asm Ip Holding B.V. Cyclic deposition methods for forming metal-containing material and films and structures including the metal-containing material
US11814715B2 (en) 2018-06-27 2023-11-14 Asm Ip Holding B.V. Cyclic deposition methods for forming metal-containing material and films and structures including the metal-containing material
US10612136B2 (en) 2018-06-29 2020-04-07 ASM IP Holding, B.V. Temperature-controlled flange and reactor system including same
US11168395B2 (en) 2018-06-29 2021-11-09 Asm Ip Holding B.V. Temperature-controlled flange and reactor system including same
US10914004B2 (en) 2018-06-29 2021-02-09 Asm Ip Holding B.V. Thin-film deposition method and manufacturing method of semiconductor device
US11646197B2 (en) 2018-07-03 2023-05-09 Asm Ip Holding B.V. Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition
US10755923B2 (en) 2018-07-03 2020-08-25 Asm Ip Holding B.V. Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition
US11923190B2 (en) 2018-07-03 2024-03-05 Asm Ip Holding B.V. Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition
US10388513B1 (en) 2018-07-03 2019-08-20 Asm Ip Holding B.V. Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition
US10755922B2 (en) 2018-07-03 2020-08-25 Asm Ip Holding B.V. Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition
US10767789B2 (en) 2018-07-16 2020-09-08 Asm Ip Holding B.V. Diaphragm valves, valve components, and methods for forming valve components
US10483099B1 (en) 2018-07-26 2019-11-19 Asm Ip Holding B.V. Method for forming thermally stable organosilicon polymer film
US11053591B2 (en) 2018-08-06 2021-07-06 Asm Ip Holding B.V. Multi-port gas injection system and reactor system including same
US10883175B2 (en) 2018-08-09 2021-01-05 Asm Ip Holding B.V. Vertical furnace for processing substrates and a liner for use therein
US10829852B2 (en) 2018-08-16 2020-11-10 Asm Ip Holding B.V. Gas distribution device for a wafer processing apparatus
US11430674B2 (en) 2018-08-22 2022-08-30 Asm Ip Holding B.V. Sensor array, apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods
US11804388B2 (en) 2018-09-11 2023-10-31 Asm Ip Holding B.V. Substrate processing apparatus and method
US11024523B2 (en) 2018-09-11 2021-06-01 Asm Ip Holding B.V. Substrate processing apparatus and method
US11274369B2 (en) 2018-09-11 2022-03-15 Asm Ip Holding B.V. Thin film deposition method
US11049751B2 (en) 2018-09-14 2021-06-29 Asm Ip Holding B.V. Cassette supply system to store and handle cassettes and processing apparatus equipped therewith
US11885023B2 (en) 2018-10-01 2024-01-30 Asm Ip Holding B.V. Substrate retaining apparatus, system including the apparatus, and method of using same
US11232963B2 (en) 2018-10-03 2022-01-25 Asm Ip Holding B.V. Substrate processing apparatus and method
US11414760B2 (en) 2018-10-08 2022-08-16 Asm Ip Holding B.V. Substrate support unit, thin film deposition apparatus including the same, and substrate processing apparatus including the same
US10847365B2 (en) 2018-10-11 2020-11-24 Asm Ip Holding B.V. Method of forming conformal silicon carbide film by cyclic CVD
US10811256B2 (en) 2018-10-16 2020-10-20 Asm Ip Holding B.V. Method for etching a carbon-containing feature
US11251068B2 (en) 2018-10-19 2022-02-15 Asm Ip Holding B.V. Substrate processing apparatus and substrate processing method
US11664199B2 (en) 2018-10-19 2023-05-30 Asm Ip Holding B.V. Substrate processing apparatus and substrate processing method
USD948463S1 (en) 2018-10-24 2022-04-12 Asm Ip Holding B.V. Susceptor for semiconductor substrate supporting apparatus
