CA2226991A1 - Improved electroplating system and process - Google Patents

Improved electroplating system and process Download PDF

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Publication number
CA2226991A1
CA2226991A1 CA002226991A CA2226991A CA2226991A1 CA 2226991 A1 CA2226991 A1 CA 2226991A1 CA 002226991 A CA002226991 A CA 002226991A CA 2226991 A CA2226991 A CA 2226991A CA 2226991 A1 CA2226991 A1 CA 2226991A1
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CA
Canada
Prior art keywords
drum
electroplating
parts
end plate
rear end
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002226991A
Other languages
French (fr)
Inventor
Anton Ernest Lazaro
Peter Heinrich Tremmel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hardwood Line Manufacturing Co
Original Assignee
Hardwood Line Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hardwood Line Manufacturing Co filed Critical Hardwood Line Manufacturing Co
Publication of CA2226991A1 publication Critical patent/CA2226991A1/en
Abandoned legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/16Apparatus for electrolytic coating of small objects in bulk
    • C25D17/18Apparatus for electrolytic coating of small objects in bulk having closed containers
    • C25D17/20Horizontal barrels

Abstract

This invention relates to a system and process for electroplating that has plating drums whereby the plating drums are filled, and emptied of parts at each individual plating cell and the parts are cleansed by spraying, wiping and/or drying and whereby only cleansed parts are transported from plating cell to plating cell. This results in less contamination and higher efficiencies in plating.

Description

CA 02226991 1998-01-1~

, IMPROVED ELECTROPLATING SYSTEM AND PROCESS

This invention relates to a new and improved electroplating system and process wherein the processing speed of plating is enhanced while certain costs are reduced, due to faster cycle time. Also, it achieves higher ~ ellt density, and, among other things, lower water ll,e~ -.L costs due to lower cont~m;n~t;on of solutions. The system processes parts with plating drums that have plate dipped parts in chemical solution and thereafter the parts are unloaded and rl~Pn~ed so that less contPmin~t;on occurs than in the conventional type of barrel plating systems where the parts are not dried or removed from the barrels. Thus contPminPt;on occurs when uncleansed parts and barrels are dipped in succeeding chemical solutions.
In prior art clc~ Iroplating, where there are loose parts that are smaller and discrete, the usual method of electroplating employed is "barrel plating."
Barrel plating employs perforated barrels that are usually dipped into various types of rinses and cle~lloplating solutions while the discrete parts remain in the barrel.
Therefore, contPmin~t;on of various solutions occurs by failure to isolate each of the solutions as well as by failure to clean and dry the parts and the barrels before the barrel is dipped in different solutions.
Two other popular alternatives to barrel plating are "continuous line plating" and "rack plating." While rack plating does not use a barrel, it has many of the drawbacks of barrel plating due to dipping the parts in different solutions without r'~~ning and drying the barrel or the parts. Continuous line plating does not furnish a satisfactory alternative to plating most small discrete parts.
SUMMARY AND OBJECTS OF THE INVENTION
It is therefore a main object of this invention to provide a drum or a plurality of drums that can each be sclc~Lively loaded and unloaded with parts and can be sub~..e. ~,ed in a solution with scle '-le levels of the solution and rotated to agitate parts and thereafter have the parts unloaded and cleaned and have the solution contained therein exh~--cted and be replenished in an çxicting bath that corresponds to the drum or to each drum where a plurality of drums are employed.
It is a further object of this invention to achieve a continuous plating process by transferring loose discrete parts from plating cell to plating cell in~e~ of transferring parts on a continuous strip or transferring plating barrels containing parts as in the prior art.
It is still further object of this invention to provide a continuous flow of parts through the plating system and through the plating drums or drums in a manner ~ I.c. eby the plating drum provides entrance and egress of the parts through respective entrance and exit apertures defined in the drum end plates where the plating drum is journalled.
Still it is a lurLl-cr object of this invention to provide a faster plating rate and more uniform and higher quality plating finishes by means of conc~ ;c semi-cylindrical anodes for the plating drums in the system in proximity to the outside of the plating drums which provides a more uniform current density in the chemical bath bcl~ cc.- the anode and cathode.
It is even still lul Ihcr an object of this invention to provide horizontal adval-ce~ ..L

