US20010012650A1 - Method of manufacturing thin film transistor - Google Patents
Method of manufacturing thin film transistor Download PDFInfo
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- US20010012650A1 US20010012650A1 US09/736,308 US73630800A US2001012650A1 US 20010012650 A1 US20010012650 A1 US 20010012650A1 US 73630800 A US73630800 A US 73630800A US 2001012650 A1 US2001012650 A1 US 2001012650A1
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- 239000010409 thin film Substances 0.000 title claims abstract description 31
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 46
- 229910021417 amorphous silicon Inorganic materials 0.000 claims abstract description 31
- 239000010408 film Substances 0.000 claims abstract description 28
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 14
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000758 substrate Substances 0.000 claims abstract description 14
- 229910004205 SiNX Inorganic materials 0.000 claims abstract description 5
- 239000007789 gas Substances 0.000 claims description 39
- 239000001257 hydrogen Substances 0.000 claims description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 14
- 238000009832 plasma treatment Methods 0.000 claims description 5
- 230000007547 defect Effects 0.000 description 10
- 239000004973 liquid crystal related substance Substances 0.000 description 9
- 238000005137 deposition process Methods 0.000 description 8
- 238000000151 deposition Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 238000000427 thin-film deposition Methods 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66742—Thin film unipolar transistors
- H01L29/6675—Amorphous silicon or polysilicon transistors
- H01L29/66765—Lateral single gate single channel transistors with inverted structure, i.e. the channel layer is formed after the gate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
- H01L29/78651—Silicon transistors
- H01L29/7866—Non-monocrystalline silicon transistors
- H01L29/78663—Amorphous silicon transistors
- H01L29/78669—Amorphous silicon transistors with inverted-type structure, e.g. with bottom gate
Definitions
- the present invention relates to a method of manufacturing a thin film transistor, and more particularly, to a method of manufacturing a thin film transistor for use in a liquid crystal display (LCD) device.
- LCD liquid crystal display
- LCD liquid crystal display
- TFTs thin film transistors
- pixel electrodes arranged in the form of a matrix
- FIG. 1 is a cross-sectional view illustrating a liquid crystal panel of a typical active matrix LCD device.
- the liquid crystal panel 20 includes lower and upper substrates 2 and 4 with a liquid crystal layer 10 interposed therebetween.
- the lower substrate 2 referred to as an array substrate, is divided into two regions: a region S; and a region P.
- TFTs are arranged on the region S as a switching element, and pixel electrodes 14 are arranged on the pixel region P.
- the upper substrate 4 includes a color filter 8 and a common electrode 12 . Through the pixel electrode 14 and the common electrode 12 , voltages are applied to the liquid crystal layer 10 .
- edge portions of the two substrate 2 and 4 are sealed by a sealant 6 .
- the TFT receives signals from external drive integrated circuit (IC) to drive the pixel electrode 14 .
- IC external drive integrated circuit
- An inverted staggered type TFT is used for a general LCD device because its simple structure and a high performance.
- the inverted staggered type TFT is divided into a back channel etch type and an etch stopper type.
- the back channel etch type TFT is explained.
- FIG. 2 is a cross-section view illustrating the typical back channel etch type TFT.
- a gate electrode 30 is formed on a substrate 1 .
- a gate insulating layer 32 is formed over the whole surface of the substrate 1 while covering the gate electrode 30 .
- An active layer 34 and an ohmic contact layer 36 are sequentially formed on the gate insulating layer 32 .
- Source and drain electrodes 38 and 40 overlap both end portions of the ohmic contact layer 36 .
- the gate electrode 30 is made of a low resistive material such as aluminum in order to reduce a RC delay.
- the gate insulating layer 34 is deposited at a low temperature of less than 350 and is made of SiNx or SiO 2 .
- the active layer 34 is made of an hydrogenated amorphous silicon (a-Si:H).
- the ohmic contact layer 36 is formed in such a way that a gas containing a boron (B) of a boron group or a phosphorous (P) of a nitrogen group is ion-doped into the amorphous silicon layer.