US10381219B1 (en) 2018-10-25 2019-08-13 Asm Ip Holding B.V. Methods for forming a silicon nitride film
US11735445B2 (en) 2018-10-31 2023-08-22 Asm Ip Holding B.V. Substrate processing apparatus for processing substrates
US11087997B2 (en) 2018-10-31 2021-08-10 Asm Ip Holding B.V. Substrate processing apparatus for processing substrates
US11499226B2 (en) 2018-11-02 2022-11-15 Asm Ip Holding B.V. Substrate supporting unit and a substrate processing device including the same
US11866823B2 (en) 2018-11-02 2024-01-09 Asm Ip Holding B.V. Substrate supporting unit and a substrate processing device including the same
US11572620B2 (en) 2018-11-06 2023-02-07 Asm Ip Holding B.V. Methods for selectively depositing an amorphous silicon film on a substrate
US11031242B2 (en) 2018-11-07 2021-06-08 Asm Ip Holding B.V. Methods for depositing a boron doped silicon germanium film
US11244825B2 (en) 2018-11-16 2022-02-08 Asm Ip Holding B.V. Methods for depositing a transition metal chalcogenide film on a substrate by a cyclical deposition process
US10847366B2 (en) 2018-11-16 2020-11-24 Asm Ip Holding B.V. Methods for depositing a transition metal chalcogenide film on a substrate by a cyclical deposition process
US11798999B2 (en) 2018-11-16 2023-10-24 Asm Ip Holding B.V. Methods for forming a metal silicate film on a substrate in a reaction chamber and related semiconductor device structures
US10818758B2 (en) 2018-11-16 2020-10-27 Asm Ip Holding B.V. Methods for forming a metal silicate film on a substrate in a reaction chamber and related semiconductor device structures
US11411088B2 (en) 2018-11-16 2022-08-09 Asm Ip Holding B.V. Methods for forming a metal silicate film on a substrate in a reaction chamber and related semiconductor device structures
US10559458B1 (en) 2018-11-26 2020-02-11 Asm Ip Holding B.V. Method of forming oxynitride film
US11217444B2 (en) 2018-11-30 2022-01-04 Asm Ip Holding B.V. Method for forming an ultraviolet radiation responsive metal oxide-containing film
US11488819B2 (en) 2018-12-04 2022-11-01 Asm Ip Holding B.V. Method of cleaning substrate processing apparatus
US11769670B2 (en) 2018-12-13 2023-09-26 Asm Ip Holding B.V. Methods for forming a rhenium-containing film on a substrate by a cyclical deposition process and related semiconductor device structures
US11158513B2 (en) 2018-12-13 2021-10-26 Asm Ip Holding B.V. Methods for forming a rhenium-containing film on a substrate by a cyclical deposition process and related semiconductor device structures
US11658029B2 (en) 2018-12-14 2023-05-23 Asm Ip Holding B.V. Method of forming a device structure using selective deposition of gallium nitride and system for same
US11390946B2 (en) 2019-01-17 2022-07-19 Asm Ip Holding B.V. Methods of forming a transition metal containing film on a substrate by a cyclical deposition process
US11171025B2 (en) 2019-01-22 2021-11-09 Asm Ip Holding B.V. Substrate processing device
US11127589B2 (en) 2019-02-01 2021-09-21 Asm Ip Holding B.V. Method of topology-selective film formation of silicon oxide
US11342216B2 (en) 2019-02-20 2022-05-24 Asm Ip Holding B.V. Cyclical deposition method and apparatus for filling a recess formed within a substrate surface
US11482533B2 (en) 2019-02-20 2022-10-25 Asm Ip Holding B.V. Apparatus and methods for plug fill deposition in 3-D NAND applications
US11251040B2 (en) 2019-02-20 2022-02-15 Asm Ip Holding B.V. Cyclical deposition method including treatment step and apparatus for same
US11227789B2 (en) 2019-02-20 2022-01-18 Asm Ip Holding B.V. Method and apparatus for filling a recess formed within a substrate surface