CA 02226991 1998-01-1~

of the parts in the system when loading and unloading parts from the plating drums by means of an auger-shaped cathode. Said auger-shaped cathode also promotes better agitation of the parts during the plating cycle as the plating drum rotates; and said cathode also promotes higher ~;ur, e.lt density by being in int;m~te contact with the parts.
It is still even fu~ cl an object of this invention to enable the level of chemical solution to be raised and lowered to prcselecled levels by means of moveable weirs while the plating drum remains rotatable. This ~lim;n~t~C need of removing the plating drum from the plating cell in order to remove the parts from il.lllle. ~-~n in the chemical bath.
Since only the dried parts are transferred to different plating cells, there is less cont~nnin~tion of the chemical baths than in the prior art.
By means of a drum or a plurality of drums, the drum devices as well as the process can achieve higher quality plating finishes that are similar to a continuous plating process as explained in METAL FINISHING GUIDEBOOK AND DIRECTORY, 1990 EDITION. '3ee pp. 621-624, entitled: CONTINUOUS STRIP PLATING OF
ELECTRICAL COMPONENTS.
In order to show a preferred embodiment of this invention, it is well to explain that just as in the continuous strip plating or reel to reel plating, each of the drum units of this invention is associated with a main reservoir tank containing liquid solution with chemical characteristics to perform the given tasks of cle~ning, etçhing and or activation as in preplating, plating and post-plating which can include everything from precious metal recovery, or any special post plating lre~ of cleaning, rinsing, drying, etc.

CA 02226991 1998-01-1~

DE'SCRIPTION OF THE DRAWINGS AND SPECIFICATION
Figure I of the drawing is a prior art schematic of a plating cell;

Figure ,' of the drawing is an example of a "demonstration" plating drum station as shown from a perspective view imposed from above the plating tank;

Figure 2A of the ~ g illu~lrates a view of the ~lign~hle rear end plate;

Figure 3 of the drawing illustrates a cross-sectional view taken on a plane p~;ng through line 3~3 in Figure 2 showing the change in horizontal il..lin~t;~., of the plating drum from loading to unloading position after the unloading handle is fully rotated counter-clocku ise;

Figure 4 of the dl ..~ g illustrates a perspective view imposed from above a plating cell showing the plating drum station and the flow of parts into and out of the plating drum station;

Figure .5 of the drawing illustrates a top view of a plating cell;

Figure ~S of the drawing illustrates a cut away side view of the plating cell showing the auger-shaped cathode;

CA 02226991 1998-01-1~

Figure ,' of the drawing illustrates a cross-sectional view taken on a plane passing through line B-B' looking in the direction of the arrows of the plating cell;

Figure B of the drawing illustrates a sectioned view taken on a plane pq~;ng through line C~C' looking in the direction of the arrows of the plating cell;

Figure ~ of the drawing illustrates the plating drum, driving gear, and hidden view of auger~shaped cathode;

Figure 10 of the drawing illustrates an end view of the plating drum assembly;

Figure 11 of the drawing illustrates a perspective view of apreferred embodiment of the rear end plate ~ c~embled from the drum and how it is assembled to journal the drum as well as be sele_tqhly rotatable from the open position (or unload position) to the closed position (or plating position) as seen respectively in Figure 11A and Figure 1 lB;
and Figure lL2 of the drawing illustrates a system flow chart of the steps of the process disclosed.
Referring to the drawing (wherein like numbers refer to corresponding parts thereof), Figure 1 is apriorartschematic of aplating cell, see p. 623, supra. This shows a continuous strip that has an anode proximate to the strip being plated that is located in a process cell that has the liquid in it controlled by weirs in slots or downspouts, so that CA 02226991 1998-01-1~

the reservoir tank can continually receive circ~ ting liquid sumped or drained from the process cell. I'his regeneration of liquid enriches the process cell with rejuvenated liquid to enable a higher current density available for enhanced plating.
Referring to Figure 2 of the drawing, is a preferred example of a "demonstration"
drum station as shown from a perspective view imposed over a plating tank 21.
Figure 2 of the drawing illustrates a perspective view from the top showing the drum station that has discrete parts 25 therein that are shown for illustrative purposes as having gone through the clccll oplating drum 30 and are being deposited in a chamber 50 that can retain the parts 25 for spraying, cle~n~ing and or drying the parts 25 and thereafter exhaust them down an inclined plane or exit chute 22 as shown in Figures 2 and 4.
Accordingly, this invention provides as one of its important fiatules a new and unique drum and process that merges the advantages of barrel plating with continuous line plating. As seen from the drawings, an electroplating drum 30 illustrates a system with continuous unloading and cle~n~ing and drying of the parts 25 as they move from one solution and plating cell to another. This not only creates faster cycles and allows higher c.lr.c.ll densities, but also has the advantages of less cont~nnin~t;on of solutions and improved efficiency with lower costs by having better integrity in the chemistry of the solutions.
As can be seen from the demonstration drum 30 shown in Figure 2, it is positioned above the plating tank legs 43 where the sides of the reservoir tank (not shown) are supposed to surround the weir gate 26 (not shown) of the plating tank 21 to form a CA 02226991 1998-01-1~