- the ohmic contact layer 36 is generally is made of n + -type hydrogenated amorphous silicon (n + a-Si:H) doped with PH 3 containing a phosphorous (P).
- the source and drain electrodes 42 and 44 are made of Cr or Mo.
- a deposition process is repeated several times, for example, using a plasma-enhanced chemical vapor deposition (PECVD) technique.
- PECVD plasma-enhanced chemical vapor deposition
- FIG. 3 is a graph illustrating a relationship between a power and each of the layers when the gate insulating layer 32 , the active layer 34 and the ohmic contact layer 36 are deposited.
- a mixed gas of NH 3 , N 2 and SiH 4 is injected into the process chamber and is decomposed by plasma, so that a silicon nitride film (SiNx) is formed on the substrate.
- NH 3 and N 2 that are used to deposit the gate insulating layer 32 are pumped, and H 2 are added.
- the pure amorphous silicon (a-Si:H) is formed using SiH 4 and H 2 .
- a small amount of PH 3 is added to the mixed gas of SiH 4 and H 2 to form an n + type amorphous silicon layer (a-Si:H).
- the active layer 34 generally contains a hydrogen (H). Electrical characteristics of the amorphous silicon TFTs depend on a density of state (DOS). The silicon atoms of the active layer 34 have 4 outmost electrons, among them uncombined electrons cause a dangling bond problem. The dangling bond problem can be solved by the hydrogen.
- H hydrogen
- DOS density of state
- plasma condition should be released first. After a predetermined time passes, the mixed gas in the process chamber is pumped.
- FIG. 4 is a graph illustrating a relationship between an internal pressure variation of the process chamber and each of the layers when the gate insulating layer 32 , the active layer 34 and the ohmic contact layer 36 are deposited.
- the active layer when the active layer is formed, a predetermined time is required to maintain an initial plasma state. At this time, the active layer deposited has defects such as a dangling bond. As a result, an interface between the insulating layer and the active layer becomes inferior, and therefore current-voltage characteristics of the TFT are lowered.
- an interface (see a portion “A” of FIG. 2) between the gate insulating layer and the active layer may have defects due to a lattice mismatch because of the difference of the atoms of the insulating layer and the active layer when the thin films are formed, thereby lowering electrical characteristics of the TFT.
- a threshold voltage of the TFT may increase, and a switching operation may become impossible, and there may come the problem in stability. For example, charges are accumulated on the interface between the gate insulating layer 32 and the active layer 34 , lowering an ON current.
- preferred embodiments of the present invention provide a method of manufacturing a thin film transistor minimizing defects generated when thin films of the thin film transistor are formed.
- the preferred embodiments of the present invention provide a method of manufacturing a thin film transistor, including: preparing a process chamber having a stage; providing a substrate on the stage of the process chamber; injecting a first mixed gas of NH 3 , N 2 and SiH 4 into the process chamber; forming a silicon nitride film (SiNx) on the substrate with the first mixed gas by creating a plasma state in the process chamber; injecting a second mixed gas of H 2 and SiH 4 into the process chamber while removing the first mixed gas in the plasma state; forming a pure amorphous silicon film (a-Si:H) on the silicon nitride film using the second mixed gas in the plasma state; injecting a third mixed gas of H 2 , SiH 4 and PH 3 into the process chamber while removing the second mixed gas in the plasma state; and forming a doped amorphous silicon film (n + a-Si:H) on the silicon nitride film using the
- the method further includes forming a gate electrode before the step of forming the silicon nitride film; and forming source and drain electrodes on the doped amorphous silicon film.
- the method further includes performing a hydrogen plasma treatment on a surface of the silicon nitride film before the step of forming the pure amorphous silicon film.
- the method further includes performing a hydrogen plasma treatment on a surface of the pure amorphous silicon film before the step of forming the doped amorphous silicon film.