US11615980B2 (en) 2019-02-20 2023-03-28 Asm Ip Holding B.V. Method and apparatus for filling a recess formed within a substrate surface
US11798834B2 (en) 2019-02-20 2023-10-24 Asm Ip Holding B.V. Cyclical deposition method and apparatus for filling a recess formed within a substrate surface
US11629407B2 (en) 2019-02-22 2023-04-18 Asm Ip Holding B.V. Substrate processing apparatus and method for processing substrates
US11901175B2 (en) 2019-03-08 2024-02-13 Asm Ip Holding B.V. Method for selective deposition of silicon nitride layer and structure including selectively-deposited silicon nitride layer
US11424119B2 (en) 2019-03-08 2022-08-23 Asm Ip Holding B.V. Method for selective deposition of silicon nitride layer and structure including selectively-deposited silicon nitride layer
US11114294B2 (en) 2019-03-08 2021-09-07 Asm Ip Holding B.V. Structure including SiOC layer and method of forming same
US11742198B2 (en) 2019-03-08 2023-08-29 Asm Ip Holding B.V. Structure including SiOCN layer and method of forming same
US11378337B2 (en) 2019-03-28 2022-07-05 Asm Ip Holding B.V. Door opener and substrate processing apparatus provided therewith
US11551925B2 (en) 2019-04-01 2023-01-10 Asm Ip Holding B.V. Method for manufacturing a semiconductor device
US11447864B2 (en) 2019-04-19 2022-09-20 Asm Ip Holding B.V. Layer forming method and apparatus
US11814747B2 (en) 2019-04-24 2023-11-14 Asm Ip Holding B.V. Gas-phase reactor system-with a reaction chamber, a solid precursor source vessel, a gas distribution system, and a flange assembly
US11781221B2 (en) 2019-05-07 2023-10-10 Asm Ip Holding B.V. Chemical source vessel with dip tube
US11289326B2 (en) 2019-05-07 2022-03-29 Asm Ip Holding B.V. Method for reforming amorphous carbon polymer film
US11355338B2 (en) 2019-05-10 2022-06-07 Asm Ip Holding B.V. Method of depositing material onto a surface and structure formed according to the method
US11515188B2 (en) 2019-05-16 2022-11-29 Asm Ip Holding B.V. Wafer boat handling device, vertical batch furnace and method
USD975665S1 (en) 2019-05-17 2023-01-17 Asm Ip Holding B.V. Susceptor shaft
USD947913S1 (en) 2019-05-17 2022-04-05 Asm Ip Holding B.V. Susceptor shaft
USD935572S1 (en) 2019-05-24 2021-11-09 Asm Ip Holding B.V. Gas channel plate
USD922229S1 (en) 2019-06-05 2021-06-15 Asm Ip Holding B.V. Device for controlling a temperature of a gas supply unit
US11345999B2 (en) 2019-06-06 2022-05-31 Asm Ip Holding B.V. Method of using a gas-phase reactor system including analyzing exhausted gas
US11453946B2 (en) 2019-06-06 2022-09-27 Asm Ip Holding B.V. Gas-phase reactor system including a gas detector
US11908684B2 (en) 2019-06-11 2024-02-20 Asm Ip Holding B.V. Method of forming an electronic structure using reforming gas, system for performing the method, and structure formed using the method
US11476109B2 (en) 2019-06-11 2022-10-18 Asm Ip Holding B.V. Method of forming an electronic structure using reforming gas, system for performing the method, and structure formed using the method
USD944946S1 (en) 2019-06-14 2022-03-01 Asm Ip Holding B.V. Shower plate
USD931978S1 (en) 2019-06-27 2021-09-28 Asm Ip Holding B.V. Showerhead vacuum transport
US11746414B2 (en) 2019-07-03 2023-09-05 Asm Ip Holding B.V. Temperature control assembly for substrate processing apparatus and method of using same
US11390945B2 (en) 2019-07-03 2022-07-19 Asm Ip Holding B.V. Temperature control assembly for substrate processing apparatus and method of using same
US11605528B2 (en) 2019-07-09 2023-03-14 Asm Ip Holding B.V. Plasma device using coaxial waveguide, and substrate treatment method