process cell similar to Figure 1 and the bottom of the reservoir tank rests on the reservoir tank legs 43 as will be more fully explained in this specification.
The demonstration drumshown is actually meant to operate in a continuous process line of drums associated with one or a plurality of operalillg reservoirs. Thus, it will become clear that the illustration of one demonstration drum is all that is nece~ary t explain the working of the system and process as defined in the claims.
In Figure 2 it can be seen that parts 25 are loaded into a hopper 20 and preferably dumped from the hopper 20 by lot~ting the hopper 20 upward so the parts 25 slide by gravity through the fixed end plate 28 shown in Figure 2A by going through an opening 28a in the end plate 28.
As seen in Figures 4, 5, 6, and 11 the plating drum 30 is journalled to rotate within the process cell wherein an anode 24 is in proximity to the plating drum 30 and is curved to conform closely to the circumference of the drum. The anode 24 is a meshed or otherwise perforated conductor that is preferably doubled over and semi-cylindrical.
The drum 30 has one of its ends fixedly associated with a driving gear 31 and its ends are journalled in end plate 27 ~not shown) and end plate 28. Alignable end plate 28 is associated with the vertical standard 37 and is ape~ luredto provide egress of parts from the drum to the chamber; and end plate 27 (not shown) is fixed within the standard 37a shown in Figures 2, 4, and 5 when the journal rotates and it is not ~lign~hle as end plate 28. End plate 28 is ~lign~hle by rotating it 180 degrees within the standard37 and a yoke 38 when it is desired to have the aperture 28a therein be positioned for unlor ling or in its open position as shown in Figures 11, 1lA and 1lB. When the parts 25 are exh~ teA

CA 02226991 1998-01-1~

into the drying chamber 50 that enables the parts 25 to be cle~nce~l by being washed, rinsed, and/or dried; then the parts 25 can be transferred to the next proc~;l-~; cell (not shown) once the parts 25 have exited the chamber 50 by falling down the inclined exit chute as shown in Figure 4 so that a conveyor belt (not shown) can transport the ~v!E~nce-l parts 25 to the next proc~i,h.g cell.
As seen from Figure 11, the ~ n~hle end plate 28 has holes 28b, 28c formed therein that are 180 degrees apart that each can be aligned with the respective hole 38a in the yoke 38 ~.hcl ~y the ~lig~ le rear end plate 28 can be allowed to be aligned by rotating it 180 degrees as seen in Figures 11, 11A and 11B.
By removing a locking pin 23 that is positioned to removably protrude through the holes 28b and 28c to m~;nt~in alignment of the ~lign~hle rear end plate 28 within the yoke 38, the end plate can be rotated 180 degrees for either loading or unlQ~ing of the parts 25 as required. The sclc~live securing means or lock for the ~lign~l-le end plate 28 is preferably a locking pin 23 that is received by the plating drum yoke 38 to hold the plate in a sclcclive position relative to the aperture 28a therein so that at selective times the end plate 28 can be moved, removed or rclcascd to enable reorientation of the aperture 28a by rotating this end plate 28 depending on whether the process requires the parts to be dumped into the chamber 50 for clE~ncing at that time. Thus, the aperture 28a through the :~lignPl~le end plate 28 is re~lign~hle on the basis of scle~live activation that can be based on time or some other variable isolated to the chemical make up of the solution.
As seen in Figure 6, 7, 8, and 9 the plating drum 30 has a cathode 32 at the center thereof that is preferably shaped as an auger so the parts 25, as they are being proce~ed CA 02226991 1998-01-1~