- the method of manufacturing the TFT according to the preferred embodiment of the present invention has the following advantages. Firstly, since each of the thin films is deposited in the plasma state, variation of an internal atmosphere of the process chamber is minimized, whereupon a processing time becomes shorten. Secondly, since the thin films deposited are hydrogen plasma-treated, the hydrogen plasma etches detects on the interface between the thin films, whereupon defects can be prevented. Thirdly, since each of the thin films is deposited under the same pressure, an occurrence of a polymer in the process chamber can be prevented, and interface characteristics of the thin films can be improved.
- FIG. 1 is a cross-sectional view illustrating a liquid crystal panel of a conventional active matrix liquid crystal display device
- FIG. 2 is a cross-sectional view illustrating a conventional back channel etch type thin film transistor
- FIG. 3 is a graph illustrating a relationship between a RF-power and thin film depositions
- FIG. 4 is a graph illustrating a relationship between an internal pressure variation of a process chamber and thin film depositions
- FIG. 5 is a graph illustrating a relationship between a RF-power and a thin film deposition according to a preferred embodiment of the present invention.
- FIG. 6 is a graph illustrating a variation of an internal pressure of the process chamber during deposition processes of the thin films.
- FIG. 5 is a graph illustrating a relationship between a RF-power and thin film depositions according to a preferred embodiment of the present invention. As shown in FIG. 5, except for a process of injecting a first mixed gas of NH 3 , N 2 and SiH 4 into the process chamber in order to deposit a gate insulating layer, the power maintains ON state through the whole deposition processes.
- the first mixed gas stabilized under a predetermined pressure is maintained in a first plasma state “A 0 ” by a predetermined RF power intensity, and then the gate insulating layer is deposited.
- a deposition temperature of the thin films is one of the most important parameters to control a surface reaction of a semiconductor layer during a deposition process. In other words, since precursors actively react on hydrogen at a temperature of about 300° C. and also the number of the silicon dangling bond is decreased at that temperature, to control a deposition temperature is very important.
- the first mixed gas is removed while the plasma state is maintained (i.e., without OFF of a power).
- a H 2 gas is injected into the process chamber. That is, in a second plasma state “A 1 ”, a remove of the first mixed gas (NH 3 +N 2 +SiH 4 ) and an injection of the H 2 gas are simultaneously carried out.
- the pressure may vary in a range of less than 200 mTorr.
- a hydrogen (H 2 ) plasma treatment is performed by adjusting radio frequency energy within the chamber during a predetermined time period.
- the hydrogen plasma terminates the dangling bond that may occur on a surface of the gate insulating layer.
- the hydrogen plasma functions to etch defects that exist on the surface of the gate insulating layer.
- a SiH 4 gas is injected into the process chamber to create a second mixed gas, so that an active layer is formed using the second mixed gas (H 2 +SiH 4 ).
- the SiH 4 gas is removed from the second mixed gas, and the active layer is hydrogen plasma-treated in the third plasma state “A 2 ”.
- the SiH 4 gas and a PH 3 gas are added to the H 2 gas to create a third mixed gas (SiH 4 +PH 3 +H 2 ), and an ohmic contact layer (n + a-Si:H) is formed on the active layer using the third mixed gas.
- a method of forming the thin films according to the preferred embodiment of the present invention does not turn off a power while depositing the gate insulating layer, the active layer and the ohmic contact layer, whereby defects due to a lattice mismatch can be prevented.
- defects on the interface of each of the thin films are decreased, charges that are trapped due to defects are decreased, and therefore trapped charges do not prevent a flow of the charges. This leads to high electrical characteristics of the TFT.
- FIG. 6 is a graph illustrating a variation of an internal pressure of the process chamber during a deposition process of the thin films. As shown in FIG. 6, there is little variation of the internal pressure during a deposition process of the thin films (the gate insulating layer, the active layer and the ohmic contact layer). Therefore, defects that may occur on a surface of the thin films due to a variation of the internal pressure can be prevented.
- a method of forming other components such as a gate electrode, a source electrode and a drain electrode shown in FIG. 2 is same as the conventional art and thus its explanation is omitted.