US11664267B2 (en) 2019-07-10 2023-05-30 Asm Ip Holding B.V. Substrate support assembly and substrate processing device including the same
US11664245B2 (en) 2019-07-16 2023-05-30 Asm Ip Holding B.V. Substrate processing device
US11615970B2 (en) 2019-07-17 2023-03-28 Asm Ip Holding B.V. Radical assist ignition plasma system and method
US11688603B2 (en) 2019-07-17 2023-06-27 Asm Ip Holding B.V. Methods of forming silicon germanium structures
US11643724B2 (en) 2019-07-18 2023-05-09 Asm Ip Holding B.V. Method of forming structures using a neutral beam
US11282698B2 (en) 2019-07-19 2022-03-22 Asm Ip Holding B.V. Method of forming topology-controlled amorphous carbon polymer film
US11557474B2 (en) 2019-07-29 2023-01-17 Asm Ip Holding B.V. Methods for selective deposition utilizing n-type dopants and/or alternative dopants to achieve high dopant incorporation
US11443926B2 (en) 2019-07-30 2022-09-13 Asm Ip Holding B.V. Substrate processing apparatus
US11430640B2 (en) 2019-07-30 2022-08-30 Asm Ip Holding B.V. Substrate processing apparatus
US11876008B2 (en) 2019-07-31 2024-01-16 Asm Ip Holding B.V. Vertical batch furnace assembly
US11227782B2 (en) 2019-07-31 2022-01-18 Asm Ip Holding B.V. Vertical batch furnace assembly
US11587814B2 (en) 2019-07-31 2023-02-21 Asm Ip Holding B.V. Vertical batch furnace assembly
US11587815B2 (en) 2019-07-31 2023-02-21 Asm Ip Holding B.V. Vertical batch furnace assembly
US11680839B2 (en) 2019-08-05 2023-06-20 Asm Ip Holding B.V. Liquid level sensor for a chemical source vessel
USD965044S1 (en) 2019-08-19 2022-09-27 Asm Ip Holding B.V. Susceptor shaft
USD965524S1 (en) 2019-08-19 2022-10-04 Asm Ip Holding B.V. Susceptor support
US11639548B2 (en) 2019-08-21 2023-05-02 Asm Ip Holding B.V. Film-forming material mixed-gas forming device and film forming device
USD940837S1 (en) 2019-08-22 2022-01-11 Asm Ip Holding B.V. Electrode
USD949319S1 (en) 2019-08-22 2022-04-19 Asm Ip Holding B.V. Exhaust duct
USD930782S1 (en) 2019-08-22 2021-09-14 Asm Ip Holding B.V. Gas distributor
USD979506S1 (en) 2019-08-22 2023-02-28 Asm Ip Holding B.V. Insulator
US11594450B2 (en) 2019-08-22 2023-02-28 Asm Ip Holding B.V. Method for forming a structure with a hole
US11827978B2 (en) 2019-08-23 2023-11-28 Asm Ip Holding B.V. Methods for depositing a molybdenum nitride film on a surface of a substrate by a cyclical deposition process and related semiconductor device structures including a molybdenum nitride film
US11898242B2 (en) 2019-08-23 2024-02-13 Asm Ip Holding B.V. Methods for forming a polycrystalline molybdenum film over a surface of a substrate and related structures including a polycrystalline molybdenum film
US11527400B2 (en) 2019-08-23 2022-12-13 Asm Ip Holding B.V. Method for depositing silicon oxide film having improved quality by peald using bis(diethylamino)silane
US11286558B2 (en) 2019-08-23 2022-03-29 Asm Ip Holding B.V. Methods for depositing a molybdenum nitride film on a surface of a substrate by a cyclical deposition process and related semiconductor device structures including a molybdenum nitride film
US11495459B2 (en) 2019-09-04 2022-11-08 Asm Ip Holding B.V. Methods for selective deposition using a sacrificial capping layer
US11823876B2 (en) 2019-09-05 2023-11-21 Asm Ip Holding B.V. Substrate processing apparatus
US11562901B2 (en) 2019-09-25 2023-01-24 Asm Ip Holding B.V. Substrate processing method
US11610774B2 (en) 2019-10-02 2023-03-21 Asm Ip Holding B.V. Methods for forming a topographically selective silicon oxide film by a cyclical plasma-enhanced deposition process