can be advanced toward the chamber 50 as the plating drum 30 rotates.
The pla1ing drum 30 is preferably shown with slots 36 and agitators ~not shown), so that as it rotates it creates a greater agitation and ~ ~~y between the parts and liquids therein to enhance the plating or rinsing or whatever the mode the process is in.
The electrical and fluid connection and agitation means are not shown since they are state of the art or conventional art in plating devices of this type but they are represented in the flow chart at Figure 12 which defines the sequence of the process steps in the system.
The system flow chart in Figure 12 explains the process steps of one stage of the demonstration barrel system in order to illustrate how it is contemplated to run the system.
Referring to the drum plating system flow chart, the clcclroplating system and process has means for loading parts 25 from the plating drum 30 as denoted in Box B, as described herein. This is preferably shown by the hopper 20 being loaded and guiding the parts 25 through the opening 27a shown in Figure 2a in the fixed end plate 27.
The system has appropriate switching and timing means shown in Box D for c~ ing the plating drum 30 to receive and ç~h~--ct parts. The switching and timing means also causes raising and lowering of the level of chemical solution 33 in plating by raising the weir gate 26 to appropriatepr~scle~led levels for plating and for el--~Jlyil-g the plating tank 21.
The system and process uses a recirculation pump (not shown) to sump and return rejuvenated chemical solution 33 from the reservoir (not shown) to the plating cell/tank CA 02226991 1998-01-1~

21. The timing and switching means shown in Box D also controls the rotation of the plating drum 30 and agitation of the parts 25 therein as denoted in Box E as well as the intensity and amount of electric power applied to the anode 24 and auger-shaped cathode 32 as shown in Box C during the rotation of the plating drum 30.
At the conclusion of a plating drum rotation cycle as denoted in Box E, the weir gate 26 can be moved to bring the level of the chemical solution 33 below the bottom of the plating drum 30 as denoted in Box F. The ~lign~hle end plate 28 is aligned by removing the pin 23, 1 olalil,g the alignable end plate 28 for 180 degrees, and r&;llsel tihg the pin 23 to permit the unloading of parts 25 from the plating drum 30 as denoted in Box G. The single plating drum 30 and single plating tank 21 described in this disclosur~
comprise a plating cell unit which can be part of a system comprising a plurality of plating cells that are incorporated into the electroplating system and process herein described.
Also, the lo~(ling end of the plating drum 30 may be raised by rotating the unloading handle 29 to facilitate unl~a ling of parts 25 through the exit aperture 28a by action of gravity.
The exit aperture 28a is then closed by removing the pin 23 and ~ligning the ~lign~hle end plate 28 by rotating it 180 degrees, and reinserting the pin 23 to lock the ~lign~hle end plate 28 in a closed position as denoted in Block H.
The unloaded parts 25 exit the plating drum 30 through the exit aperture 28a, into a cle~n~ing chamber as denoted in Box I. The cleaned and dried parts 25 are transferred to a new work station through exit chute 22 for another plating cycle as denoted in Box J.
As stated earlier, rotation of the plating drumwith an auger-shaped cathode creates a more thorough contact with the parts; and the cylindrical shape of the anode allows a more uniform and higher c~ll.e.lt density. The drum is rotatable and it is loaded or unloaded with parts at each plating cell. The parts may be unloaded, cleaned and/or dried at each plating cell giving the advantage of m;nimi~ing the cont~n~:n~tion of electrolyte in snccç~cive plating cells with electrolyte from prece-ling plating cells. The process of the plating system is enhanced by means of substantially vertical moveable weirs ~. Lel eby the level of the electrolyte or chemical in each plating cell within the elc~ plating system can be maintained at prcsf Ic te~l levels, thereby pe, .llillh.g parts to be transported between plating cells within the cleclloplating system during the process and thus providing the advantage of elimin:~ting transporting of the plating drums wherein the parts are electroplated. The front and rear end plates are finely timed with each other to allow loading and unlo?(ling of parts and enable the parts to be delivered as cle~nce-l parts at each cell in the process and thereby accomplish many of the objects as stated.
It should be realized that the present invention is an advantage over the previous alternative systems and processes including continuous line plating and barrel plating.
Unlike continuous line plating, dis~- ele parts may be plated in the present invention and, unlike barrel plating, the plating drums in the present invention remain rotatable in each plating cell and are not transported to successive plating cells during the process.
This gives the advantage of a more efficient and quicker el~lroplating process by maintaining the chemical solutions and the parts in a subst~nt;~lly clean and CA 02226991 1998-01-1~