- the method of manufacturing the TFT according to the preferred embodiment of the present invention has the following advantages. Firstly, since each of the thin films is deposited in the plasma state, variation of an internal atmosphere of the process chamber is minimized, whereupon a processing time becomes shorten. Secondly, since the thin films deposited are hydrogen plasma-treated, the hydrogen plasma etches detects on the interface between the thin films, whereupon defects can be prevented. Thirdly, since each of the thin films is deposited under the same or similar pressure, an occurrence of a polymer in the process chamber can be prevented, and interface characteristics of the thin films can be improved.
Abstract
Description
- This application claims the benefit of Korean Patent Application No. 1999-67845, filed on Dec. 31, 2000, under 35 U.S.C. § 119, the entirety of which is hereby incorporated by reference.
- 1. Field of the Invention
- The present invention relates to a method of manufacturing a thin film transistor, and more particularly, to a method of manufacturing a thin film transistor for use in a liquid crystal display (LCD) device.
- 2. Description of Related Art
- Liquid crystal display (LCD) devices are in wide use as display devices capable of being reduced in weight, size and thickness. Of these, active matrix LCD devices, where thin film transistors (TFTs) and pixel electrodes are arranged in the form of a matrix, have been widely used due to a high resolution and an excellent performance of implementing moving images.
- FIG. 1 is a cross-sectional view illustrating a liquid crystal panel of a typical active matrix LCD device. As shown in FIG. 1, the
liquid crystal panel 20 includes lower andupper substrates liquid crystal layer 10 interposed therebetween. Thelower substrate 2, referred to as an array substrate, is divided into two regions: a region S; and a region P. TFTs are arranged on the region S as a switching element, andpixel electrodes 14 are arranged on the pixel region P. Theupper substrate 4 includes acolor filter 8 and acommon electrode 12. Through thepixel electrode 14 and thecommon electrode 12, voltages are applied to theliquid crystal layer 10. In order to prevent a leakage of the liquid crystal, edge portions of the twosubstrate sealant 6. The TFT receives signals from external drive integrated circuit (IC) to drive thepixel electrode 14. - An inverted staggered type TFT is used for a general LCD device because its simple structure and a high performance. The inverted staggered type TFT is divided into a back channel etch type and an etch stopper type. Hereinafter, the back channel etch type TFT is explained.
- FIG. 2 is a cross-section view illustrating the typical back channel etch type TFT. As shown in FIG. 2, a
gate electrode 30 is formed on asubstrate 1. Agate insulating layer 32 is formed over the whole surface of thesubstrate 1 while covering thegate electrode 30. Anactive layer 34 and anohmic contact layer 36 are sequentially formed on thegate insulating layer 32. Source anddrain electrodes ohmic contact layer 36. - The
gate electrode 30 is made of a low resistive material such as aluminum in order to reduce a RC delay. Thegate insulating layer 34 is deposited at a low temperature of less than 350 and is made of SiNx or SiO2. Theactive layer 34 is made of an hydrogenated amorphous silicon (a-Si:H). Theohmic contact layer 36 is formed in such a way that a gas containing a boron (B) of a boron group or a phosphorous (P) of a nitrogen group is ion-doped into the amorphous silicon layer. Theohmic contact layer 36 is generally is made of n+-type hydrogenated amorphous silicon (n+ a-Si:H) doped with PH3 containing a phosphorous (P). The source and drain electrodes 42 and 44 are made of Cr or Mo. - In order to form the TFT, a deposition process is repeated several times, for example, using a plasma-enhanced chemical vapor deposition (PECVD) technique. The
gate insulating layer 32, theactive layer 34 and theohmic contact layer 36 undergo a deposition process in the same process chamber. - FIG. 3 is a graph illustrating a relationship between a power and each of the layers when the
gate insulating layer 32, theactive layer 34 and theohmic contact layer 36 are deposited. - In order to form the
gate insulating layer 32, a mixed gas of NH3, N2 and SiH4 is injected into the process chamber and is decomposed by plasma, so that a silicon nitride film (SiNx) is formed on the substrate. - In order to form the
active layer 34, NH3 and N2 that are used to deposit thegate insulating layer 32 are pumped, and H2 are added. The pure amorphous silicon (a-Si:H) is formed using SiH4 and H2. - Then, in order to form the
ohmic contact layer 36, a small amount of PH3 is added to the mixed gas of SiH4 and H2 to form an n+ type amorphous silicon layer (a-Si:H). - The
active layer 34 generally contains a hydrogen (H). Electrical characteristics of the amorphous silicon TFTs depend on a density of state (DOS). The silicon atoms of theactive layer 34 have 4 outmost electrons, among them uncombined electrons cause a dangling bond problem. The dangling bond problem can be solved by the hydrogen. - As described above, in order to remove the mixed gases used to deposit the gate insulating layer, the active layer and the ohmic contact layer, plasma condition should be released first. After a predetermined time passes, the mixed gas in the process chamber is pumped.