US11339476B2 (en) 2019-10-08 2022-05-24 Asm Ip Holding B.V. Substrate processing device having connection plates, substrate processing method
US11735422B2 (en) 2019-10-10 2023-08-22 Asm Ip Holding B.V. Method of forming a photoresist underlayer and structure including same
US11637011B2 (en) 2019-10-16 2023-04-25 Asm Ip Holding B.V. Method of topology-selective film formation of silicon oxide
US11637014B2 (en) 2019-10-17 2023-04-25 Asm Ip Holding B.V. Methods for selective deposition of doped semiconductor material
US11315794B2 (en) 2019-10-21 2022-04-26 Asm Ip Holding B.V. Apparatus and methods for selectively etching films
US11646205B2 (en) 2019-10-29 2023-05-09 Asm Ip Holding B.V. Methods of selectively forming n-type doped material on a surface, systems for selectively forming n-type doped material, and structures formed using same
US11594600B2 (en) 2019-11-05 2023-02-28 Asm Ip Holding B.V. Structures with doped semiconductor layers and methods and systems for forming same
US11501968B2 (en) 2019-11-15 2022-11-15 Asm Ip Holding B.V. Method for providing a semiconductor device with silicon filled gaps
US11626316B2 (en) 2019-11-20 2023-04-11 Asm Ip Holding B.V. Method of depositing carbon-containing material on a surface of a substrate, structure formed using the method, and system for forming the structure
US11915929B2 (en) 2019-11-26 2024-02-27 Asm Ip Holding B.V. Methods for selectively forming a target film on a substrate comprising a first dielectric surface and a second metallic surface
US11401605B2 (en) 2019-11-26 2022-08-02 Asm Ip Holding B.V. Substrate processing apparatus
US11923181B2 (en) 2019-11-29 2024-03-05 Asm Ip Holding B.V. Substrate processing apparatus for minimizing the effect of a filling gas during substrate processing
US11646184B2 (en) 2019-11-29 2023-05-09 Asm Ip Holding B.V. Substrate processing apparatus
US11929251B2 (en) 2019-12-02 2024-03-12 Asm Ip Holding B.V. Substrate processing apparatus having electrostatic chuck and substrate processing method
US11840761B2 (en) 2019-12-04 2023-12-12 Asm Ip Holding B.V. Substrate processing apparatus
US11885013B2 (en) 2019-12-17 2024-01-30 Asm Ip Holding B.V. Method of forming vanadium nitride layer and structure including the vanadium nitride layer
US11527403B2 (en) 2019-12-19 2022-12-13 Asm Ip Holding B.V. Methods for filling a gap feature on a substrate surface and related semiconductor structures
US11551912B2 (en) 2020-01-20 2023-01-10 Asm Ip Holding B.V. Method of forming thin film and method of modifying surface of thin film
US11521851B2 (en) 2020-02-03 2022-12-06 Asm Ip Holding B.V. Method of forming structures including a vanadium or indium layer
US11828707B2 (en) 2020-02-04 2023-11-28 Asm Ip Holding B.V. Method and apparatus for transmittance measurements of large articles
US11776846B2 (en) 2020-02-07 2023-10-03 Asm Ip Holding B.V. Methods for depositing gap filling fluids and related systems and devices
US11781243B2 (en) 2020-02-17 2023-10-10 Asm Ip Holding B.V. Method for depositing low temperature phosphorous-doped silicon
US11837494B2 (en) 2020-03-11 2023-12-05 Asm Ip Holding B.V. Substrate handling device with adjustable joints
US11488854B2 (en) 2020-03-11 2022-11-01 Asm Ip Holding B.V. Substrate handling device with adjustable joints
US11876356B2 (en) 2020-03-11 2024-01-16 Asm Ip Holding B.V. Lockout tagout assembly and system and method of using same
US11823866B2 (en) 2020-04-02 2023-11-21 Asm Ip Holding B.V. Thin film forming method
US11830738B2 (en) 2020-04-03 2023-11-28 Asm Ip Holding B.V. Method for forming barrier layer and method for manufacturing semiconductor device