uncont~min~ted condition during the process. This also gives the advantage of depositing a more uniform and purer finish and a (l~ eased cycle time over either the continuous line plating or barrel plating processes.
It may thus be seen that the objects of the present invention set forth herein as well as those made apparent from the foregoing description are effil,;-,.llly obtained. While preferred embo-lil"cnls of the invention have been set forth for purposes of ~ 'Ds ~re, modification of disclosed embodil-le.ll~ of the invention as well as other em~o.l;...o..~i thereof may occur to those skilled in the art. Accordingly, the appended claims are intended to cover all embo.l;~ ..L~ which do not depart from the spirit and scope of the invention.

s, ~~

Claims (15)

1. An electroplating system comprising: a tank of electroplating chemical solution that is recirculated during processing of parts to be plated in a rotatable perforated drum and weir gate means operatively associated with the tank for keeping the solution at a preselectable level to enable said electroplating system to process the parts fed to it, said electroplating drum having a front end, a rear end, an inside, and an outer circumference that is at least partially immersed in the electroplating chemical solution, at least a cathode located within the drum, said cathode comprising a helical conductor fixedly engaged to said drum, said cathode serving as a driver to move the parts through the drum when the drum is rotated as well as said cathode, means for rotating, loading and unloading the parts located in the electroplating drum, means for cleansing the parts that have been electroplated after they have been loaded and processed and thereafter unloaded from the drum.
2. A system as defined in Claim 1, further comprising a fixed front end plate at the front end of said drum, wherein an aperture is defined above the level of the chemical electroplating solution and communicates with the inside of said drum and enables the parts to be loaded in said drum.
3. A system defined in Claim 2, wherein said electroplating solution has a preselected level which is below said aperture in said fixed front end plate, to enable the aperture to accept the parts without losing the chemical electroplating solution through said fixed front end plate.
4. An electroplating system, as defined in Claim 1, wherein an alignable rear end plate is provided at the rear end of the drum, said rear end plate having an open and a closed position and means for aligning said plate and locking said plate in either the open or closed position, said rear end plate having an aperture that is positioned to enable said parts to be exhausted from said drum through said aperture for purposes of cleansing said parts when said rear end plate is in the open position.
5. A system as defined in Claim 4, wherein a chamber means for cleansing is associated with said system to spray, clean, wipe, rinse, or dry said parts exhausted through said rear end plate.
6. A system as defined in Claim 4 wherein said alignable rear end plate has at least a locking pin for selectably locking said rear end plate to anchor the same either in the open or closed position.
7. A system as defined in Claim 6 wherein said open position of said alignable rear end plate is locked where said aperture is below the preselectable solution level of said tank, and communicates with a chamber for cleansing by spraying, drying or wiping, and said alignable rear end plate is locked in said open position to enable the parts from the drum to enter said chamber means after having been processed through said drum.
8. A system as defined in Claim 7 wherein said aperture is above said solution level in the closed position and said rear end plate has been rotated 180 degrees from the open position after removing said locking pin and then replacing said locking pin in said rear end plate to removably lock the same in place in said closed position.
9. A system as defined in Claim 4 wherein said drum is journalled for rotation in both of said end plates, and is associated with a gear driving means for rotation and both of said end plates are adapted to accept and journal support said drum for rotation.
10. A system as defined in Claim 4 wherein said alignable rear end plate can be rotated 180 degrees from the open position to the closed position when said pin is removed and thereafter by reorienting said rear end plate back to the closed position to removably lock the same in the closed position by reinserting said pin.
11. A system as defined in Claim 10, further comprising manual means to enable tipping the drum to promote further unloading of the parts through said aperture in said rear end plate.
12. An electroplating process that electroplates parts in an electroplating drum having an anode and having an electroplating chemical solution, recirculating pumps to circulate the electroplating chemical solution and to maintain a preselected level of the electroplating chemical solution in the electroplating drum to effect efficient plating of parts, means for loading and unloading the electroplating drum having openings located in front and rear end plates of the drum, having switch timing means and cathode means contained in said drum, and shaped to cause electroplating as well as movement of said parts toward the rear of the drum when the drum rotates, and means for unloading the parts through said rear end plates for cleansing the parts by spraying, wiping, drying or rinsing the parts, comprising the steps of:
(a) providing a supply of the electroplating chemical solution for said electroplating system;
(b) loading said parts in said drum;
(c) raising the electroplating chemical solution to a preselected level;
(d) energizing the electroplating drum, the cathode means, the anode and the recirculating pumps;
(e) rotating the electroplating drum and cathode means to electroplate the parts as well as cause the parts to agitate and move toward the rear end plate of the electroplating drum; and (f) removing said parts from said drum through an opening in the rear end plate.
13. A process as set forth in Claim 12, further comprising the step of:
cleansing by at least spraying, drying, wiping or rinsing the parts, and expelling the parts for treatment in a new work station.
14. An electroplating process carried out with an anode and cathode having means for loading and unloading an electroplating drum through the front and rear ends of the drum without removing said drum from an electroplating chemical solution into which it is immersed during electroplating, wherein electroplated parts are cleansed by spraying, cleaning, drying, or rinsing the parts after being unloaded from one end of the electroplating drum while the electroplating drum is at least partially immersed in the electroplating chemical solution and the drum has an alignable rear end plate having an aperture that is rotatable 180 degrees from a closed position for electroplating to an open position where the parts are exhausted from said electroplating drum to rotate as well as receive and exhaust the parts for cleansing at selected times, a reservoir for an electroplating chemical solution and pumps to circulate the electroplating chemical solution to effect efficient electroplating and weir cell gates that maintain a preselected level of the electroplating chemical solution in a weir cell that is activated and controlled at selected times by the switch means comprising the steps of:
(a) closing the aperture in the alignable rear end plate by rotating the rear end plate 180 degrees and removably locking the plate into a fixed position;
(b) loading the parts to be electroplated into the electroplating drum;
(e) raising the electroplating chemical solution to the preselected level by moving at least a partially vertical weir cell gate to the preselected level, to immerse the parts in the electroplating chemical solution in a weir cell;
(d) actuating switch means to agitate the parts in the electroplating drum by rotating the cathode and the electroplating drum while electroplating the parts and to control loading, unloading, agitation of the parts and rotation of the electroplating drum, a preselected weir cell gate height, and intensity and amount of electric power applied to the cathode and an anode;