- FIG. 4 is a graph illustrating a relationship between an internal pressure variation of the process chamber and each of the layers when the
gate insulating layer 32, theactive layer 34 and theohmic contact layer 36 are deposited. After a deposition of thegate insulating layer 32, if the mixed gas is removed in the state that the plasma condition is released, an internal pressure of the process chamber varies suddenly. When the internal pressure of the process chamber varies, the polymer generated during the deposition process may fall onto a surface of the gate insulating layer, leading to inferiority in subsequent process. - Further, when the active layer is formed, a predetermined time is required to maintain an initial plasma state. At this time, the active layer deposited has defects such as a dangling bond. As a result, an interface between the insulating layer and the active layer becomes inferior, and therefore current-voltage characteristics of the TFT are lowered.
- Furthermore, an interface (see a portion “A” of FIG. 2) between the gate insulating layer and the active layer may have defects due to a lattice mismatch because of the difference of the atoms of the insulating layer and the active layer when the thin films are formed, thereby lowering electrical characteristics of the TFT. In other words, a threshold voltage of the TFT may increase, and a switching operation may become impossible, and there may come the problem in stability. For example, charges are accumulated on the interface between the
gate insulating layer 32 and theactive layer 34, lowering an ON current. - To overcome the problems described above, preferred embodiments of the present invention provide a method of manufacturing a thin film transistor minimizing defects generated when thin films of the thin film transistor are formed.
- It is another object of the invention to provide a method of forming thin films for the thin film transistor, which can lower the manufacturing time.
- In order to achieve the above object, the preferred embodiments of the present invention provide a method of manufacturing a thin film transistor, including: preparing a process chamber having a stage; providing a substrate on the stage of the process chamber; injecting a first mixed gas of NH3, N2 and SiH4 into the process chamber; forming a silicon nitride film (SiNx) on the substrate with the first mixed gas by creating a plasma state in the process chamber; injecting a second mixed gas of H2 and SiH4 into the process chamber while removing the first mixed gas in the plasma state; forming a pure amorphous silicon film (a-Si:H) on the silicon nitride film using the second mixed gas in the plasma state; injecting a third mixed gas of H2, SiH4 and PH3 into the process chamber while removing the second mixed gas in the plasma state; and forming a doped amorphous silicon film (n+ a-Si:H) on the silicon nitride film using the third mixed gas in the plasma state.
- The method further includes forming a gate electrode before the step of forming the silicon nitride film; and forming source and drain electrodes on the doped amorphous silicon film. The method further includes performing a hydrogen plasma treatment on a surface of the silicon nitride film before the step of forming the pure amorphous silicon film. The method further includes performing a hydrogen plasma treatment on a surface of the pure amorphous silicon film before the step of forming the doped amorphous silicon film.
- The method of manufacturing the TFT according to the preferred embodiment of the present invention has the following advantages. Firstly, since each of the thin films is deposited in the plasma state, variation of an internal atmosphere of the process chamber is minimized, whereupon a processing time becomes shorten. Secondly, since the thin films deposited are hydrogen plasma-treated, the hydrogen plasma etches detects on the interface between the thin films, whereupon defects can be prevented. Thirdly, since each of the thin films is deposited under the same pressure, an occurrence of a polymer in the process chamber can be prevented, and interface characteristics of the thin films can be improved.