US11437241B2 (en) 2020-04-08 2022-09-06 Asm Ip Holding B.V. Apparatus and methods for selectively etching silicon oxide films
US11821078B2 (en) 2020-04-15 2023-11-21 Asm Ip Holding B.V. Method for forming precoat film and method for forming silicon-containing film
US11530876B2 (en) 2020-04-24 2022-12-20 Asm Ip Holding B.V. Vertical batch furnace assembly comprising a cooling gas supply
US11898243B2 (en) 2020-04-24 2024-02-13 Asm Ip Holding B.V. Method of forming vanadium nitride-containing layer
US11887857B2 (en) 2020-04-24 2024-01-30 Asm Ip Holding B.V. Methods and systems for depositing a layer comprising vanadium, nitrogen, and a further element
US11515187B2 (en) 2020-05-01 2022-11-29 Asm Ip Holding B.V. Fast FOUP swapping with a FOUP handler
US11798830B2 (en) 2020-05-01 2023-10-24 Asm Ip Holding B.V. Fast FOUP swapping with a FOUP handler
US11626308B2 (en) 2020-05-13 2023-04-11 Asm Ip Holding B.V. Laser alignment fixture for a reactor system
US11804364B2 (en) 2020-05-19 2023-10-31 Asm Ip Holding B.V. Substrate processing apparatus
US11705333B2 (en) 2020-05-21 2023-07-18 Asm Ip Holding B.V. Structures including multiple carbon layers and methods of forming and using same
US11767589B2 (en) 2020-05-29 2023-09-26 Asm Ip Holding B.V. Substrate processing device
US11646204B2 (en) 2020-06-24 2023-05-09 Asm Ip Holding B.V. Method for forming a layer provided with silicon
US11658035B2 (en) 2020-06-30 2023-05-23 Asm Ip Holding B.V. Substrate processing method
US11644758B2 (en) 2020-07-17 2023-05-09 Asm Ip Holding B.V. Structures and methods for use in photolithography
US11674220B2 (en) 2020-07-20 2023-06-13 Asm Ip Holding B.V. Method for depositing molybdenum layers using an underlayer
US11725280B2 (en) 2020-08-26 2023-08-15 Asm Ip Holding B.V. Method for forming metal silicon oxide and metal silicon oxynitride layers
USD990534S1 (en) 2020-09-11 2023-06-27 Asm Ip Holding B.V. Weighted lift pin
USD1012873S1 (en) 2020-09-24 2024-01-30 Asm Ip Holding B.V. Electrode for semiconductor processing apparatus
US11827981B2 (en) 2020-10-14 2023-11-28 Asm Ip Holding B.V. Method of depositing material on stepped structure
US11873557B2 (en) 2020-10-22 2024-01-16 Asm Ip Holding B.V. Method of depositing vanadium metal
US11901179B2 (en) 2020-10-28 2024-02-13 Asm Ip Holding B.V. Method and device for depositing silicon onto substrates
US11891696B2 (en) 2020-11-30 2024-02-06 Asm Ip Holding B.V. Injector configured for arrangement within a reaction chamber of a substrate processing apparatus
US11946137B2 (en) 2020-12-16 2024-04-02 Asm Ip Holding B.V. Runout and wobble measurement fixtures
US11885020B2 (en) 2020-12-22 2024-01-30 Asm Ip Holding B.V. Transition metal deposition method
US11961741B2 (en) 2021-03-04 2024-04-16 Asm Ip Holding B.V. Method for fabricating layer structure having target topological profile
US11959168B2 (en) 2021-04-26 2024-04-16 Asm Ip Holding B.V. Solid source precursor vessel
USD980814S1 (en) 2021-05-11 2023-03-14 Asm Ip Holding B.V. Gas distributor for substrate processing apparatus
USD981973S1 (en) 2021-05-11 2023-03-28 Asm Ip Holding B.V. Reactor wall for substrate processing apparatus
USD980813S1 (en) 2021-05-11 2023-03-14 Asm Ip Holding B.V. Gas flow control plate for substrate processing apparatus
USD990441S1 (en) 2021-09-07 2023-06-27 Asm Ip Holding B.V. Gas flow control plate
US11959171B2 (en) 2022-07-18 2024-04-16 Asm Ip Holding B.V. Methods of forming a transition metal containing film on a substrate by a cyclical deposition process