(e) recirculating the electroplating chemical solution in the weir cell to replenish, regenerate, and enrich the weir cell with rejuvenated electroplating chemical solution from the reservoir;
(f) moving the weir gates at a termination of the agitation to drain the chemical electroplating solution from the weir cell;
(g) aligning the aperture of the alignable rear end plate and to unload the parts from the electroplating drum for at least spraying, drying, wiping, or rinsing the parts and achieving optimum means for the continuous electroplating of the parts without contaminating successive electroplating solutions.
15. A system as defined in Claim 1 wherein the anode is external to and proximate to the drum, said anode extending along and conforming with a portion of the outer circumference of the drum in an arcuate manner.
CA002226991A 1997-01-23 1998-01-15 Improved electroplating system and process Abandoned CA2226991A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/786,872 1997-01-23
US08/786,872 US5755948A (en) 1997-01-23 1997-01-23 Electroplating system and process

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US6187164B1 (en) * 1997-09-30 2001-02-13 Symyx Technologies, Inc. Method for creating and testing a combinatorial array employing individually addressable electrodes
US6228232B1 (en) 1998-07-09 2001-05-08 Semitool, Inc. Reactor vessel having improved cup anode and conductor assembly
US5945594A (en) * 1998-10-14 1999-08-31 Meritor Light Vehicle Systems-France Method and apparatus for the electrochemical inspection of galvanized cable and method and apparatus for predicting the corrosion life of galvanized cable undergoing mechanical fatigue
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US7118658B2 (en) * 2002-05-21 2006-10-10 Semitool, Inc. Electroplating reactor
KR100617070B1 (en) * 2005-09-13 2006-08-30 동부일렉트로닉스 주식회사 Method for cleaning electronic chemical planting cell
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US11352709B1 (en) 2019-09-04 2022-06-07 Presidio Components. Inc. Helically ribbed electroplating barrel
CN113638157B (en) * 2021-07-22 2022-04-19 绍兴越城恒乔纺织有限公司 Negative ion fabric and preparation method thereof
CN116180203B (en) * 2023-04-27 2023-07-21 苏州台祥机电设备有限公司 Inclined barrel plating equipment
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