- For a more complete understanding of the present invention and the advantages thereof, reference is now made to the following descriptions taken in conjunction with the accompanying drawings, in which like reference numerals denote like parts, and in which:
- FIG. 1 is a cross-sectional view illustrating a liquid crystal panel of a conventional active matrix liquid crystal display device;
- FIG. 2 is a cross-sectional view illustrating a conventional back channel etch type thin film transistor;
- FIG. 3 is a graph illustrating a relationship between a RF-power and thin film depositions;
- FIG. 4 is a graph illustrating a relationship between an internal pressure variation of a process chamber and thin film depositions;
- FIG. 5 is a graph illustrating a relationship between a RF-power and a thin film deposition according to a preferred embodiment of the present invention; and
- FIG. 6 is a graph illustrating a variation of an internal pressure of the process chamber during deposition processes of the thin films.
- Reference will now be made in detail to a preferred embodiment of the present invention, example of which is illustrated in the accompanying drawings.
- FIG. 5 is a graph illustrating a relationship between a RF-power and thin film depositions according to a preferred embodiment of the present invention. As shown in FIG. 5, except for a process of injecting a first mixed gas of NH3, N2 and SiH4 into the process chamber in order to deposit a gate insulating layer, the power maintains ON state through the whole deposition processes.
- First, the first mixed gas stabilized under a predetermined pressure is maintained in a first plasma state “A0” by a predetermined RF power intensity, and then the gate insulating layer is deposited. At this point, a deposition temperature of the thin films is one of the most important parameters to control a surface reaction of a semiconductor layer during a deposition process. In other words, since precursors actively react on hydrogen at a temperature of about 300° C. and also the number of the silicon dangling bond is decreased at that temperature, to control a deposition temperature is very important.
- Subsequently, after depositing the gate insulating layer using the first mixed gas, the first mixed gas is removed while the plasma state is maintained (i.e., without OFF of a power). At the same time, a H2 gas is injected into the process chamber. That is, in a second plasma state “A1”, a remove of the first mixed gas (NH3+N2+SiH4) and an injection of the H2 gas are simultaneously carried out. At this time, there is little variation of the pressure, but the pressure may vary in a range of less than 200 mTorr.
- At this point, in the second plasma state “A1”, a hydrogen (H2) plasma treatment is performed by adjusting radio frequency energy within the chamber during a predetermined time period. The hydrogen plasma terminates the dangling bond that may occur on a surface of the gate insulating layer. In other words, the hydrogen plasma functions to etch defects that exist on the surface of the gate insulating layer.
- Subsequently, in the hydrogen plasma state “A2”, a SiH4 gas is injected into the process chamber to create a second mixed gas, so that an active layer is formed using the second mixed gas (H2+SiH4).
- After forming the active layer, the SiH4 gas is removed from the second mixed gas, and the active layer is hydrogen plasma-treated in the third plasma state “A2”.
- Next, the SiH4 gas and a PH3 gas are added to the H2 gas to create a third mixed gas (SiH4+PH3+H2), and an ohmic contact layer (n+ a-Si:H) is formed on the active layer using the third mixed gas.
- As described above, a method of forming the thin films according to the preferred embodiment of the present invention does not turn off a power while depositing the gate insulating layer, the active layer and the ohmic contact layer, whereby defects due to a lattice mismatch can be prevented. As a result, since defects on the interface of each of the thin films are decreased, charges that are trapped due to defects are decreased, and therefore trapped charges do not prevent a flow of the charges. This leads to high electrical characteristics of the TFT.
- FIG. 6 is a graph illustrating a variation of an internal pressure of the process chamber during a deposition process of the thin films. As shown in FIG. 6, there is little variation of the internal pressure during a deposition process of the thin films (the gate insulating layer, the active layer and the ohmic contact layer). Therefore, defects that may occur on a surface of the thin films due to a variation of the internal pressure can be prevented.
- A method of forming other components such as a gate electrode, a source electrode and a drain electrode shown in FIG. 2 is same as the conventional art and thus its explanation is omitted.