Also Published As

Publication number Publication date
KR20040035393A (en) 2004-04-29
KR100460841B1 (en) 2004-12-09
US6723642B1 (en) 2004-04-20

Similar Documents

Publication Publication Date Title
US6723642B1 (en) Method for forming nitrogen-containing oxide thin film using plasma enhanced atomic layer deposition
US6806145B2 (en) Low temperature method of forming a gate stack with a high k layer deposited over an interfacial oxide layer
US6989573B2 (en) Lanthanide oxide/zirconium oxide atomic layer deposited nanolaminate gate dielectrics
KR100550641B1 (en) Dielectric layer alloyed hafnium oxide and aluminium oxide and method for fabricating the same
US8154066B2 (en) Titanium aluminum oxide films
EP1292970B1 (en) Thin film forming method
US7396719B2 (en) Method of forming high dielectric film using atomic layer deposition and method of manufacturing capacitor having the high dielectric film
US7312494B2 (en) Lanthanide oxide / hafnium oxide dielectric layers
US7851285B2 (en) Non-volatile memory device and method for fabricating the same
US7851307B2 (en) Method of forming complex oxide nanodots for a charge trap
TWI488290B (en) Semiconductor device including carbon-containing electrode and method for fabricating the same
KR20050028980A (en) Inorganic thin film electroluminescent device and method for manufacturing the same
US8372746B2 (en) Electrode of semiconductor device and method for fabricating capacitor
KR20080029716A (en) Flash memory device and manufacturing method thereof
KR100996884B1 (en) Semiconductor device empolying an oxide layer prepared by ecr-ald, preparation method thereof and the uses therof
US20230197796A1 (en) Formation of gate stacks comprising a threshold voltage tuning layer
KR100920402B1 (en) Low Temperature Gate Stack
KR20070094154A (en) Method of manufacturing a flash memory device
KR100841679B1 (en) Method of preparing passivation layer in organic device
Ahn et al. Lanthanide doped TiO x films
EP1425785A2 (en) Method of fabricating a gate stack at low temperature

Legal Events

Date Code Title Description
AS Assignment

Owner name: ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTIT

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:LIM, JUNG-WOOK;YUN, SUN-JIN;REEL/FRAME:013841/0134

Effective date: 20030116

FEPP Fee payment procedure

Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: SMALL ENTITY

FPAY Fee payment

Year of fee payment: 4

FEPP Fee payment procedure

Free format text: PAYER NUMBER DE-ASSIGNED (ORIGINAL EVENT CODE: RMPN); ENTITY STATUS OF PATENT OWNER: SMALL ENTITY

Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: SMALL ENTITY

REMI Maintenance fee reminder mailed
LAPS Lapse for failure to pay maintenance fees
STCH Information on status: patent discontinuation

Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362

FP Lapsed due to failure to pay maintenance fee

Effective date: 20120420