- As described herein before, the method of manufacturing the TFT according to the preferred embodiment of the present invention has the following advantages. Firstly, since each of the thin films is deposited in the plasma state, variation of an internal atmosphere of the process chamber is minimized, whereupon a processing time becomes shorten. Secondly, since the thin films deposited are hydrogen plasma-treated, the hydrogen plasma etches detects on the interface between the thin films, whereupon defects can be prevented. Thirdly, since each of the thin films is deposited under the same or similar pressure, an occurrence of a polymer in the process chamber can be prevented, and interface characteristics of the thin films can be improved.
- While the invention has been particularly shown and described with reference to a preferred embodiment thereof, it will be understood by those skilled in the art that the foregoing and other changes in form and details may be made therein without departing from the spirit and scope of the invention.
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KR1019990067845A KR100338125B1 (en) | 1999-12-31 | 1999-12-31 | Thin Film Transistor and method for fabricating the same |
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US20010012650A1 true US20010012650A1 (en) | 2001-08-09 |
US6395652B2 US6395652B2 (en) | 2002-05-28 |
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Cited By (3)
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US20040121085A1 (en) * | 2002-12-20 | 2004-06-24 | Shulin Wang | Method and apparatus for forming a high quality low temperature silicon nitride film |
US20040194706A1 (en) * | 2002-12-20 | 2004-10-07 | Shulin Wang | Method and apparatus for forming a high quality low temperature silicon nitride layer |
US20080050852A1 (en) * | 2006-08-23 | 2008-02-28 | Tae-Hyung Hwang | Manufacturing of flexible display device panel |
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JPS56135968A (en) | 1980-03-27 | 1981-10-23 | Canon Inc | Amorphous silicon thin film transistor and manufacture thereof |
JPS5961964A (en) * | 1982-10-01 | 1984-04-09 | Fujitsu Ltd | Manufacture of thin film transistor |
JPS62200768A (en) * | 1986-02-27 | 1987-09-04 | Fujitsu Ltd | Manufacture of thin film transistor |
JPH0227771A (en) * | 1988-07-15 | 1990-01-30 | Sumitomo Metal Ind Ltd | Thin film semiconductor element |
JP3255942B2 (en) * | 1991-06-19 | 2002-02-12 | 株式会社半導体エネルギー研究所 | Method for manufacturing inverted staggered thin film transistor |
US5582880A (en) * | 1992-03-27 | 1996-12-10 | Canon Kabushiki Kaisha | Method of manufacturing non-single crystal film and non-single crystal semiconductor device |
TW454101B (en) * | 1995-10-04 | 2001-09-11 | Hitachi Ltd | In-plane field type liquid crystal display device comprising liquid crystal molecules with more than two different kinds of reorientation directions and its manufacturing method |
WO2004079826A1 (en) * | 1996-10-22 | 2004-09-16 | Mitsutoshi Miyasaka | Method for manufacturing thin film transistor, display, and electronic device |
-
1999
- 1999-12-31 KR KR1019990067845A patent/KR100338125B1/en active IP Right Grant
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US20040121085A1 (en) * | 2002-12-20 | 2004-06-24 | Shulin Wang | Method and apparatus for forming a high quality low temperature silicon nitride film |
US20040194706A1 (en) * | 2002-12-20 | 2004-10-07 | Shulin Wang | Method and apparatus for forming a high quality low temperature silicon nitride layer |
US7172792B2 (en) * | 2002-12-20 | 2007-02-06 | Applied Materials, Inc. | Method for forming a high quality low temperature silicon nitride film |
US7972663B2 (en) | 2002-12-20 | 2011-07-05 | Applied Materials, Inc. | Method and apparatus for forming a high quality low temperature silicon nitride layer |
US20080050852A1 (en) * | 2006-08-23 | 2008-02-28 | Tae-Hyung Hwang | Manufacturing of flexible display device panel |
Also Published As
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US6395652B2 (en) | 2002-05-28 |
KR100338125B1 (en) | 2002-05-24 |
KR20010066250A (en) | 2001-07-11 |
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